Review
Chemistry, Physical
A. Ya Malkin
Summary: This review discusses various studies on shear-induced structure transformation in complex liquids, showing that shearing can lead to the creation of inhomogeneities which may result in phase separation or the formation of new phases. The effects of diffusion-induced phase separation and phase transitions driven by deformation are explored, emphasizing the appearance of regular structures in systems coexisting in different concentrations or phase states.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2021)
Article
Mechanics
Roger Tanner, Shaocong Dai
Summary: An inelastic model of non-Brownian suspension behavior based on the persistence of straining concept of Thompson and Souza Mendes (TSM model) is proposed and compared with experiments and computations in various flow conditions. The model shows good agreement in general and highlights the significant influence of interparticle friction, which has been incorporated via a bootstrap concept.
Article
Mechanics
Peifeng Lin, Rui Wang, Xiao Hu, Zuchao Zhu, Chenlin Zhu
Summary: Experimental research was conducted to investigate the shear-thinning and strain-stiffening behavior of a bidisperse non-colloidal suspension under steady-state shear and oscillatory shear. The results showed the presence of a second shear-thinning behavior when the volume fraction of the particle suspension was between medium and high. The viscosity exhibited a significant particle size dependence at low shear rates, while the dependence became almost nonexistent at high shear rates. Furthermore, the addition of a surfactant of specific concentration confirmed the influence of microstructural changes on the rheological properties of the suspension.
Article
Mechanics
Shivji Prasad Yadav, Atul Sharma, Amit Agrawal
Summary: This paper presents a continuum approach for blood flow simulation inside micro-channels using the finite volume method. The Navier-Stokes equations are solved to obtain velocity and pressure fields, while a particle transport equation is utilized to calculate the hematocrit distribution. The study shows that the proposed approach provides meaningful insights into biophysics with lower computational cost and good agreement with experiments and mesoscale simulations.
Article
Multidisciplinary Sciences
Chih-Tang Liao, An -Jun Liu, Yeng-Long Chen
Summary: This study investigates the flow-induced structural organization in dilute suspensions of red blood cells under confined shear flow. The results show that hydrodynamic interaction between the discoid particles leads to the formation of layered RBC chains and synchronized rotating RBC pairs. The presence of more pairs is observed with increasing volume fraction, and stronger shear stress disrupts the structural arrangements.
Article
Mechanics
Yankai Liu, Qingsong Zhang, Rentai Liu
Summary: The experimental rheology of spherical silica particle suspensions with different particle volume fractions and particle size distributions was determined under different shear rates. The results showed that as the particle volume fraction increased, the shear thinning effect of the suspensions became more apparent. The proposed suspension relative viscosity model effectively predicted the rheology of concentrated suspensions.
Article
Chemistry, Multidisciplinary
Kristine M. Smith, Lilian C. Hsiao
Summary: The study reveals that the cluster-level structural parameters of colloidal thermogelling nanoemulsions in channel flow are influenced by attractive interactions and local shear stress. Specifically, under strong attractions, the largest clusters are affected by confinement and accumulate towards the central axis of the channel, resulting in a volume fraction gradient. Larger gel clusters formed under strong attractions and low shear stresses are susceptible to shear-induced migration, intensifying r-dependent heterogeneity and deviations in flow behavior.
Article
Mechanics
Yuan Lin, Ying Wang, Huaitao Qin, Dingyi Pan, Jiawang Chen
Summary: The study investigates the shear thinning behavior of non-colloidal suspensions with a focus on the effect of particle surface roughness. Two shear thinning phenomena are observed, with the first originating from particle-particle interaction and the second from polymeric solvent. Theoretical models are developed and experimental data support the findings, concluding the impact of roughness on rheological behavior.
Article
Chemistry, Physical
Andrey V. Minakov, Maxim I. Pryazhnikov, Mikhail M. Simunin, Sergey S. Dobrosmyslov, Airaana A. Kuular, Maxim S. Molokeev, Mikhail N. Volochaev, Stanislav V. Khartov, Anton S. Voronin
Summary: We studied the rheological properties of colloidal suspensions based on alumina nanofibers (ANF) with a mass fraction of 0.125-2 wt%. It was found that ANF suspensions exhibit high colloidal stability and have a significant impact on shear viscosity. Non-Newtonian behavior was observed in suspensions with an ANF mass fraction of 0.5 wt%. The results suggest that ANF can be a promising fibrous additive for optimizing the rheological properties of suspensions for various technical purposes.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Mechanics
Yuan Lin, Ying Wang, Zixin Weng, Dingyi Pan, Jiawang Chen
Summary: The presence of bubbles in non-colloidal suspensions significantly affects the shear thinning behavior, with large bubbles enhancing shear thinning and nano-bubbles suppressing it. Additionally, nano-bubbles influence the particle organization behavior, leading to a larger critical strain for the finish of the organization process. Therefore, a degassing process is essential to obtain reliable rheological properties of the two-phase suspension system.
