Article
Chemistry, Multidisciplinary
Yucheng Dong, Yutai Wu, Xuyun Wang, Hui Wang, Jianwei Ren, Peng Wang, Lei Pan, Guoqiang Wang, Rongfang Wang
Summary: In this study, a biomimicry-inspired design of Ni3N/FeNi3N/NF nanoarrays with a fish scale-like structure was demonstrated, which allowed for rapid infiltration of aqueous solution within 60 ms and a 169 degrees bubble contact angle. The optimized Ni3N/FeNi3N/NF sample exhibited catalytic activity with low overpotentials for both the hydrogen evolution reaction (HER) and the anodic-coupled urea oxidation reaction (UOR). Furthermore, the rapid bubble extraction within the nanoarrays ensured excellent cycling stability for HER over 100 hours at a current density of 50 mA cm(-2). The scale-up experiment indicated the potential for industrialized application of the prepared electrocatalysts.
Article
Chemistry, Physical
Rui Yang, Xuefeng Bai, Xiangfeng Guo, Kun Song, Lihua Jia, Xiaoshuang Chen, Jun Wang
Summary: The rational construction of hierarchical electrode materials using porous Ni/C substrate and NiCo2O4 nanostructure arrays is proposed in this paper. The as-constructed electrode exhibits improved electrochemical properties and energy density, indicating its promising prospects in electrochemical applications.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Mechanical
Yansong Li, Dayong Hu, Zhenyu Yang
Summary: A novel bio-inspired multicell tube (UCGS) mimicking the structure of glass sponge was fabricated and analyzed for its crash worthiness. The results showed that UCGS had higher specific energy absorption (SEA) than conventional multi-cell tubes and other bio-inspired tubes. The influence of geometric parameters and hierarchical designs on the energy absorption performance were investigated. A theoretical model was proposed to predict the mean crushing force and was in good agreement with the numerical results. This study provides insights for designing and optimizing energy absorbers with high performance.
INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES
(2023)
Article
Chemistry, Physical
Bo Zhong, Panyong Kuang, Linxi Wang, Jiaguo Yu
Summary: Hydrogen is considered as the most promising alternative energy carrier for the future energy system. Water electrolysis, as an innovative method for green hydrogen production, is hindered by the slow kinetics of the oxygen evolution reaction (OER). The development of efficient and robust electrocatalysts for OER is crucial for promoting the hydrogen industry.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Analytical
Jongmin Lee, Soosung Kim, Heungjoo Shin
Summary: This study develops a highly sensitive electrochemical heavy metal sensor based on hierarchical porous carbon electrodes, which can detect Cd(II) and Pb(II) at low concentrations. The hierarchical porous structure and sub-micrometer edges of the nanoporous carbon electrodes contribute to the enhanced performance of the sensor.
Article
Chemistry, Multidisciplinary
Pengzhou Mu, Shu Zhang, Huanrui Zhang, Jiedong Li, Zhi Liu, Shanmu Dong, Guanglei Cui
Summary: This study reports an aqueous-oil binary solution-based blend (AOB) binder with a spidroin-like hierarchical structure, which can tolerate the huge volume changes of silicon-based electrodes. The AOB binder has high tensile strength and elasticity, as well as strong electrode adhesion, which significantly stabilizes the silicon-based electrode structure and extends electrode cycle life.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Fei Xiao, Longjian Li, Wenzhi Cui, Yuqi Zhang, Chen Zhan, Wanyun Xiao
Summary: This study investigates the effect of catalyst structure on the performance of hydrogen evolution reaction (HER) in alkaline water electrolysis. Aligned porous nickel electrodes (APNEs) with smaller pore size, larger electrocatalytic activity area, and stronger bubble removal ability outperform isotropic porous structures. The particle size of nickel powders used to prepare APNEs also plays a dominant role in determining the structure and performance of the electrodes. The results demonstrate that smaller particles lead to wider pores and thinner walls, resulting in excellent HER performance.
JOURNAL OF POWER SOURCES
(2023)
Article
Engineering, Manufacturing
Guanjin Li, Xinyu Dong, Ambrose Raphael Chuan, Beng Wah Chua, Li Tao, Wei Zhai
Summary: Inspired by the unique hierarchical porous structure of cacti, researchers have developed a new material and an efficient oil-water separation technique. The material shows excellent oil absorption and retention capabilities, and can be reused.
