Tracking and Understanding Dynamics of Atoms and Clusters of Late Transition Metals with In-Situ DRIFT and XAS Spectroscopy Assisted by DFT

Surface Noble Metal Concentration on Ceria as a Key Descriptor for Efficient Catalytic CO Oxidation

(2022) Florian Maurer et al.   ACS Catalysis

Active and Regioselective Ru Single-Site Heterogeneous Catalysts for Alpha-Olefin Hydroformylation

(2022) Francisco Javier Escobar-Bedia et al.   ACS Catalysis

Design of Single-Atom Catalysts and Tracking Their Fate Using Operando and Advanced X-ray Spectroscopic Tools

(2022) Bidyut Bikash Sarma et al.   Chemical Reviews

Unraveling CO adsorption on model single-atom catalysts

(2021) Jan Hulva et al.   SCIENCE

In Situ PM-IRRAS Study of CO Adsorption on Au Surfaces: Solving the Puzzle

(2021) Yunxi Yao et al.   Journal of Physical Chemistry C

Unraveling the Intermediate Reaction Complexes and Critical Role of Support-Derived Oxygen Atoms in CO Oxidation on Single-Atom Pt/CeO2

(2021) Yubing Lu et al.   ACS Catalysis

Interface dynamics of Pd–CeO2 single-atom catalysts during CO oxidation

(2021) Valery Muravev et al.   Nature Catalysis

Relevance of IR Spectroscopy of Adsorbed CO for the Characterization of Heterogeneous Catalysts Containing Isolated Atoms

(2021) Frederic C. Meunier   Journal of Physical Chemistry C

One-Pot Cooperation of Single-Atom Rh and Ru Solid Catalysts for a Selective Tandem Olefin Isomerization-Hydrosilylation Process

(2020) Bidyut B. Sarma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Prospects of Heterogeneous Hydroformylation with Supported Single Atom Catalysts

(2020) Jonas Amsler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single atoms or not? The limitation of EXAFS

(2020) Kun Feng et al.   APPLIED PHYSICS LETTERS

Metal-specific reactivity in single-atom-catalysts: CO oxidation on 4d and 5d transition metals atomically dispersed on MgO

(2020) Bidyut Bikash Sarma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2

(2020) Florian Maurer et al.   Nature Catalysis

Synergy between Metallic and Oxidized Pt Sites Unravelled during Room Temperature CO Oxidation on Pt/Ceria

(2020) Frederic C. Meunier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vibrational Frequencies of Cerium-Oxide-Bound CO: A Challenge for Conventional DFT Methods

(2020) Pablo G. Lustemberg et al.   PHYSICAL REVIEW LETTERS

In situ spectroscopy-guided engineering of rhodium single-atom catalysts for CO oxidation

(2019) Max J. Hülsey et al.   Nature Communications

On the contamination with nickel and nickel tetracarbonyl during FT-IR investigation of catalysts under CO-containing gases

(2019) Frederic C. Meunier   JOURNAL OF CATALYSIS

La-Stabilized, Single-Atom Ir/AC Catalyst for Heterogeneous Methanol Carbonylation to Methyl Acetate

(2019) Siquan Feng et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Reversible and cooperative photoactivation of single-atom Cu/TiO2 photocatalysts

(2019) Byoung-Hoon Lee et al.   NATURE MATERIALS

Local Structure and Electronic State of Atomically Dispersed Pt Supported on Nanosized CeO2

(2019) Matthew Kottwitz et al.   ACS Catalysis

Determination of the Evolution of Heterogeneous Single Metal Atoms and Nanoclusters under Reaction Conditions: Which Are the Working Catalytic Sites?

(2019) Lichen Liu et al.   ACS Catalysis

Distribution and Valence State of Ru Species on CeO2 Supports: Support Shape Effect and Its Influence on CO Oxidation

(2019) Junhao Li et al.   ACS Catalysis

Iridium Atoms Bonded to Crystalline Powder MgO: Characterization by Imaging and Spectroscopy

(2019) Louise M. Debefve et al.   Journal of Physical Chemistry C

Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2

(2019) Joaquin Resasco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and Chemical Properties of Oxide Nanoparticles Determined by Surface-Ligand IR Spectroscopy

(2019) Christof Wöll   ACS Catalysis

Heterogeneous single-atom catalysis

(2018) Aiqin Wang et al.   Nature Reviews Chemistry

Low-temperature restructuring of CeO2-supported Ru nanoparticles determines selectivity in CO2 catalytic reduction

(2018) Aisulu Aitbekova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Chemistry of CO: Carbonylation

(2018) Jin-Bao Peng et al.   Chem

Atomically Dispersed Rhodium on Self-Assembled Phosphotungstic Acid: Structural Features and Catalytic CO Oxidation Properties

(2017) Bin Zhang et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Atomically Dispersed Pd–O Species on CeO2(111) as Highly Active Sites for Low-Temperature CO Oxidation

(2017) Giulia Spezzati et al.   ACS Catalysis

Surface Faceting and Reconstruction of Ceria Nanoparticles

(2016) Chengwu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)3

(2016) Rui Lang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fundamentals and Catalytic Applications of CeO2-Based Materials

(2016) Tiziano Montini et al.   CHEMICAL REVIEWS

Can the state of platinum species be unambiguously determined by the stretching frequency of an adsorbed CO probe molecule?

(2016) Hristiyan A. Aleksandrov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping

(2016) J. Jones et al.   SCIENCE

Individual Heat of Adsorption of Adsorbed CO Species on Palladium and Pd–Sn Nanoparticles Supported on Al2O3 by Using Temperature-Programmed Adsorption Equilibrium Methods

(2016) Imen Jbir et al.   ACS Catalysis

Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt1 Catalyst

(2016) Chunlei Wang et al.   ACS Catalysis

Catalytically Active and Spectator Ce3+in Ceria-Supported Metal Catalysts

(2015) René Kopelent et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolated Metal Active Site Concentration and Stability Control Catalytic CO2 Reduction Selectivity

(2015) John C. Matsubu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts

(2015) K. Ding et al.   SCIENCE

Equilibrium Thermodynamics To Form a Rhodium Formyl Complex from Reactions of CO and H2: Metal σ Donor Activation of CO

(2014) Gregory H. Imler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina

(2014) Eric J. Peterson et al.   Nature Communications

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

(2013) Xiao-Feng Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reactivity of Surface Species in Heterogeneous Catalysts Probed by In Situ X-ray Absorption Techniques

(2013) Silvia Bordiga et al.   CHEMICAL REVIEWS

Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment

(2013) Joachim Paier et al.   CHEMICAL REVIEWS

Remarkable Performance of Ir1/FeOx Single-Atom Catalyst in Water Gas Shift Reaction

(2013) Jian Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing adsorption sites for CO on ceria

(2013) Kumudu Mudiyanselage et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Density functionals for surface science: Exchange-correlation model development with Bayesian error estimation

(2012) Jess Wellendorff et al.   PHYSICAL REVIEW B

Atomically Dispersed Supported Metal Catalysts

(2012) Maria Flytzani-Stephanopoulos et al.   Annual Review of Chemical and Biomolecular Engineering

Supported Molecular Iridium Catalysts: Resolving Effects of Metal Nuclearity and Supports as Ligands

(2011) Jing Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-atom catalysis of CO oxidation using Pt1/FeO x

(2011) Botao Qiao et al.   Nature Chemistry

Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

(2010) Carlo Lamberti et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Ethanol Synthesis from Syngas on Rh(111)

(2009) YongMan Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY