Journal
CATALYSIS COMMUNICATIONS
Volume 72, Issue -, Pages 121-126Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.09.029
Keywords
Selective catalytic reduction; Arsenic; V2O5-WO3/TiO2; Poisoning mechanism
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Funding
- National Natural Science Foundation of China [51274263, 51204220]
- Chongqing Natural Science Foundation [cstc2013jjB0035]
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The performance impact and poisoning mechanism of arsenic on commercial V2O5-WO3/TiO2 SCR catalysts were studied. XRD, BET, FT-IR and XPS were used to characterize its physical-chemical properties. The results showed that As2O3 would be adsorbed on the catalyst surface and most oxidized by surface chemisorption oxygen to ultimately form As2O5. Lattice oxygen of V2O5 may also be transformed into surface sorption oxygen to oxidize As2O3, but tungsten and titanium species showed no changes in this progress. The creating As2O5 formed dense layer on catalyst surface, preventing NH3 adsorption and active sites recovery, which finally resulted in catalytic deactivation. (C) 2015 Elsevier B.V. All rights reserved.
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