Redox Mediators in Homogeneous Co-electrocatalysis

Electrochemical Enantioselective Nucleophilic α-C(sp3)–H Alkenylation of 2-Acyl Imidazoles

(2022) Peng Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Corrigendum: Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO 2 via Through‐Space Electronic Conjugation

(2022) Shelby L. Hooe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic metal hydride generation using CPET mediators

(2022) Subal Dey et al.   NATURE

Use of a PCET Mediator Enables a Ni-HER Electrocatalyst to Act as a Hydride Delivery Agent

(2022) Joseph Derosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem electrocatalytic N2 fixation via proton-coupled electron transfer

(2022) Pablo Garrido-Barros et al.   NATURE

The Role of Organic Promoters in the Electroreduction of Carbon Dioxide

(2021) Dmitry V. Vasilyev et al.   ACS Catalysis

Strengths of Acids in Acetonitrile

(2021) Agnes Kütt et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

DFT Study on the Electrocatalytic Reduction of CO2 to CO by a Molecular Chromium Complex

(2021) Juan J. Moreno et al.   INORGANIC CHEMISTRY

Enhancing a Molecular Electrocatalyst’s Activity for CO2 Reduction by Simultaneously Modulating Three Substituent Effects

(2021) Weixuan Nie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan–Lam Coupling Reactions

(2021) Benjamin R. Walker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO 2 via Through‐Space Electronic Conjugation**

(2021) Shelby L. Hooe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications

(2021) Rishi G. Agarwal et al.   CHEMICAL REVIEWS

Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron−Proton Transfer Mediators

(2020) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels

(2020) Colin W. Anson et al.   CHEMICAL REVIEWS

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

(2020) Matthew J. Chalkley et al.   CHEMICAL REVIEWS

Determining Proton-Coupled Standard Potentials and X–H Bond Dissociation Free Energies in Nonaqueous Solvents using Open-Circuit Potential Measurements

(2020) Catherine F. Wise et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO2 Reduction Catalyzed by Iron Porphyrin

(2020) Peter T. Smith et al.   INORGANIC CHEMISTRY

Electrochemical Strategy for Hydrazine Synthesis: Development and Overpotential Analysis of Methods for Oxidative N–N Coupling of an Ammonia Surrogate

(2020) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simulation of electrochemical properties of naturally occurring quinones

(2020) Sebastian Birkedal Kristensen et al.   Scientific Reports

Atropisomeric Hydrogen Bonding Control for CO 2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins

(2020) Philipp Gotico et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

(2020) Hui Chen et al.   CHEMICAL REVIEWS

Electrochemically Regenerable Hydrogen Atom Acceptors: Mediators in Electrocatalytic Alcohol Oxidation Reactions

(2020) Elizabeth A. McLoughlin et al.   ACS Catalysis

Oxygen Reduction by Iron Porphyrins with Covalently Attached Pendent Phenol and Quinol

(2020) Asmita Singha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen Reduction to Hydrogen Peroxide by a Molecular Mn Complex: Mechanistic Divergence between Homogeneous and Heterogeneous Reductants

(2019) Shelby L. Hooe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

(2019) Stephanie Nitopi et al.   CHEMICAL REVIEWS

Introduction to Electron Transfer: Theoretical Foundations and Pedagogical Examples

(2019) Eric J. Piechota et al.   JOURNAL OF CHEMICAL EDUCATION

Highly Efficient Electrocatalytic Reduction of CO2 to CO by a Molecular Chromium Complex

(2019) Shelby L. Hooe et al.   ACS Catalysis

Ferric ion pair mediated biomass redox flow fuel cell and related chemical reaction kinetics study

(2018) Xihong Zu et al.   CHEMICAL ENGINEERING JOURNAL

Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions

(2018) Jordan E. Nutting et al.   CHEMICAL REVIEWS

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts

(2018) Robert Francke et al.   CHEMICAL REVIEWS

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

(2018) Michael L. Pegis et al.   CHEMICAL REVIEWS

Thermodynamic and kinetic hydricities of metal-free hydrides

(2018) Stefan Ilic et al.   CHEMICAL SOCIETY REVIEWS

Pancake bonding, an unusual pi-stacking interaction

(2018) Miklos Kertesz   CHEMISTRY-A EUROPEAN JOURNAL

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pKa Effects and Demonstrating Electrocatalysis

