Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds

Pathways to Highly Oxidized Products in the Δ3-Carene + OH System

(2022) Emma L. D’Ambro et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Rates and Yields of Unimolecular Reactions Producing Highly Oxidized Peroxy Radicals in the OH-Induced Autoxidation of α-Pinene, β-Pinene, and Limonene

(2022) Ivan R. Piletic et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry

(2021) Sophie Tomaz et al.   Nature Communications

Molecular mechanism for rapid autoxidation in α-pinene ozonolysis

(2021) Siddharth Iyer et al.   Nature Communications

Efficient alkane oxidation under combustion engine and atmospheric conditions

(2021) Zhandong Wang et al.   Communications Chemistry

Trimethylamine Outruns Terpenes and Aromatics in Atmospheric Autoxidation

(2021) Torsten Berndt et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules

(2021) Catherine G. Masoud et al.   ACS Earth and Space Chemistry

Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene

(2021) Hongru Shen et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Peroxy Radical Processes and Product Formation in the OH Radical-Initiated Oxidation of α-Pinene for Near-Atmospheric Conditions

(2021) Torsten Berndt   JOURNAL OF PHYSICAL CHEMISTRY A

Double Bonds Are Key to Fast Unimolecular Reactivity in First-Generation Monoterpene Hydroxy Peroxy Radicals

(2020) Kristian H. Møller et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Size-dependent influence of NOx on the growth rates of organic aerosol particles

(2020) C. Yan et al.   Science Advances

The Importance of Peroxy Radical Hydrogen Shift Reactions in Atmospheric Isoprene Oxidation

(2019) Kristian H. Møller et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Anthropogenic enhancements to production of highly oxygenated molecules from autoxidation

(2019) Havala O. T. Pye et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Secondary organic aerosol reduced by mixture of atmospheric vapours

(2019) Gordon McFiggans et al.   NATURE

Unimolecular Reactions of Peroxy Radicals Formed in the Oxidation of α-Pinene and β-Pinene by Hydroxyl Radicals

(2019) Lu Xu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol

(2019) Federico Bianchi et al.   CHEMICAL REVIEWS

Formation of Highly Oxygenated Organic Molecules from α-Pinene Ozonolysis: Chemical Characteristics, Mechanism, and Kinetic Model Development

(2019) Ugo Molteni et al.   ACS Earth and Space Chemistry

Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: an Experimental and Theoretical Study

(2019) Barbara Noziere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct detection of atmospheric atomic bromine leading to mercury and ozone depletion

(2019) Siyuan Wang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Molecular identification of organic vapors driving atmospheric nanoparticle growth

(2019) Claudia Mohr et al.   Nature Communications

The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system

(2019) Pontus Roldin et al.   Nature Communications

Accretion Product Formation from Self- and Cross-Reactions of RO2 Radicals in the Atmosphere

(2018) Torsten Berndt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers

(2018) Yuanlong Huang et al.   ENVIRONMENTAL SCIENCE & TECHNOLOGY

Observations of biogenic ion-induced cluster formation in the atmosphere

(2018) Clémence Rose et al.   Science Advances

Ambient Measurements of Highly Oxidized Gas-Phase Molecules during the Southern Oxidant and Aerosol Study (SOAS) 2013

(2018) Paola Massoli et al.   ACS Earth and Space Chemistry

Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals

(2018) Eric Praske et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry

(2018) Yue Zhao et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

(2018) Katrianne Lehtipalo et al.   Science Advances

A look at the density functional theory zoo with the advanced GMTKN55 database for general main group thermochemistry, kinetics and noncovalent interactions

(2017) Lars Goerigk et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Atmospheric autoxidation is increasingly important in urban and suburban North America

(2017) Eric Praske et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Environmental conditions regulate the impact of plants on cloud formation

(2017) D. F. Zhao et al.   Nature Communications

Solar eclipse demonstrating the importance of photochemistry in new particle formation

(2017) Tuija Jokinen et al.   Scientific Reports

Rapid Hydrogen Shift Scrambling in Hydroperoxy-Substituted Organic Peroxy Radicals

(2016) Solvejg Jørgensen et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Ion-induced nucleation of pure biogenic particles

(2016) Jasper Kirkby et al.   NATURE

The role of low-volatility organic compounds in initial particle growth in the atmosphere

(2016) Jasmin Tröstl et al.   NATURE

Hydroxyl radical-induced formation of highly oxidized organic compounds

(2016) Torsten Berndt et al.   Nature Communications

Modeling the Charging of Highly Oxidized Cyclohexene Ozonolysis Products Using Nitrate-Based Chemical Ionization

(2015) Noora Hyttinen et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications

(2015) Tuija Jokinen et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Formation of Highly Oxidized Multifunctional Products in the Ozonolysis of Cyclohexene

(2014) Matti P. Rissanen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A large source of low-volatility secondary organic aerosol

(2014) Mikael Ehn et al.   NATURE

Autoxidation of Organic Compounds in the Atmosphere

(2013) John D. Crounse et al.   Journal of Physical Chemistry Letters

Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance

(2012) John J. Orlando et al.   CHEMICAL SOCIETY REVIEWS

Kinetics, products, and mechanisms of secondary organic aerosol formation

(2012) Paul J. Ziemann et al.   CHEMICAL SOCIETY REVIEWS

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Experimental Revaluation of the Importance of the Abstraction Channel in the Reactions of Monoterpenes with OH Radicals

(2010) Caroline Rio et al.   CHEMPHYSCHEM

Computational Thermochemistry: Scale Factor Databases and Scale Factors for Vibrational Frequencies Obtained from Electronic Model Chemistries

(2010) I. M. Alecu et al.   Journal of Chemical Theory and Computation

A structure–activity relationship for the rate coefficient of H-migration in substituted alkoxy radicals

(2010) L. Vereecken et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Decomposition of substituted alkoxy radicals—part I: a generalized structure–activity relationship for reaction barrier heights

(2009) L. Vereecken et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Amplified Trace Gas Removal in the Troposphere

(2009) A. Hofzumahaus et al.   SCIENCE

Evolution of Organic Aerosols in the Atmosphere

(2009) J. L. Jimenez et al.   SCIENCE

Aerosol–cloud–precipitation interactions. Part 1. The nature and sources of cloud-active aerosols

(2008) M.O. Andreae et al.   EARTH-SCIENCE REVIEWS