Review
Chemistry, Physical
Pritam Kumar Dikshit, Jatin Kumar, Amit K. Das, Soumi Sadhu, Sunita Sharma, Swati Singh, Piyush Kumar Gupta, Beom Soo Kim
Summary: In the past decade, nanotechnology research has seen significant growth due to its applications in fields such as food safety, transportation, and environmental science. The unique properties of nanomaterials make them suitable for a wide range of functions, with green synthesis methods being particularly desirable. Experimentation with plants and microorganisms is being conducted to optimize the production process in a cost-effective and environmentally friendly manner.
Article
Materials Science, Ceramics
N. R. Khalid, Areeg Gull, Faisal Ali, M. B. Tahir, T. Iqbal, M. Rafique, Mohammad A. Assiri, Muhammad Imran, Meshal Alzaid
Summary: The pollution of industrial wastewater with different dyes has become a severe issue, and the synthesis of green electrode materials has great potential in this field. This study successfully synthesized cobalt oxide nano-materials using green chili and sunflower seeds extracts, and conducted various tests to evaluate their performance. The results showed excellent photocatalytic and electrochemical properties, providing a new solution for water treatment and energy storage devices.
CERAMICS INTERNATIONAL
(2022)
Article
Biochemistry & Molecular Biology
Krishnan Meenambigai, Ranganathan Kokila, Kandasamy Chandhirasekar, Ayyavu Thendralmanikandan, Durairaj Kaliannan, Kalibulla Syed Ibrahim, Shobana Kumar, Wenchao Liu, Balamuralikrishnan Balasubramanian, Arjunan Nareshkumar
Summary: The study synthesized selenium nanoparticles using Nilgirianthus ciliatus leaf extracts, with significant antimicrobial and insecticidal activities. Characterization through various techniques and molecular docking studies provided insights into the mechanistic approach.
BIOLOGICAL TRACE ELEMENT RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Fuad Ameen
Summary: Bi-metallic Ag-Cu nanoparticles synthesized using Aspergillus terreus-mediated method exhibited high antioxidant and antibacterial activities. The synthesis conditions were optimized using response surface methodology, leading to an improvement in nanoparticle yield.
APPLIED SCIENCES-BASEL
(2022)
Article
Materials Science, Multidisciplinary
Anil Tevfik Kocer, Didem Ozcimen
Summary: Silver, iron-oxide, and copper-oxide nanoparticles were synthesized from Botryococcus braunii extracts, and their properties were studied. The optimal synthesis conditions were determined, and the produced nanoparticles showed antibacterial effects against various bacteria. This study demonstrates the potential of B. braunii as a source for nanoparticle synthesis, and the results provide guidance for future applications of antibacterial nanoparticles.
Article
Chemistry, Multidisciplinary
Sivasankar Kulandaivel, Chia-Her Lin, Yi-Chun Yeh
Summary: The study reported a bi-metal organic framework, MOF-919 (Fe-Cu), capable of bifunctional-enzyme mimicking activity with oxidase- and peroxidase-like activities. A simple epinephrine colorimetric biosensor was developed based on this MOF, with a broad linear range and low detection limit, demonstrating its potential application as new nanosensors.
CHEMICAL COMMUNICATIONS
(2022)
Review
Chemistry, Multidisciplinary
Pranali Kurhade, Shyam Kodape, Rohit Choudhury
Summary: Nanotechnology offers advanced solutions to modern issues, allowing for more sustainable products and processes. Green synthesis of metal nanoparticles is non-toxic, high-yield, and influenced by the diverse chemical components of biological extracts. This method shows potential applications across various fields and demonstrates a unique sustainability impact over the environment.
Article
Chemistry, Inorganic & Nuclear
Salem S. Salem, Moustafa M. G. Fouda, Amr Fouda, Mohamed A. Awad, Ebtesam M. Al-Olayan, Ahmed A. Allam, Tharwat I. Shaheen
Summary: Anopheles mosquitoes pose a serious threat to human life by transmitting malaria, and Selenium nanoparticles (Se-NPs) synthesized by Penicillium corylophilum have shown antibacterial properties against both Gram +Ve and Gram -Ve bacteria, as well as high toxicity towards cancer cells. Additionally, Se-NPs exhibit larvicidal activity against Anopheles mosquitoes.