Article
Engineering, Chemical
Kohei Ohie, Taiki Yoshida, Yuji Tasaka, Yuichi Murai
Summary: Flow prediction of complex fluids in a circular pipe was successfully conducted using a velocity-profiling-assisted rheometer. The obtained results demonstrated the high industrial practicality of this method for complex fluids that are outside the application scope of a standard rheometer.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Physical
Arghyadeep Paul, N. R. Aluru
Summary: The study investigates the impact of nonlocal shear stress on gravity-driven isothermal flow in nanochannels under strong confinement. The local average density model is used and the fluid's viscosity kernel is estimated using the sinusoidal transverse force method. A continuum model is proposed to solve the nonlocal hydrodynamics problem and its solutions are qualitatively compared with the results of non-equilibrium molecular dynamics simulations.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Xinhao Li, Zihua Hu, Yang Wang, Changjiang Qin, Zhiyuan Xu, Xiaogao Chen, Shicheng Wu, Yu Tu, Yi Wang
Summary: This paper systematically investigates the shear-thickening and shear-thinning rheological properties of a non-Newtonian fluid composed of polyethylene glycol (PEG) mixed with nano-silica (Nano-SiO2) using dissipative particle dynamics (DPD) method. At low shear rates, the molecular chains of PEG are stretched, resulting in shear-thinning behavior. At high shear rates, increased contact and collision probability between Nano-SiO2 beads leads to particle aggregation and shear-thickening behavior. This study provides insights into the microscopic mechanisms of non-Newtonian fluid rheological behavior and contributes to intelligent applications.
Article
Chemistry, Physical
Yawei Liu, Asaph Widmer-Cooper
Summary: A dissipative particle dynamics (DPD) model is developed to study dynamics in colloidal rod suspensions, where the interaction between solvent particles and rigid linear chains representing individual rods is controlled using a hard repulsive potential. The model accurately predicts diffusion coefficients of single colloids in the DPD solvent, showing good agreement with theoretical calculations based on rod size and including correct Navier-Stokes hydrodynamic interactions. Comparison with experimental measurements of gold nanorod diffusion coefficients validates the model's ability to describe dynamics in real nanorod suspensions and suggests potential for further extension to study colloid dynamics in more complex situations or particle types.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Pharmacology & Pharmacy
William C. Smith, Jungeun Bae, Ying Zhang, Bin Qin, Yan Wang, Darby Kozak, Muhammad Ashraf, Xiaoming Xu
Summary: Variation in injection method can alter the particle state and dissolution rate of triamcinolone acetonide suspensions, potentially impacting drug bioavailability. Study also shows that deflocculated particles dissolve significantly faster than flocculated particles, highlighting the importance of shear-induced changes during injection on drug dissolution and bioavailability.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2021)
Article
Engineering, Chemical
Mariano Michelon, Bruna C. Leopercio, Marcio S. Carvalho
CHEMICAL ENGINEERING SCIENCE
(2020)
Article
Engineering, Chemical
Alireza Mohammad Karim, Wieslaw J. Suszynski, Saswati Pujari, Lorraine F. Francis, Marcio S. Carvalho
CHEMICAL ENGINEERING SCIENCE
(2020)
Article
Engineering, Chemical
Jose F. Roca, Ivan F. Menezes, Marcio S. Carvalho
Summary: The study analyzed the flow characteristics of suspended capsules passing through a planar constricted channel and described the flow of inner and continuous liquid phases using the two-dimensional Navier-Stokes equations. The fluid-structure interaction problem was solved using finite element and immersed boundary methods, revealing a reduction in the mobility of the flow.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Energy & Fuels
Kamila Scheffer, Yves Meheust, Marcio S. Carvalho, Marcos H. P. Mauricio, Sidnei Paciornik
Summary: The efficiency of emulsion injection as an enhanced oil recovery method was studied in a synthetic porous medium, where micro-CT images showed that the oil droplets of the emulsion diverted the water path, mobilizing previously trapped oil ganglia.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2021)
Article
Chemistry, Applied
Yun-Han Huang, Fleur Salmon, Abhijeet Kamble, April Xu Xu, Mariano Michelon, Bruna C. Leopercio, Marcio S. Carvalho, John M. Frostad
Summary: This research characterized polymer-based microcapsules with a sunflower oil core and a gellan gum shell. Analysis of the force-displacement relationship under uniaxial compression emphasized the importance of determining the precise compressive contact point. Two models were presented to describe the data, with the new model showing the advantage of providing an overall modulus for the capsule as well as the modulus of shell material.
FOOD HYDROCOLLOIDS
(2021)
Article
Multidisciplinary Sciences
Bruna C. Leopercio, Mariano Michelon, Marcio S. Carvalho
Summary: This study experimentally investigates the flow of monodispersed gellan gum microcapsules through a constricted capillary tube by measuring the evolution of pressure difference and flow visualization. The maximum pressure difference and capsule deformation for capsules with different diameter and shell thickness were obtained. Mapping the conditions at which the capsule membrane ruptures during the flow and releases its internal phase was also conducted.
