Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 8, Pages 3457-3463Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00266
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Funding
- CSIR New Delhi, India
- UGC New Delhi, India
- DST, New Delhi, Government of India [SR/S1/0C-13/2011]
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Synthesis of alpha-oxygenated ketones from styrenes mediated by phenyliodonium diacetate in the presence of molecular oxygen and N-hydroxyphthalimide or N-hydroxybenzotriazole has been described. Addition of carbonyl oxygen at the alpha-position and formation of C-O bond at the beta-position of styrenes was achieved under metal-free conditions. The present method is applicable for wide range of styrenes with a variety of functional groups.
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