JOURNAL OF CLUSTER SCIENCE
(2021)
Article
Environmental Sciences
Utaiyachandran Manojkumar, Durairaj Kaliannan, Venkatesan Srinivasan, Balamuralikrishnan Balasubramanian, Hesam Kamyab, Zainab Haider Mussa, Jayanthi Palaniyappan, Mohsen Mesbah, Shreeshivadasan Chelliapan, Senthilkumar Palaninaicker
Summary: Green synthesis of zinc oxide nanoparticles (ZnO NPs) using plant leaf extracts has been successfully carried out in this study. The synthesized BO-ZnO NPs exhibited photocatalytic and antibacterial activities. Characterization of BO-ZnO NPs was performed using various instrumental techniques, confirming the formation of nanoparticles with a hexagonal wurtzite structure and an average size of 52 nm. The presence of hydroxyl, carbonyl, carboxylic, and phenol groups was also confirmed.
Article
Spectroscopy
E. Proniewicz
Summary: This work discusses the synthesis and characterization of biologically important nanostructures of metals (AgNPs, AuNPs, and PtNPs) and metal oxides (Cu2ONPs, CuONSs, gamma-Fe2O3NPs, ZnONPs, ZnONPs-GS, anatase-TiO2NPs, and rutile-TiO2NPs). The adsorption of a peptide (bombesin, BN) onto these nanostructures and its influence on peptide geometry and biological activity were studied using surface-enhanced Raman scattering spectroscopy (SERS). The SERS enhancement factor was determined for each metallic surface.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Review
Biochemistry & Molecular Biology
Orest Kuntyi, Galyna Zozulya, Andriy Kytsya
Summary: The sonoelectrochemical method is a green synthesis technique for metallic nanoparticles, characterized by manufacturability and environmental friendliness, with the ability to control the geometry of nanoparticles. Ultrasound increases mass transfer and radical formation, accelerating the nucleation and growth of nanoparticles. Combining electrolysis and ultrasound, this hybrid method has attracted significant interest from researchers in the past two decades.
BIOINORGANIC CHEMISTRY AND APPLICATIONS
(2021)
Review
Chemistry, Medicinal
Shabaaz J. P. Begum, S. Pratibha, Janhvi M. Rawat, Divya Venugopal, Prashant Sahu, Abhilash Gowda, Kamal A. Qureshi, Mariusz Jaremko
Summary: Biogenic synthesis of metallic nanoparticles is more environmentally friendly and versatile than physical and chemical synthesis, with plants being more suitable as reducing agents. Metallic nanoparticles have a wide range of bioactivity and can serve as ideal antimicrobial agents.
Article
Environmental Sciences
Julia C. Diel, Dison S. P. Franco, Andrei Igansi, Tito R. S. Cadaval Jr, Hercules A. Pereira, Isaac dos S. Nunes, Charles W. Basso, Maria do Carmo M. Alves, Jonder Morais, Diana Pinto, Guilherme L. Dotto
Summary: In this study, multi-walled carbon nanotubes (MWCNTs) were used as support material for metallic nanoparticles produced by green synthesis, with pecan leaves as a reducing agent. The synthesized materials showed favorable adsorption of glyphosate, with iron nanoparticles impregnated MWCNTs having the highest adsorption capacity and removal percentage. This study demonstrated the potential for advanced adsorbents for glyphosate removal through green synthesis.
Article
Microbiology
Mohamed A. Awad, Ahmed M. Eid, Tarek M. Y. Elsheikh, Zarraq E. Al-Faifi, Nadia Saad, Mahmoud H. Sultan, Samy Selim, Areej A. Al-Khalaf, Amr Fouda
Summary: Silver nanoparticles (Ag-NPs) were successfully synthesized using metabolites of Aspergillus niger F2, and their high toxicity against Aedes aegypti larvae, pupae, and adults, as well as their ovicidal activity, were confirmed. These findings demonstrate the significant potential of biosynthesized Ag-NPs for the control of Aedes aegypti at low concentrations.
Review
Biochemistry & Molecular Biology
Salem S. Salem, Amr Fouda
Summary: Green synthesis of nanoparticles using biological methods offers advantages such as avoiding high pressure, temperature, toxic substances, and improving productivity and purity, making it environmentally friendly, clean, safe, cost-effective, and easy to use.
BIOLOGICAL TRACE ELEMENT RESEARCH
(2021)
Article
Energy & Fuels
Selvaraju Sivamani, Prema Binnal, Capili Roy, Amal Al Khaldi, Fatema Al Hamar, J. Prakash Maran, N. Sivarajasekar, G. Rajeshkumar, Naif Abdullah Al-Dhabi, Ponmurugan Karuppiah
Summary: The present study aims to optimize the recovery of pectin from Persea americana peel using statistical and non-statistical methods. The results show that the non-statistical method accurately predicts the pectin recovery. Structural analysis reveals that the recovered pectin from Persea americana peel has good quality and can be used as a food ingredient.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Cell Biology
Gokul Sudhakaran, Pandurangan Prathap, Ajay Guru, Ravi Rajesh, Sruthy Sathish, Thirumurthy Madhavan, Mariadhas Arasu, Naif A. Al-Dhabi, Ki Choon Choi, Pushparathinam Gopinath, Jesu Arockiaraj
Summary: This study found that Nimbin and its analogs N2 and N3 have anti-inflammatory properties and can promote wound healing and reduce reactive oxygen species levels. N2 showed better activity in docking with anti-inflammatory and antioxidant proteins.