SCIENTIFIC REPORTS
(2021)
Article
Energy & Fuels
P. K. P. Reis, M. S. Carvalho
Summary: This study introduces a pore-network model to simulate liquid deposition and its impact in gas-condensate reservoirs. The model considers flow under different gas and liquid saturations, and updates phase properties through PT-flash. Analysis based on coreflooding experiments demonstrated good predictive capability of the model for relative permeability curves.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2021)
Article
Engineering, Chemical
Paulo Roberto C. Mendes Junior, Ivan R. Siqueira, Roney L. Thompson, Marcio S. Carvalho
Summary: This study investigates planar extrudate swell flows of Newtonian liquids with a viscous liquid-gas interface. Results demonstrate that the extrudate swells dramatically as the interfacial viscosity grows, indicating a clear relationship between parameters.
Article
Chemistry, Physical
Tatiana Porto Santos, Mariano Michelon, Marcio Silveira Carvalho, Rosiane Lopes Cunha
Summary: Undesirable oil-in-water emulsions formed during biotechnological processes hinder the recovery of oil-based bioproducts. A thorough understanding of the formation and stability of emulsions, as well as careful selection of antifoaming agents, is crucial to address this issue. While antifoams can promote the formation of oil-phase emulsions, different antifoaming agents may have varying effects on emulsion stability.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Applied
Yun-Han Huang, Xiran Li, Mariano Michelon, Bruna C. Leopercio, Marcio S. Carvalho, John M. Frostad
Summary: This study investigated the aging of edible gellan gum microcapsules, revealing changes in structure, color, stability, and density, as well as precise rheological property measurements. As microcapsules aged, they transitioned from relatively soft and purely elastic to increasingly stiff and viscoelastic, ultimately losing integrity by shedding outer shell and aggregating.
FOOD HYDROCOLLOIDS
(2021)
Article
Engineering, Chemical
Aureliano Agostinho Dias Meirelles, Ana Leticia Rodrigues Costa, Mariano Michelon, Juliane Vigano, Marcio S. Carvalho, Rosiane Lopes Cunha
Summary: The study evaluated the use of glass microfluidic devices to produce emulsion-filled alginate microgels and investigated the effect of process variables on microgels size and polydispersity. Monodisperse particle size distribution of the microgels was observed, with size influenced by the viscosity of the O/W emulsion and the phases flow rates. These results demonstrate the potential of microfluidic processes for encapsulating lipophilic compounds in microgels.
JOURNAL OF FOOD ENGINEERING
(2022)
Article
Nanoscience & Nanotechnology
Bruna C. Leopercio, Sergio Ribeiro, Frederico Gomes, Mariano Michelon, Marcio S. Carvalho
Summary: Magnetized microcapsules produced by microfluidics are studied for their response to external magnetic fields, with the response found to be dependent on the concentration of the ferrofluid, capsule diameter, and shell thickness.
MICROFLUIDICS AND NANOFLUIDICS
(2021)
Article
Mechanics
Alireza Mohammad Karim, Wieslaw J. Suszynski, Saswati Pujari, Lorraine F. Francis, Marcio S. Carvalho
Summary: The rheological characteristics of liquids play a critical role in the flow near dynamic contact lines. Effects of shear thinning and extensional thickening on liquid contact line dynamics in the curtain coating of polymer solutions were experimentally studied. Critical web speeds for heel formation and air entrainment were compared to behavior of a Newtonian liquid, with contact line dynamics described using dimensionless parameters.
Article
Chemistry, Physical
Talita Coffler Botti, Anthony Hutin, Erick Quintella, Marcio S. Carvalho
Summary: Several studies have investigated the relationship between the rheological properties of oil-water interfaces and the drainage time of a thin oil film between two aqueous drops. The results show that the properties of the structure formed at the oil-water interface are related to the absence of droplet coalescence. At low surfactant concentrations, the interface is weakly elastic and coalescence always occurs. At higher surfactant concentrations, a solid-like film forms at the interface, preventing further coalescence.
Article
Energy & Fuels
Willer P. Goncalves, Danmer M. Quinones, Abelardo B. Barreto Jr, Marcio S. Carvalho
Summary: Traditionally, oil well tests rely on pressure transient analysis (PTA) based on isothermal flow models. With the availability of accurate temperature records, non-isothermal models are now used for temperature transient analysis (TTA) to better characterize reservoir parameters. This study develops a numerical simulator that incorporates a non-isothermal model for well test analysis and solves the inverse problem of reservoir parameter characterization using multivariable optimization methods.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Mechanics
Mateus C. Guimaraes, Fernando T. Pinho, Carlos B. da Silva
Summary: A new theory is proposed to describe the conformation state of polymer chains in free turbulent shear flows of viscoelastic fluids. The theory shows the existence of minimum and maximum solvent dissipation reduction asymptotes and four different polymer deformation regimes, based on self-similarity arguments and new scaling relations for the turbulent flux of conformation tensor. In addition, analytical solutions for the self-similar transverse profiles of the conformation tensor components are obtained. The theory is validated through excellent agreement with direct numerical simulations employing the FENE-P rheological model.
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS
(2024)