VIRTUAL AND PHYSICAL PROTOTYPING
(2023)
Article
Chemistry, Multidisciplinary
Wei Guo, Yuanlan Liu, Yinghui Sun, Yawen Wang, Wei Qin, Bo Zhao, Zhiqiang Liang, Lin Jiang
Summary: Inspired by natural forest light absorption strategies, researchers have successfully constructed a hierarchical plasmonic superstructure composed of vertical TiO2 pillar arrays, nanorod arrays, and numerous plasmonic Au nanoparticles to achieve higher nitrogen photo-fixation photocatalytic activity. This forest-like plasmonic superstructure effectively absorbs light through surface plasmonic resonance effects of Au nanoparticles and multiple light scattering.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Fei Fei Dai, Yan Xue Xue, Ding Ling Gao, Yu Xiang Liu, Jian Hua Chen, Qiao Jing Lin, Wei Wei Lin, Qian Yang
Summary: Research shows that the porous CuMoO4@Co3O4 nanosheet electrocatalyst, which is prepared by hydrothermal reactions and the impregnation method, exhibits excellent electrocatalytic activity and durability in the cathodic hydrogen evolution reaction (HER) and the anodic oxygen evolution reaction (OER) under alkaline conditions. The synergistic effect between CuMoO4 and Co3O4, as well as the structure of the porous nanosheets, contributes to the catalytic activity of CuMoO4@Co3O4.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Physical
Chunyan Wang, Mingqiang Wang, Li Liu, Yudong Huang
Summary: A novel material CVO shows promising performance as a cathode material in ZIBs, with high capacity, good rate capability, and long cycling life. The strategy of using three-dimensional carbon-coated metallic oxides opens up opportunities for the development of high-performance aqueous rechargeable zinc-ion batteries.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Lu Liu, Xing Yu, Weiwei Zhang, Qingyun Lv, Long Hou, Yves Fautrelle, Zhongming Ren, Guanghui Cao, Xionggang Lu, Xi Li
Summary: The sluggish charge transport kinetics in all-solid-state supercapacitors can be improved by designing open hierarchical porous electrodes. In this study, a template-directed strategy was used to fabricate open hierarchical porous Ni-Co-Zn-P nanoplate arrays. The porous conductive NiZn alloy nanoplate arrays were first designed as the template using a strong magnetic field-assisted electrodeposition. The resulting electrode showed higher specific capacitance, enhanced rate capability, and remarkable cycling stability.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Yu-Shi Shen, Xing Zhou, Shuai You, Lu-Chan Gong, Jun Wang, Tao Chen, Wei-Guo Zhao, Xiao-Hui Yao, Dong-Yang Zhang
Summary: Inspired by the structure of natural wood, a cellulose-based bionic microfluidic biocatalytic reactor was developed for the continuous fluid catalytic conversion of polydatin to resveratrol. The reactor, with vertically aligned channels and a porous inner wall, showed high catalytic activity (98.69% treatment efficiency) and excellent stability (maintain a conversion rate of more than 90% within 15 days) due to the unidirectionally aligned channels and porous inner wall. The reactor has great potential for simplifying industrial production and has broad application prospects for catalytic reactions.
Article
Engineering, Environmental
Rui He, Tuo Lu, Nengneng Xu, Guicheng Liu, Yanxing Zhang, Jinli Qiao
Summary: This study reports a new synthetic method for designing multi-functional electrocatalysts with controllable nanostructures for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). The designed material exhibits high tri-functional catalytic activities and can be used in zinc-air batteries and water splitting devices with high power density and low cell voltage. This work provides a promising approach for the development of efficient and low-cost carbon-supported phosphate tri-functional electrodes.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Praphaiphon Phonsuksawang, Suchunya Wongprasod, Nantawat Tanapongpisit, Arreerat Jiamprasertboon, Kamonwad Ngamchuea, Wittawat Saenrang, Theeranun Siritanon
Summary: This research focuses on preparing high mass loading hierarchical nickel and cobalt sulfides binder-free electrodes using simple techniques. The obtained electrodes exhibit good electrochemical properties with a maximum areal capacitance of 2.16 F/cm2 at 10 mA/cm2, although the electrode made of NiCo2(CO3)1.5(OH)3 has lower rate capability and slightly lower cycle stability.
MATERIALS CHEMISTRY AND PHYSICS
(2024)