4.7 Article

Carboxylated-covalent organic frameworks and chitosan assembled membranes for precise and efficient dye separation

Journal

JOURNAL OF MEMBRANE SCIENCE
Volume 663, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.memsci.2022.121075

Keywords

Covalent organic frameworks; Membrane; Chitosan; Nanofiltration; Dye separation

Funding

  1. National Natural Science Foundation of China
  2. Fujian Provin-cial Department of Science and Technology
  3. School-enterprise cooperation project
  4. Fujian Shunchang Rao?s BaiYu Food Co., Ltd.
  5. [21676133]
  6. [2020N0016]
  7. [A91884]

Ask authors/readers for more resources

This study focuses on the development of highly crystalline COF powders and their assembly with chitosan to construct precise-sieving membranes. The membranes exhibit precise rejection to various dyes, while allowing ultrafast permeance. The study provides a significant concept and strategy for the preparation of high precise-sieving COF membranes.
Covalent organic frameworks (COFs) based membranes have demonstrated great potentials in molecular separation. Currently, most studies focus on developing continuous COF membranes. However, their low crystallinity compared with COF powders due to the more restricted synthesis conditions impedes their application in precise separation. Herein, we explored the assembly of highly crystalline COF powders with chitosan (CS) to construct precise-sieving membranes with high COFs loading. A post-carboxylated COFs (TATP-COOH) was synthesized, and a facile and scalable strategy was developed for constructing the assembled COF membranes (TATPCOOH@CS/TATP-COOH/CA) with TATP-COOH loading as high as 40 wt% (82 v%). Characterizations revealed TATP-COOH particles could interact with CS via H-bonding to form dense TATP-COOH@CS layers, and the TATP-COOH layer on the CA substrate was essential to obtain mechanically stable membranes. The prepared membranes exhibited precise rejection to Congo red, Coomassie brilliant blue (BB), Alcian blue and Direct blue 19 with 100% rejection and ultrafast permeance (>1350 L m- 2 h-1 MPa- 1). It also showed superior precision in separating Methyl orange and BB mixed solution with only Methyl orange passing through. This study provides a significant concept and a facile strategy to the preparation of high precise-sieving COF membranes to take advantages of highly crystalline COFs.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Surface Cleaning and Protection Engineering via Functionalization to Awaken the Intrinsic Catalytic Activity of Co3O4

Bingxian Chu, Shaoqing Liu, Qiuju Qin, Runqi Zhao, Kean Chen, Xueyan Hou, Rongyao Li, Chen Li, Jianhua Chen, Lihui Dong, Bin Li

Summary: Reflux treatment with methanol effectively enhances the CO oxidation activity, water resistance, and stability of Co3O4 catalysts. Methanol molecules clean the surface hydroxyl groups spontaneously and form hydrophobic entrances in the pores of Co3O4, protecting the internal surface from erosion by water. This study provides new insights for the modification strategies of transition metal oxide catalysts.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Computer Science, Information Systems

Isoga: An Isogeny-Based Quantum-Resist Searchable Encryption Scheme Against Keyword Guessing Attacks

Qing Fan, Debiao He, Jianhua Chen, Cong Peng, Lianhai Wang

Summary: Driven by cloud computing technologies, public-key encryption with keyword search (PEKS) is becoming popular in various fields. However, there are security and privacy issues in the encrypted data search and access processes. This article presents a postquantum searchable encryption scheme named Isoga, which fights against keyword guessing attacks. The scheme utilizes designated tester primitive and quantum resistance of isogeny.

IEEE SYSTEMS JOURNAL (2023)

Article Computer Science, Information Systems

On the Niho Type Locally-APN Power Functions and Their Boomerang Spectrum

Xi Xie, Sihem Mesnager, Nian Li, Debiao He, Xiangyong Zeng

Summary: This article discusses the locally-APN power functions introduced by Blondeau, Canteaut, and Charpin, which generalize APN functions and are potentially more resistant to differential attacks. The study focuses on the Niho type power function F(x) = xs(2m- 1)+1 over the finite field F22m, where s is the multiplicative inverse modulo 2m + 1. The authors prove the locally-APN property of F(x) and determine its differential spectrum through detailed analysis of equation solutions in finite fields. The article highlights that computer experiments confirm the coverage of all Niho type locally-APN power functions for 2 <= m <= 10. Additionally, the boomerang spectrum of F(x) is determined by using its differential spectrum.

IEEE TRANSACTIONS ON INFORMATION THEORY (2023)

Article Computer Science, Hardware & Architecture

An identity-based dynamic group signature scheme for reputation evaluation systems

Haoyang An, Debiao He, Zijian Bao, Cong Peng, Qin Liu

Summary: As reputation evaluation systems become popular on Internet service platforms, there is a growing concern about the presence of malicious merchants who try to disrupt the market environment through unfair practices. To protect the privacy of evaluators and ensure fairness in the evaluation system, this paper proposes an identity-based dynamic group signature scheme for reputation evaluation systems. The scheme allows group members to sign messages anonymously in the name of the group, and the group manager can identify the actual signer in case of disputes. The proposed scheme is secure, efficient, and meets the complex application requirements.

