Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 215, Issue -, Pages 176-184Publisher
ELSEVIER
DOI: 10.1016/j.molliq.2015.12.029
Keywords
Ionic liquid solvents; Activity coefficients at infinite dilution; Gas-to-ionic liquid partition coefficients; Water-to-ionic liquid partition coefficients
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Infinite dilution activity coefficients and gas-to-liquid partition coefficients are reported for 47 and 45 organic probe molecules dissolved in 1-hexylquinuclidinium bis(trifluoromethylsulfonyl)imide ([Quin6](+)[Tf2N](-)) and 1-octylquinuclidinium bis(trifluoromethylsulfonyl)imide ([Quin8](+)[Tf2N](-)), respectively, as determined by inverse gas chromatography in the temperature range of 313 K to 353 K. The measured partition coefficient data were converted to water-to-liquid partition coefficients using standard thermodynamic relationships and published gas-to-water partition coefficient data. Both sets of calculated partition coefficient data for each ionic liquid solvent were analyzed in terms of the Abraham general solvation model. Mathematical correlations derived from the Abraham model described the measured partition coefficient data to within 0.14 or fewer log units. (C) 2015 Elsevier B.V. All rights reserved.
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