(2018) Matthew J. Chalkley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Urea-Based Multipoint Hydrogen-Bond Donor Additive Promotes Electrochemical CO2 Reduction Catalyzed by Nickel Cyclam

(2018) Eva M. Nichols et al.   ORGANOMETALLICS

Selective electrochemical generation of benzylic radicals enabled by ferrocene-based electron-transfer mediators

(2018) Alastair J. J. Lennox et al.   Chemical Science

Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins

(2018) Eva M. Nichols et al.   Chemical Science

Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

(2018) Kate M. Waldie et al.   ACS Catalysis

Fe-Mediated HER vs N2RR: Exploring Factors That Contribute to Selectivity in P3EFe(N2) (E = B, Si, C) Catalyst Model Systems

(2018) Benjamin D. Matson et al.   ACS Catalysis

H2 Oxidation Electrocatalysis Enabled by Metal-to-Metal Hydrogen Atom Transfer: A Homolytic Approach to a Heterolytic Reaction

(2018) Geoffrey M. Chambers et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzimidazoles as Metal-Free and Recyclable Hydrides for CO2 Reduction to Formate

(2018) Chern-Hooi Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Resolving orbital pathways for intermolecular electron transfer

(2018) Cameron W. Kellett et al.   Nature Communications

Electrocatalytic Reduction of Dioxygen to Hydrogen Peroxide by a Molecular Manganese Complex with a Bipyridine-Containing Schiff Base Ligand

(2017) Shelby L. Hooe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Alcohol Oxidation with Ruthenium Transfer Hydrogenation Catalysts

(2017) Kate M. Waldie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Electrocatalytic O2 Reduction Involving Co(salophen) with p-Hydroquinone as an Electron–Proton Transfer Mediator

(2017) Colin W. Anson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET

(2017) Matthew J. Chalkley et al.   ACS Central Science

Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide Oxidation

(2016) Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coenzyme Q biosynthesis and its role in the respiratory chain structure

(2016) María Alcázar-Fabra et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

An internal electron reservoir enhances catalytic CO2 reduction by a semisynthetic enzyme

(2016) Camille R. Schneider et al.   CHEMICAL COMMUNICATIONS

Thermodynamic Hydricity of Transition Metal Hydrides

(2016) Eric S. Wiedner et al.   CHEMICAL REVIEWS

Direct Conversion of Wheat Straw into Electricity with a Biomass Flow Fuel Cell Mediated by Two Redox Ion Pairs

(2016) Jian Gong et al.   ChemSusChem

Quinone 1 e– and 2 e–/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships

(2016) Mioy T. Huynh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis

(2016) Colin W. Anson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials

(2016) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators

(2016) Artavazd Badalyan et al.   NATURE

Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion

(2015) Cyrille Costentin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst

(2015) Scott D. McCann et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrodes Functionalized with the 2,2,6,6-Tetramethylpiperidinyloxy Radical for the Waste-Free Oxidation of Alcohols

(2015) Rosaria Ciriminna et al.   ChemCatChem

Efficient Conversion of Lignin to Electricity Using a Novel Direct Biomass Fuel Cell Mediated by Polyoxometalates at Low Temperatures

(2015) Xuebing Zhao et al.   ChemSusChem

Active Thermochemical Tables: Sequential Bond Dissociation Enthalpies of Methane, Ethane, and Methanol and the Related Thermochemistry

(2015) Branko Ruscic   JOURNAL OF PHYSICAL CHEMISTRY A

Kinetic Stabilization of Quinone Dianions via Hydrogen Bonding by Water in Aprotic Solvents

(2015) Patrick A. Staley et al.   Journal of Physical Chemistry C

Predicting Electrocatalytic Properties: Modeling Structure–Activity Relationships of Nitroxyl Radicals

(2015) David P. Hickey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects

(2015) Mohammad Rafiee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mn Bipyrimidine Catalyst Predicted To Reduce CO2 at Lower Overpotential

(2015) Yan Choi Lam et al.   ACS Catalysis

High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

(2015) James B. Gerken et al.   ACS Central Science

Redox catalysis in organic electrosynthesis: basic principles and recent developments

(2014) Robert Francke et al.   CHEMICAL SOCIETY REVIEWS

Redox Mediators in Visible Light Photocatalysis: Photocatalytic Radical Thiol–Ene Additions

