Journal
CATALYSIS COMMUNICATIONS
Volume 60, Issue -, Pages 120-123Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2014.11.025
Keywords
Cobalt; Amides; Nitriles; Homogeneous catalysis; Selective conversions
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Funding
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2013R1A1A1061399]
- research grant of the Chungbuk National University
- National Research Foundation of Korea [2013R1A1A1061399] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A novel cobalt/nitrophenolate complex has been synthesized, characterized and studied for their catalytic activities. Conversion of aldoximes to nitriles can be performed via in situ conditions from cobalt(II) acetate and 2,4-dinitrophenol. The rearrangement of aldoximes to amides via cobalt(II) acetate and 2-nitro-1-naphthol has also been demonstrated. A complete reversal of transformation was accomplished by modifying the cobalt salt and careful choice of both the nitrophenol ligand and reaction conditions. (C) 2014 Elsevier B.V. All rights reserved.
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