Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 19, Pages 9476-9482Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01776
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Funding
- National Natural Science Foundation of China [21242002]
- Science and Technology Planning Project of Guangdong Province [2015A020211026]
- 100 Young Talents Programme of Guangdong University of Technology [220413506]
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An efficient P-arylation of secondary phosphine oxides has been achieved through the ligand-free copper-catalyzed addition of H-P(O) bonds to in situ generated arynes at room temperature. This transformation provides a straightforward route to the formation of the aryl-P bond with wide functional group compatibility, which produces arylphosphine oxides in up to 99% yield.
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