JOURNAL OF SYSTEMS ARCHITECTURE (2023)

Article Engineering, Multidisciplinary

Efficient and Anonymous Cross-Domain Authentication for IIoT Based on Blockchain

Jie Cui, Nan Liu, Qingyang Zhang, Debiao He, Chengjie Gu, Hong Zhong

Summary: The rapid development of the Industrial Internet of Things (IIoT) has improved industrial manufacturing efficiency through intelligent devices and collaboration. However, cross-domain communication in IIoT faces security and privacy issues. To address these issues, we propose an efficient and anonymous cross-domain authentication scheme based on blockchain, which improves authentication efficiency, ensures device anonymity, and combines blockchain and dynamic accumulator technology for fast authentication.

IEEE TRANSACTIONS ON NETWORK SCIENCE AND ENGINEERING (2023)

Article Engineering, Multidisciplinary

A Survey on Redactable Blockchain: Challenges and Opportunities

Tao Ye, Min Luo, Yi Yang, Kim-Kwang Raymond Choo, Debiao He

Summary: This survey article focuses on designing redactable blockchain-based solutions. While immutability is essential for blockchain, it can also be misused to disseminate illicit content and violate privacy regulations like GDPR. The article surveys the existing literature on redactable blockchain, discusses limitations and challenges, and highlights future research opportunities.

IEEE TRANSACTIONS ON NETWORK SCIENCE AND ENGINEERING (2023)

Article Computer Science, Hardware & Architecture

MCPAP: A MSIS-based conditional privacy-preserving authentication protocol for smart grids

Quanrun Li, Debiao He, Haifeng Liu, Xiaoying Jia, Zhichao Yang

Summary: This paper presents a security-enhanced conditional privacy-preserving authentication protocol to address the vulnerability of existing protocols in the smart grid to attacks from quantum computers. The protocol is shown to have superior security in the random oracle model, and its potential utility and efficiency improvement are demonstrated through performance analysis.

JOURNAL OF SYSTEMS ARCHITECTURE (2023)

Article Computer Science, Information Systems

User-Friendly Public-Key Authenticated Encryption With Keyword Search for Industrial Internet of Things

Lang Pu, Chao Lin, Biwen Chen, Debiao He

Summary: The Industrial Internet of Things (IIoT) utilizes physical devices to collect data, which needs to be saved on a cloud server for processing and analysis. Traditional encryption techniques make it difficult to search the generated ciphertext. Public-key encryption with keyword search (PEKS) can provide data encryption and confidential searching, but it is susceptible to internal keyword guessing attacks (IKGAs) due to limited commonly used keywords. A user-friendly public-key authenticated encryption with keyword search (PAEKS) scheme is proposed in this article to address this issue.

IEEE INTERNET OF THINGS JOURNAL (2023)

Article Computer Science, Information Systems

Blockchain-Assisted Secure Data Sharing Protocol With a Dynamic Multiuser Keyword Search in IIoT

Ningbin Yang, Chunming Tang, Debiao He

Summary: The Industrial Internet of Things (IIoT) and cloud computing have seen rapid development, leading to enterprises outsourcing industrial data via the cloud to lower costs and improve efficiency. However, concerns over data security and privacy in cloud outsourcing systems exist. To address these issues, this study proposes a blockchain-assisted secure data-sharing protocol with dynamic multiuser keyword search (DMUKS) in IIoT. The protocol utilizes blockchain techniques to solve the single-key exposure problem and allows for fast certificateless keyword search, dynamic user and key management.

IEEE INTERNET OF THINGS JOURNAL (2023)

Article Engineering, Multidisciplinary

PCNNCEC: Efficient and Privacy-Preserving Convolutional Neural Network Inference Based on Cloud-Edge-Client Collaboration

Jing Wang, Debiao He, Aniello Castiglione, Brij B. Gupta, Marimuthu Karuppiah, Libing Wu

Summary: Deploying CNN inference on resource-constrained devices is a challenge in IIoT, but a new framework called PCNNCEC has been designed to address this issue. The framework enables efficient and privacy-preserving CNN inference through private comparison protocols and secure two-party computation protocols. Experimental results show that PCNNCEC achieves a better tradeoff between latency and throughput compared to other protocols.

IEEE TRANSACTIONS ON NETWORK SCIENCE AND ENGINEERING (2023)

Article Computer Science, Theory & Methods

PERCE: A Permissioned Redactable Credentials Scheme for a Period of Membership

Yang Liu, Debiao He, Qi Feng, Min Luo, Kim-Kwang Raymond Choo

Summary: The anonymous credential has various applications, such as pay-as-you-go strategy in electronic subscription. However, the strategy may not suit non-regular users as they require stricter identity supervision. Identity supervision is a crucial part of an anonymous credential system and needs to be both reasonable and practical in regulating user behavior. The combination of customized k-times and epochs is necessary due to the limitations of existing works. This paper presents a permissioned redactable credentials scheme that allows fine-grained supervision, user control, and user redaction, providing potential utility when evaluated for performance.

