4.7 Article

Cobalt phosphide decorated on reduced graphene oxide with enhanced microwave absorption performance

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 925, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.166636

Keywords

Transition metal phosphides; Cobalt phosphide; Reduced graphene oxide; Microwave absorption

Funding

  1. Natural Science Foundation of Jiangsu Province [BK20210616, BK20190413]
  2. National Defense Technology Innovation Special Zone Spark Project [2016300TS00911901]
  3. China Postdoctoral Science Foundation [2019M661825]
  4. Jiangsu Key Laboratory of Electrochemical Energy-Storage Technologies [EEST2021-2]
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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In this paper, the authors prepared a novel cobalt phosphide wrapped by reduced graphene oxide (CoP/RGO) by simple hydrothermal and phosphating reaction. The introduction of RGO enhanced the conductive loss and polarization loss of materials, resulting in better microwave absorption performance compared to most reported transition metal phosphate-based absorbents. The CoP/RGO composites demonstrated a minimum reflect loss value of -52.60 dB and a maximum effective absorption bandwidth of 5.04 GHz, making it a promising candidate as an absorber material.
The application of microwave absorbing materials is one of the important means to reduce electromagnetic pollution. Transition metal phosphides as absorbers with high conductivity attract researchers' interest. Therefore, in this paper, the novel cobalt phosphide wrapped by reduced graphene oxide (CoP/RGO) were prepared by simple hydrothermal and phosphating reaction. Meanwhile, the introduction of RGO is beneficial to enhance the conductive loss and polarization loss of materials. Compared with most of the reported transition metal phosphate-based absorbents, CoP/RGO has a better microwave absorption (MA) performance. The minimum reflect loss (RLmin) value can reach - 52.60 dB with 2.05 mm, and the maximum effective absorption bandwidth (EAB, RL < -10 dB) can reach 5.04 GHz at 2.25 mm. The superior MA performance of CoP/RGO composites makes it possible to be a candidate as an absorber. (c) 2022 Elsevier B.V. All rights reserved.

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