Journal
JOURNAL OF MATERIALS SCIENCE
Volume 52, Issue 4, Pages 2366-2372Publisher
SPRINGER
DOI: 10.1007/s10853-016-0531-2
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Funding
- Urumqi Science and Technology Plan [P151010005]
- National Natural Science Foundation of China [61504168]
- Thousand Youth Talents Plan [Y42H831301]
- Foundation of Director of Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, China [2015RC010]
- Hebei outstanding young scholars, Science and Technology Program of Hebei Province [D2016403064, 16044601Z]
- Hebei Science and Technology Support Program [15211121]
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In order to obtain high-performance nanoscale LiFePO4 cathode materials for lithium-ion batteries, CH3COOLi center dot 2H(2)O, FeC2O4 center dot 2H(2)O, and NH4H2PO4 were used as raw materials to prepare the precursors of LiFePO4 by room-temperature solid-state reaction method firstly; then, LiFePO4 cathode materials were synthesized by high heating solid-state reaction method. The influence of temperature on the crystal structure, microstructure, and electrochemical properties were studied by thermogravimetric analysis, differential scanning calorimetry, X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy, and charge-discharge performance test. It was indicated that the olivine-phase LiFePO4 not only presented nano-sized particles in the range of 40-80 nm, but also showed excellent initial discharge specific capacity of about 155 mAh/g at 0.2 C at a sintering temperature of 700 A degrees C and possessed good cycle performance. This preparation method without any solvent and carbon source addition could realize industrialized production of single-phase nano-LiFePO4.
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