4.8 Article

Triboelectric Potential Powered High- Performance Organic Transistor Array

Journal

ACS NANO
Volume 16, Issue 11, Pages 19199-19209

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.2c08420

Keywords

field effect transistor; triboelectric potential; high performance; organic semiconductor; logic device

Funding

  1. National Key Research and Development Program of China [2021YFB3200304]
  2. National Natural Science Foundation of China [52073031, 61975241]
  3. Beijing Nova Program [Z191100001119047, Z211100002121148]
  4. Fundamental Research Funds for the Central Universities [E0EG6801X2]
  5. Huxiang Youth Talent Program of Hunan Province [2020RC3010]
  6. Hundred Talents Program of the Chinese Academy of Sciences

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This article introduces a friction-controlled transistor array composed of a friction nano-generator and C8-BTBT-PS transistors. It exhibits record-breaking high performance and provides an effective research and development platform for mechanically-driven electronic terminals, intelligent systems, and robotic skin applications.
Triboelectric potential gated transistors have inspired various applications toward mechanical behavior controlled logic circuits, multifunctional sensors, artificial sensory neurons, etc. Their rapid development urgently calls for high-performance devices and corresponding figure of merits to standardize the tribotronic gating properties. Organic semiconductors paired with solution processability promise low-cost manufacture of high-performance tribotronic tran-sistor devices/arrays. Here, we demonstrate a record high-performance tribotronic transistor array composed of an integrated triboelectric nanogenerator (TENG) and a large-area device array of C8-BTBT-PS transistors. The working mechanism of effective triboelectric potential gating is elaborately explained from the aspect of conjugated energy bands of the contact-electrification mediums and organic semiconductors. Driven by the triboelectric potential, the tribotronic transistor shows superior properties of record high current on/off ratios (>108), a steep subthreshold swing (29.89 mu m/dec), high stability, and excellent reproducibility. Moreover, tribotronic logic devices modulated by mechanical displacement have also been demonstrated with good stability and a high gain of 1260 V/mm. The demonstrated large-area tribotronic transistor array of organic semiconductor exhibits record high performance and offers an effective R&D platform for mechano-driven electronic terminals, interactive intelligent system, artificial robotic skin, etc.

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