(2014) Elizabeth L. Tyson et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemical Generation of Strong One-Electron Reductants via Light-Induced Electron Transfer with Reversible Donors Followed by Cross Reaction with Sacrificial Donors

(2014) Bing Shan et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals

(2014) Bradford L. Ryland et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis

(2014) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Small electron-transfer proteins as mediators in enzymatic electrochemical biosensors

(2013) Célia M. Silveira et al.   ANALYTICAL AND BIOANALYTICAL CHEMISTRY

Selective 4e–/4H+ O2 Reduction by an Iron(tetraferrocenyl)Porphyrin Complex: From Proton Transfer Followed by Electron Transfer in Organic Solvent to Proton Coupled Electron Transfer in Aqueous Medium

(2013) Kaustuv Mittra et al.   INORGANIC CHEMISTRY

Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation

(2013) Jessica M. Hoover et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Do spin state and spin density affect hydrogen atom transfer reactivity?

(2013) Caroline T. Saouma et al.   Chemical Science

Selective four electron reduction of O2 by an iron porphyrin electrocatalyst under fast and slow electron fluxes

(2012) Subhra Samanta et al.   CHEMICAL COMMUNICATIONS

Organic molecules as mediators and catalysts for photocatalytic and electrocatalytic CO2reduction

(2012) Yeonji Oh et al.   CHEMICAL SOCIETY REVIEWS

Electrochemical and chemical formation of a low-barrier proton transfer complex between the quinone dianion and hydroquinone

(2012) Pablo D. Astudillo et al.   ELECTROCHIMICA ACTA

Marcus Theory: Thermodynamics CAN Control the Kinetics of Electron Transfer Reactions

(2012) Todd P. Silverstein   JOURNAL OF CHEMICAL EDUCATION

Reinvestigation of a former concerted proton-electron transfer (CPET), the reduction of a hydrogen-bonded complex between a proton donor and the anion radical of 3,5-di-tert-butyl-1,2-benzoquinone

(2012) Dennis H. Evans et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Electrochemical determination of hydrogen peroxide with cytochrome c peroxidase and horse heart cytochrome c entrapped in a gelatin hydrogel

(2011) Karolien De Wael et al.   BIOELECTROCHEMISTRY

Photocatalytic hydrogen production

(2011) Thomas S. Teets et al.   CHEMICAL COMMUNICATIONS

Strategies for “wiring” redox-active proteins to electrodes and applications in biosensors, biofuel cells, and nanotechnology

(2011) Tanja Nöll et al.   CHEMICAL SOCIETY REVIEWS

Photogenerated avenues in macromolecules containing Re(i), Ru(ii), Os(ii), and Ir(iii) metal complexes of pyridine-based ligands

(2011) Bobby Happ et al.   CHEMICAL SOCIETY REVIEWS

Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells

(2011) Eugen S. Andreiadis et al.   PHOTOCHEMISTRY AND PHOTOBIOLOGY

How to Conceptualize Catalytic Cycles? The Energetic Span Model

(2010) Sebastian Kozuch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Acid/base and hydrogen bonding effects on the proton-coupled electron transfer of quinones and hydroquinones in acetonitrile: Mechanistic investigation by voltammetry, 1H NMR and computation

(2010) Timothy M. Alligrant et al.   ELECTROCHIMICA ACTA

Scales of Oxidation Potentials, pKa, and BDE of Various Hydroquinones and Catechols in DMSO

(2010) Xiao-Qing Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Immobilization of glucose oxidase on reagentless ferrocene-containing polythiophene derivative and its glucose sensing application

(2009) M. Fatih Abasıyanık et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Comparative Analysis of the Multicenter, Long Bond in [TCNE]·−and Phenalenyl Radical Dimers: A Unified Description of Multicenter, Long Bonds

(2009) Fernando Mota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Approach to the Mechanistic Study of Proton-Coupled Electron Transfer

(2008) Cyrille Costentin   CHEMICAL REVIEWS

One-Electron and Two-Electron Transfers in Electrochemistry and Homogeneous Solution Reactions

(2008) Dennis H. Evans   CHEMICAL REVIEWS

Electrochemical Glucose Sensors and Their Applications in Diabetes Management

(2008) Adam Heller et al.   CHEMICAL REVIEWS

[Cyanil]22− dimers possess long, two-electron ten-center (2e−/10c) multicenter bonding

(2008) Iñigo Garcia-Yoldi et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS