Ensemble effect for single-atom, small cluster and nanoparticle catalysts

Number of surface sites and turnover frequencies for oxide catalysts

(2022) Israel E. Wachs   JOURNAL OF CATALYSIS

Few-Atom Pt Ensembles Enable Efficient Catalytic Cyclohexane Dehydrogenation for Hydrogen Production

(2022) Yuchen Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The concept of active site in heterogeneous catalysis

(2022) Charlotte Vogt et al.   Nature Reviews Chemistry

Fully exposed palladium cluster catalysts enable hydrogen production from nitrogen heterocycles

(2022) Chunyang Dong et al.   Nature Catalysis

Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts

(2021) Mengyao Ouyang et al.   Nature Communications

Synergistic Effects for Enhanced Catalysis in a Dual Single-Atom Catalyst

(2021) Junhong Fu et al.   ACS Catalysis

Interface dynamics of Pd–CeO2 single-atom catalysts during CO oxidation

(2021) Valery Muravev et al.   Nature Catalysis

N-Coordinated Dual-Metal Single-Site Catalyst for Low-Temperature CO Oxidation

(2020) Jing Wang et al.   ACS Catalysis

Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts

(2020) Hojin Jeong et al.   Nature Catalysis

Subnanometer Bimetallic Platinum–Zinc Clusters in Zeolites for Propane Dehydrogenation

(2020) Qiming Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Synthesis of Kilogram-Scale Co-Alloyed Pt Single-Atom Catalysts via Ball Milling for Hydrodeoxygenation of 5-Hydroxymethylfurfural

(2020) Tao Gan et al.   ACS Sustainable Chemistry & Engineering

Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation

(2020) Xiaoben Zhang et al.   Nature Catalysis

Selective Methanol Carbonylation to Acetic Acid on Heterogeneous Atomically Dispersed ReO4/SiO2 Catalysts

(2020) Ji Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst

(2020) Tian-Nan Ye et al.   NATURE

Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts

(2020) Lizhi Jiang et al.   Nature Nanotechnology

Alkali ions secure hydrides for catalytic hydrogenation

(2020) Ruixuan Qin et al.   Nature Catalysis

Insights into the Mechanism of n-Hexane Reforming over a Single-Site Platinum Catalyst

(2020) Shuchen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supported Metal Clusters: Fabrication and Application in Heterogeneous Catalysis

(2020) Chunyang Dong et al.   ACS Catalysis

Size Dependence of Pt Catalysts for Propane Dehydrogenation: from Atomically Dispersed to Nanoparticles

(2020) Wei Zhang et al.   ACS Catalysis

Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2

(2020) Florian Maurer et al.   Nature Catalysis

Atomically Dispersed Pt-group Catalysts: Reactivity, Uniformity, Structural Evolution, and Paths to Increased Functionality

(2020) Joaquin Resasco et al.   Journal of Physical Chemistry Letters

Atomically Dispersed Ni/α-MoC Catalyst for Hydrogen Production from Methanol/Water

(2020) Lili Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Measuring Transient Reaction Rates from Nonstationary Catalysts

(2020) Dmitriy Borodin et al.   ACS Catalysis

Fully Exposed Cluster Catalyst (FECC): Toward Rich Surface Sites and Full Atom Utilization Efficiency

(2020) Mi Peng et al.   ACS Central Science

Shape-selective C–H activation of aromatics to biarylic compounds using molecular palladium in zeolites

(2020) Jannick Vercammen et al.   Nature Catalysis

Structure sensitivity of n-butane hydrogenolysis on supported Ir catalysts

(2020) Xiwen Zhang et al.   JOURNAL OF CATALYSIS

Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2

(2019) Lina Cao et al.   NATURE

Interplay Between Site Activity and Density of BCC Iron for Ammonia Synthesis Based on First-Principles Theory

(2019) Bing-Yan Zhang et al.   ChemCatChem

Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms

(2019) Leilei Zhang et al.   CHEMICAL REVIEWS

MgO-Supported Iridium Metal Pair-Site Catalysts Are More Active and Resistant to CO Poisoning than Analogous Single-Site Catalysts for Ethylene Hydrogenation and Hydrogen–Deuterium Exchange

(2019) Erjia Guan et al.   ACS Catalysis

Regulating the coordination structure of single-atom Fe-NxCy catalytic sites for benzene oxidation

(2019) Yuan Pan et al.   Nature Communications

In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles

(2019) Siquan Feng et al.   Nature Communications

Determination of the Evolution of Heterogeneous Single Metal Atoms and Nanoclusters under Reaction Conditions: Which Are the Working Catalytic Sites?

(2019) Lichen Liu et al.   ACS Catalysis

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

(2018) Lichen Liu et al.   CHEMICAL REVIEWS

Catalytic performance of Ru, Os, and Rh nanoparticles for ammonia synthesis: A density functional theory analysis

(2018) Atsushi Ishikawa et al.   JOURNAL OF CATALYSIS

Fully Dispersed Rh Ensemble Catalyst To Enhance Low-Temperature Activity

(2018) Hojin Jeong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C–H activation

(2018) Matthew D. Marcinkowski et al.   Nature Chemistry

NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen

(2018) Georgios Giannakakis et al.   TOPICS IN CATALYSIS

Carbon nitride supported Fe2 cluster catalysts with superior performance for alkene epoxidation

(2018) Shubo Tian et al.   Nature Communications

Beating Heterogeneity of Single-Site Catalysts: MgO-Supported Iridium Complexes

(2018) Adam S. Hoffman et al.   ACS Catalysis

Coordination chemistry of atomically dispersed catalysts

(2018) Pengxin Liu et al.   National Science Review

Atomically Dispersed Pd on Nanodiamond/Graphene Hybrid for Selective Hydrogenation of Acetylene

(2018) Fei Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ion and velocity map imaging for surface dynamics and kinetics

(2017) Dan J. Harding et al.   JOURNAL OF CHEMICAL PHYSICS

Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO2

(2017) Leo DeRita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemical Insights into the Design and Development of Face-Centered Cubic Ruthenium Catalysts for Fischer–Tropsch Synthesis

(2017) Wei-Zhen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts

(2017) Lili Lin et al.   NATURE

Activation of surface lattice oxygen in single-atom Pt/CeO2for low-temperature CO oxidation

(2017) Lei Nie et al.   SCIENCE

Use of molecular beams for kinetic measurements of chemical reactions on solid surfaces

(2017) Francisco Zaera   SURFACE SCIENCE REPORTS

Fluxionality of Catalytic Clusters: When It Matters and How to Address It

(2017) Huanchen Zhai et al.   ACS Catalysis

Stable Pt Single Atoms and Nanoclusters on Ultrathin CuO Film and Their Performances in CO Oxidation

(2016) Xiong Zhou et al.   Journal of Physical Chemistry C

Homogeneity of Surface Sites in Supported Single-Site Metal Catalysts: Assessment with Band Widths of Metal Carbonyl Infrared Spectra

(2016) Adam S. Hoffman et al.   Journal of Physical Chemistry Letters

Photochemical route for synthesizing atomically dispersed palladium catalysts

(2016) P. Liu et al.   SCIENCE

A Stable Single-Site Palladium Catalyst for Hydrogenations

(2015) Gianvito Vilé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Atom Alloy Pd–Ag Catalyst for Selective Hydrogenation of Acrolein

(2015) Payoli Aich et al.   Journal of Physical Chemistry C

Aqueous-Phase Preparation of Model HDS Catalysts on Planar Alumina Substrates: Support Effect on Mo Adsorption and Sulfidation

(2015) Cédric Bara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons

(2015) Jovana Zecevic et al.   NATURE

Counting electrons on supported nanoparticles

(2015) Yaroslava Lykhach et al.   NATURE MATERIALS

Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts

(2015) K. Ding et al.   SCIENCE

Engineering Catalyst Microenvironments for Metal-Catalyzed Hydrogenation of Biologically Derived Platform Chemicals

(2014) Thomas J. Schwartz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol

(2014) Felix Studt et al.   Nature Chemistry

Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen

(2014) X. Guo et al.   SCIENCE

Catalytically active Au-O(OH)x- species stabilized by alkali ions on zeolites and mesoporous oxides

(2014) Ming Yang et al.   SCIENCE

Recent Approaches in Mechanistic and Kinetic Studies of Catalytic Reactions Using SSITKA Technique

(2014) Cristian Ledesma et al.   ACS Catalysis

Effect of treatment conditions on ruthenium particle size and ammonia synthesis activity of ruthenium catalyst

(2013) Bingyu Lin et al.   CATALYSIS COMMUNICATIONS

Remarkable Performance of Ir1/FeOx Single-Atom Catalyst in Water Gas Shift Reaction

(2013) Jian Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Active sites and reactive intermediates in the hydrogenolytic cleavage of C–C bonds in cyclohexane over supported iridium

(2012) Hui Shi et al.   JOURNAL OF CATALYSIS

Finite-Size Effects in O and CO Adsorption for the Late Transition Metals

(2012) Andrew A. Peterson et al.   TOPICS IN CATALYSIS

Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters

(2011) Ayman D. Allian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-atom catalysis of CO oxidation using Pt1/FeO x

(2011) Botao Qiao et al.   Nature Chemistry

Size- and support-dependent silver cluster catalysis for chemoselective hydrogenation of nitroaromatics

(2010) Ken-ichi Shimizu et al.   JOURNAL OF CATALYSIS

Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions

(2010) Y. Zhai et al.   SCIENCE

On the Origin of the Cobalt Particle Size Effects in Fischer−Tropsch Catalysis

(2009) J. P. den Breejen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A [Cu2O]2+core in Cu-ZSM-5, the active site in the oxidation of methane to methanol

(2009) Julia S. Woertink et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Complementary Structure Sensitive and Insensitive Catalytic Relationships

(2008) Rutger A. Van Santen   ACCOUNTS OF CHEMICAL RESEARCH

Structure sensitivity of the methanation reaction: H2-induced CO dissociation on nickel surfaces

(2008) M.P. Andersson et al.   JOURNAL OF CATALYSIS