CELL BIOLOGY INTERNATIONAL
(2022)
Article
Chemistry, Physical
Natarajan Arumugam, Abdulrahman Almansour, Raju Suresh Kumar, Saied M. Soliman, E. Viswanathan, Karthikeyan Perumal, Gnanavel Angamuthu, Ponmurugan Karuppiah, Naif Abdullah Al-Dhabi
Summary: A novel class of structurally diverse azetidinone integrated spirooxindolopyrrolidine hetero-cyclic hybrid was successfully synthesized, showing significant activity against ESBL producing E. coli strains.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Biochemistry & Molecular Biology
Mohandass Kaviya, Balamuralikrishnan Balasubramanian, Kathirvel Bharathi, Arunkumar Malaisamy, Naif Abdullah Al-Dhabi, Valan Arasu Mariadhas, Arumugam Vijaya Anand, Wenchao Liu
Summary: The present study focused on the phytochemical analysis of different parts of the medicinal herb Boerhavia diffusa using various solvents. The decoction extraction method performed well in most qualitative and quantitative tests, as well as the DPPH assay. The aqueous extract showed good results in the FRAP assay and ABTS assay. The ethanol extract of B. diffusa roots inhibited the growth of Pseudomonas aeruginosa and Staphylococcus aureus in the antimicrobial test.
Article
Green & Sustainable Science & Technology
Dharman Kalaimurugan, Balasubramanian Balamuralikrishnan, Rasiravathanahalli Kaveriyappan Govindarajan, Naif Abdullah Al-Dhabi, Mariadhas Valan Arasu, Chithravel Vadivalagan, Srinivasan Venkatesan, Hesam Kamyab, Shreeshivadasan Chelliapan, Chartchai Khanongnuch
Summary: This study aimed to extract a novel biosurfactant molecule from Bacillus safensis YKS2, which is a biodegradation accelerator that improves bioavailability and facilitates degradation by microorganisms. An efficient biosurfactant-producing strain, Bacillus safensis YKS2, was selected from four oil-degrading strains isolated from a soil sample using various tests. The bacteria culture conditions were optimized, and the biosurfactant was characterized using different analysis techniques. The wastewater treatment efficiency was high, and metagenomics analysis showed a decrease in microbial load. The results suggest that B. safensis YKS2 has potential benefits in wastewater remediation.
Article
Multidisciplinary Sciences
Fuad H. Rzayev, Eldar K. Gasimov, Nargiz J. Agayeva, Asif A. Manafov, Chingiz A. Mamedov, Ismat S. Ahmadov, Ameer Khusro, Mariadhas Valan Arasu, Muhammad Umar Khayam Sahibzada, Naif Abdullah Al-Dhabi, Ki Choon Choi
Summary: The study investigated the bioaccumulation of aluminium nanoparticles in aquatic plants, freshwater snails, and molluscs, revealing adverse effects on these organisms. The findings underscore the importance of minimizing the release of toxic nanoparticles into freshwater and marine environments.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Multidisciplinary Sciences
Fatima Zohra Djebbah, Naif Abdullah Al-Dhabi, Mariadhas Valan Arasu, Larbi Belyagoubi, Farid Kherbouche, Djamel Eddine Abdelouahid, Balasubramani Ravindran
Summary: This study isolated a potential antimicrobial and antioxidant Streptomyces strain from cave areas in Algeria. The strain showed significant antimicrobial activity against Staphylococcus aureus and Bacillus subtilis, as well as good antioxidant capacity. The identified metabolites in the crude extract have important biotechnological and medical applications.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Pharmacology & Pharmacy
Subramanian Mutheeswaran, Antony Mariappan, Kamaraj Ragavendran, Vedapuri Porchezhiyan, Poovan Elankani, Naif Abdullah Al-Dhabi, Mariadhas Valan Arasu, Savarimuthu Ignacimuthu
Summary: An ethnobotanical survey was conducted in Sathuragiri hills, India, revealing 139 medicinally useful plant species. The study highlighted the importance of Fabaceae, Euphorbiaceae, and Apocynaceae families, which contained numerous important medicinal plants. Dermatological ailments, gastrointestinal problems, joint pain, fever, and poisonous bites were among the important diseases treated by these species. The study emphasized the need for conservation of these medicinal plants and local knowledge.
