4.8 Article

Heterostructured bimetallic-sulfide@layered Ti3C2Tx-MXene as a synergistic electrode to realize high-energy-density aqueous hybrid-supercapacitor

Journal

NANO ENERGY
Volume 101, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2022.107624

Keywords

MXene; Bimetallic-sulfide; Heterostructure; Hybrid supercapacitor; High-energy-density

Funding

  1. School of Physical Science and Technology, Lanzhou University, China
  2. scientific research start-up grant for Youth Researchers at Lanzhou University
  3. National Natural Science Foundation of China [51972153]
  4. Fundamental Research Funds for the Central Universities [lzujbky-2021-sp64]
  5. Supercomputing Center of Lanzhou University
  6. King Khalid University Saudi Arabia [RGP. 2/40/43]

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In this study, a heterostructured composite of nickel-cobalt-sulfide nanoflowers embedded in exfoliated Ti3C2Tx-MXene layers was proposed to enhance the energy density and electrochemical performance of aqueous hybrid supercapacitors (AHSCs). The composite exhibited remarkable pseudocapacitive performance and could operate in a wide potential range with high capacitance and stable cyclic life. The synergistic effect of NCS and MXene enabled the composite to deliver outstanding electrochemical performance for AHSCs.
Aqueous hybrid supercapacitors (AHSCs) exhibit promising electrochemical performance with long cyclic stability and high power density. However, the low-energy density restricted their development to commercialization. To improve the energy density, we proposed a heterostructured (HS) composite of nickel-cobalt-sulfide (NCS) nanoflowers embedded in exfoliated Ti3C2Tx-MXene layers (HS-NCS@MXene). The NCS nanoflowers were uniformly dispersed inside the MXene layers and formed a sandwich-like structure. The HS-NCS@MXene exhibited remarkable pseudocapacitive performance in a three-electrode system. The capacitance can reach 2637 F g(-1) (1582 C g(-1)) at 2.5 A g(-1) with stable cycling life over 10,000 cycles and retained 96% capacity of the initial value. Post-mortem investigations confirmed that the charge storage mechanism in HS-NCS@MXene composite is a combination of Faradic and electrochemical double-layer storage. An AHSC was assembled by coupling the HS-NCS@MXene as a positive electrode and activated carbon as a negative electrode (HS-NCS@MXene//AC-AHSC). The HS-NCS@MXene//AC-AHSC can operate in a potential range up to 1.6 V and deliver a high capacitance of 226 F g(-1) at 1.5 A g(-1) with stable cyclic life (92%) up to 20,000 cycles. Moreover, the HS-NCS@MXene//AC-AHSC also possessed a high energy density of 80 Wh kg(-1) at a power density of 1196 W kg(-1), which exceeds most recently published works. The synergistic effect of NCS and MXene enables the HS-NCS@MXene composite to deliver outstanding electrochemical performance for AHSCs.

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