4.7 Article

Visible Light-Induced Radical Rearrangement to Construct C-C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 16, Pages 7036-7041

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00735

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Funding

  1. National Natural Science Foundation of China [21232003]

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A highly efficient intramolecular selective aryl migration/desulfonylation of 2-bromo-N-aryl-N-(arenesulfonyl)amide via visible light-induced photoredox catalysis has been accomplished. This approach allows for the construction of a variety of multisubstituted N,2-diarylacetamide under mild reaction conditions.

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