ADVANCES IN TRADITIONAL MEDICINE
(2023)
Article
Biochemistry & Molecular Biology
Kaliannan Durairaj, Balamuralikrishnan Balasubramanian, Vijaya Anand Arumugam, Murugesh Easwaran, Sungkwon Park, Utthapon Issara, Karthika Pushparaj, Naif Abdullah Al-Dhabi, Mariadhas Valan Arasu, Wen-Chao Liu, Amin Mousavi Khaneghah
Summary: The limitations of graft material and surgical sites in bone defects treatment pose a challenge in bone tissue engineering. Phytocompounds have a significant impact on bone metabolism. In this study, a biocompatible hydrogel composed of chitosan and methylcellulose encapsulated with veratric acid was investigated for bone defect treatment. The hydrogel showed compatibility with mesenchymal stem cells and promoted osteogenic differentiation, indicating its potential as a therapeutic alternative for bone regeneration.
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
(2023)
Article
Anatomy & Morphology
Gokul Sudhakaran, Ravi Rajesh, Ajay Guru, Mariadhas Valan Arasu, Pusparathinam Gopinath, Jesu Arockiaraj
Summary: The aim of this study was to evaluate the anti-adipogenic activity of semi-natural Nimbin analogs, N5 and N7, on zebrafish larvae induced with oxidative stress due to a high-fat diet. The results showed that N5 and N7 suppressed adipogenesis, reduced intracellular ROS and superoxide anion production, and restored glutathione levels. Additionally, they lowered total TC and TG levels, prevented inflammatory macrophage build-up, and enhanced glucose absorption.
Article
Environmental Sciences
Rengasamy Sathya, Mariadhas Valan Arasu, Naif Abdullah Al-Dhabi, Ponnuswamy Vijayaraghavan, Soundharrajan Ilavenil, T. S. Rejiniemon
Summary: Water is vital for all living things on earth, and protecting water from pollution has become an essential need due to rapid urbanization and industrialization. Traditional methods of water treatment have drawbacks, but biological methods have gained more attention in recent years. This paper aims to review the role of bio-remedies in wastewater treatment, along with their advantages and limitations.
Article
Multidisciplinary Sciences
Antonia Ho, Richard Orton, Rachel Tayler, Patawee Asamaphan, Vanessa Herder, Chris Davis, Lily Tong, Katherine Smollett, Maria Manali, Jay Allan, Konrad Rawlik, Sarah E. McDonald, Elen Vink, Louisa Pollock, Louise Gannon, Clair Evans, Jim McMenamin, Kirsty Roy, Kimberly Marsh, Titus Divala, Matthew T. G. Holden, Michael Lockhart, David Yirrell, Sandra Currie, Maureen O'Leary, David Henderson, Samantha J. Shepherd, Celia Jackson, Rory Gunson, Alasdair MacLean, Neil McInnes, Amanda Bradley-Stewart, Richard Battle, Jill A. Hollenbach, Paul Henderson, Miranda Odam, Primrose Chikowore, Wilna Oosthuyzen, Meera Chand, Melissa Shea Hamilton, Diego Estrada-Rivadeneyra, Michael Levin, Nikos Avramidis, Erola Pairo-Castineira, Veronique Vitart, Craig Wilkie, Massimo Palmarini, Surajit Ray, David L. Robertson, Ana da Silva Filipe, Brian J. Willett, Judith Breuer, Malcolm G. Semple, David Turner, J. Kenneth Baillie, Emma C. Thomson
Summary: An investigation found a possible association between AAV2 infection and host genetics in a recent outbreak of acute hepatitis in children in Scotland. The study used various methods to detect AAV2 infection in plasma and liver samples, and identified pathological features related to the virus in liver biopsy samples.
Review
Infectious Diseases
Juhi Puthukulangara Jaison, Balamuralikrishnan Balasubramanian, Jaya Gangwar, Nilina James, Manikantan Pappuswamy, Arumugam Vijaya Anand, Naif Abdullah Al-Dhabi, Mariadhas Valan Arasu, Wen-Chao Liu, Joseph Kadanthottu Sebastian
Summary: The Asteraceae family, with its rich phytochemicals, is widely used for traditional and medicinal purposes. These plants have found applications in various biological fields and nanotechnology. The synthesized nanoparticles from Asteraceae plants are stable, inexpensive, non-toxic, and eco-friendly, and have extensive applications in antibacterial, antifungal, antioxidant, anticancer, antidiabetic, and photocatalytic activities. This review provides an opportunity to understand the recent trend in green synthesis of advanced nanoparticles and discusses the extraction methods, synthesis, characterization, and potential applications of Asteraceae-mediated nanoparticles for human welfare. Constraints and future prospects for green synthesis of nanoparticles from Asteraceae family are summarized.
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)