Carboxylate-Enhanced Rhodium(III)-Catalyzed Aryl C-H Alkylation with Conjugated Alkenes under Mild Conditions

Rhodium(III)-catalyzed C-H bond functionalization for the synthesis of beta-aryl aldehydes and ketones from (hetero)aryl oximes, pyri(mi)dine, as well as pyrazoles and alpha,beta-unsaturated carbonyl compounds has been developed under exceedingly mild reaction conditions. Thus, the versatile rhodium(III) catalysis features high step- and atom-economy, oxidant-free reaction conditions, and broad substrate scope.