4.7 Article

Microstructure evolution in the hypo-eutectic alloy Al0.75CrFeNi2.1 manufactured by laser powder bed fusion and subsequent annealing

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2022.144315

Keywords

Additive manufacturing; Eutectic high entropy alloys; Microstructure; Atom probe tomography; Synchrotron X-ray diffraction

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The medium entropy alloy Al0.75CrFeNi2.1 with hypo-eutectic composition was processed by laser powder bed fusion (LPBF). Non-equilibrium solidification conditions led to the formation of cellular and lamellar microstructures. In-situ high-energy synchrotron X-ray diffraction (HEXRD) and atom probe tomography (APT) were used to study the microstructure evolution during post-build annealing. The mechanical properties of the alloy, including tensile strength and elongation at fracture, were evaluated and compared to martensitic steels.
The hypo-eutectic medium entropy alloy Al0.75CrFeNi2.1 was processed by laser powder bed fusion (LPBF). The off-equilibrium solidification conditions prohibited coupled eutectic growth. Instead, the primary face centered cubic phase A1(FCC) solidified with a cellular morphology and the body centered, initially ordered B2(BCC) phase formed as a thin intercellular envelope. During post-build annealing an ultrafine quasi-lamellar pattern evolved following BCC growth and coarsening. The novel solid state transformation from cellular to lamellar morphology was attributed to a pronounced anisotropy of the FCC|BCC phase boundary energy. Microstructure evolution was also studied during continuous heating using in situ high-energy synchrotron X-ray diffraction (HEXRD) carried out at the beamline P07-HEMS of PETRA III (German Electron Synchrotron, DESY). The ul-trafine and nano-scale features of the microstructure were quantitatively analyzed by atom probe tomography (APT) in the as-built condition and after isothermal annealing at 950 degrees C. The benefits of LPBF processing were discussed on the basis of mechanical properties measured by 3-point bending. The estimated tensile properties after annealing at 950 degrees C/6 h reached YS approximate to 860 MPa, UTS approximate to 1384 MPa with an elongation at fracture of approximate to 11%. Tensile properties in the as-built condition were comparable to martensitic steels.

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