IEEE TRANSACTIONS ON INFORMATION FORENSICS AND SECURITY (2023)

Article Computer Science, Information Systems

Exploring Dynamic Task Loading in SGX-Based Distributed Computing

Pengfei Wu, Jianting Ning, Wu Luo, Xinyi Huang, Debiao He

Summary: This article introduces a T-SGX framework based on trusted execution environments, which aims to protect user privacy and ensure system efficiency by dynamically loading enclave objects. All these objects are secretly shared and stored in a verifiably distributed share management system to mitigate exposure of sensitive information. Security analysis shows that T-SGX achieves secure distributed computing without privacy leakage to unauthorized parties. Experimental results demonstrate that T-SGX outperforms a state-of-the-art solution, with 11.9%-29.7% less overhead in SGX-based applications.

IEEE TRANSACTIONS ON SERVICES COMPUTING (2023)

Article Computer Science, Hardware & Architecture

An Efficient Decentralized Identity Management System Based on Range Proof for Social Networks

Xinjie Zhu, Debiao He, Zijian Bao, Min Luo, Cong Peng

Summary: Online social networks (OSNs) are becoming increasingly popular as the demand for online interaction grows. However, current OSNs using centralized identity management systems face issues of single point of failure and privacy data leakage. This paper presents a decentralized identity (DID) protocol to address these challenges, including a range proof protocol for attribute privacy and an extended identity model for identity revocation. The proposed protocol is implemented on the blockchain and analysis shows it provides stronger privacy protection with acceptable computation cost and blockchain overheads.

IEEE OPEN JOURNAL OF THE COMPUTER SOCIETY (2023)

Article Computer Science, Theory & Methods

Efficient Multi-Party EdDSA Signature With Identifiable Aborts and its Applications to Blockchain

Qi Feng, Kang Yang, Mimi Ma, Debiao He

Summary: This paper presents two practical multi-party EdDSA protocols for semi-honest and malicious settings in EdDSA-based blockchain. These protocols eliminate distributed hashing by securely maintaining a global state, making them efficient, identifiable in case of execution abort, and highly compatible. These properties make the protocols ideal for threshold wallets for EdDSA-based cryptocurrency.

IEEE TRANSACTIONS ON INFORMATION FORENSICS AND SECURITY (2023)

Article Computer Science, Hardware & Architecture

LedgerMaze: An Efficient Privacy-Preserving Noninteractive Zero-Knowledge Scheme Over Account-Model Blockchain

Zijian Bao, Debiao He, Wei Wei, Cong Peng, Xinyi Huang

Summary: This paper presents an efficient privacy-preserving scheme called LedgerMaze based on the account-based model. It introduces a cheque mechanism to cut the link between the sender and receiver, ensuring full privacy protection.

IEEE TRANSACTIONS ON COMPUTERS (2023)

Article Engineering, Chemical

r-HGO/MXene composite membrane with enhanced permeability and rejection performance for water treatment

Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu

Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Designing a multifunctional TFC membrane with improved permeability and anti-biofouling performance using zwitterionic, quaternary ammonium, and fluorinated materials

Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma

Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Defect-free asymmetric Matrimid® gas separation membranes using dihydrolevoglucosenone (Cyrene™) as a greener polar aprotic solvent than traditional solvents

Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman

Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Nanofiber composite ultrafiltration membrane functionalized with cross-linked β-cyclodextrin for steroid hormone micropollutant removal

Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer

Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Modeling the flux of volatile fatty acid in a membrane distillation with the effect of pH

Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho

Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Plasma-engineered GQD-inorganic membranes with tunable interactions for ultrahigh-efficiency molecular separations

Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang

Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Water vapor sorption and transport in carbon molecular sieve membranes

Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar

Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Vinyl-addition polynorbornenes with glycerol and diethylene glycol moieties: Synthesis and structure-property study

Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev

Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Hydrogel electrolyte membrane with regulated pore effect to stabilize zinc anode in aqueous zinc-ion batteries

Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun

Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Fabrication of an ultra-thin and ordered SPEEK proton exchange membrane by a Langmuir-Blodgett self-assembly process

Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li

Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Estimating Gas Sorption In Polymeric Membranes From The Molecular Structure: A Machine Learning Based Group Contribution Method For The Non-Equilibrium Lattice Fluid Model (ML-GC-NELF)

Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis

Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Angular vibrations for fouling control during ultrafiltration of microalgae in a spiral wound module

Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang

Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Polyphenol-coated hollow fiber system for energy-efficient dehumidification in air-conditioning

Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes

Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

A facile method to fabricate anti-fouling nanofiltration membrane with aminated lignin

Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang

Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.

JOURNAL OF MEMBRANE SCIENCE (2024)