4.8 Article

3D network graphene interlayer for excellent interlaminar toughness and strength in fiber reinforced composites

Journal

CARBON
Volume 95, Issue -, Pages 978-986

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2015.09.001

Keywords

-

Funding

  1. Australian Research Council [DP130104648]

Ask authors/readers for more resources

A novel CVD grown 3D network graphene is used as interleaves to toughen and strengthen glass fiber reinforced epoxy composite (GF/EP). Remarkable increases of 70% and 206% in mode I and mode II interlaminar fracture energies, respectively, and 36% enhancement in interlaminar shear strength are achieved in GF/EP by incorporating network graphene in the failure-prone mid-plane compared to those composite laminates without interleaves. Pertinent toughening mechanisms include crack deflection and formation of interfacial micro-cracks with significant increase in surface areas owing to the 3D hollow sphere-like graphene wrapping around the epoxy matrix as well as graphene fracture and slippage between adjacent layers. (C) 2015 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Interdigitated Three-Dimensional Heterogeneous Nanocomposites for High-Performance Mechanochromic Smart Membranes

Haomin Chen, Donghwi Cho, Kwonhwan Ko, Caiyan Qin, Minsoo P. Kim, Heng Zhang, Jeng-Hun Lee, Eunyoung Kim, Dawon Park, Xi Shen, Jinglei Yang, Hyunhyub Ko, Jung-Wuk Hong, Jang-Kyo Kim, Seokwoo Jeon

Summary: This study presents a strategy for designing mechanochromic scattering membranes with high-contrast optical modulation based on Young's modulus mismatch. The 3D heterogeneity of the membrane enables incident light scattering under tension, resulting in a high transmittance contrast and maximum contrast. The membrane can be used as a smart window for effective diffusion of sunlight and enhanced coloration sensitivity.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Integrated Water and Thermal Managements in Bioinspired Hierarchical MXene Aerogels for Highly Efficient Solar-Powered Water Evaporation

Hongming Zhang, Xi Shen, Eunyoung Kim, Mingyue Wang, Jeng-Hun Lee, Haomin Chen, Guangcheng Zhang, Jang-Kyo Kim

Summary: This study reports an integrated design of solar absorbers for efficient water desalination. The design combines spectrally modified Ti3C2Tx nanosheets with polyvinyl alcohol to create a composite aerogel with a feather-like microstructure, providing excellent thermal insulation. The functional features of the material enable high energy efficiency and evaporation rate, making it suitable for solar-powered water desalination.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Physical

Graphene and MXene-based porous structures for multifunctional electromagnetic interference shielding

Xi Shen, Jang-Kyo Kim

Summary: This review summarizes the recent progress in developing porous composites and structures for electromagnetic interference (EMI) shielding using graphene and MXene nanosheets. The relationships between material properties, microstructures, and EMI shielding performance are explored, and different technological approaches to constructing porous structures are compared. The review also highlights the multifunctional applications of porous composites and their unique compositions and microstructures.

NANO RESEARCH (2023)

Article Engineering, Manufacturing

Wrinkled, cracked and bridged carbon networks for highly sensitive and stretchable strain sensors

Dan Liu, Heng Zhang, Haomin Chen, Jeng-Hun Lee, Fengmei Guo, Xi Shen, Qingbin Zheng, Jang-Kyo Kim

Summary: In this work, highly sensitive and stretchable strain sensors are designed using single-walled carbon nanotube (SWNT)/graphene oxide (GO) hybrid thin films with unique wrinkled, cracked and bridged morphologies. The sensors exhibit a wide sensing range and high stability, enabling them to monitor full range human motions.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2022)

Article Chemistry, Multidisciplinary

Salt-Assisted Selective Growth of H-phase Monolayer VSe2 with Apparent Hole Transport Behavior

Jiawen You, Jie Pan, Shun-Li Shang, Xiang Xu, Zhenjing Liu, Jingwei Li, Hongwei Liu, Ting Kang, Mengyang Xu, Shaobo Li, Deqi Kong, Wenliang Wang, Zhaoli Gao, Xing Zhou, Tianyou Zhai, Zi-Kui Liu, Jang-Kyo Kim, Zhengtang Luo

Summary: This study reports the epitaxial growth of monolayer vanadium diselenide on a mica substrate using chemical vapor deposition. The research reveals that the monolayer H-phase vanadium diselenide with a large lateral size is energetically favorable and exhibits a honeycomb-like structure with broken symmetry. Additionally, the study demonstrates the p-type transport behavior of the material.

NANO LETTERS (2022)

Review Materials Science, Multidisciplinary

Heusler alloys: Past, properties, new alloys, and prospects

Sheron Tavares, Kesong Yang, Marc A. Meyers

Summary: Heusler alloys have emerged as exciting materials for various functional applications due to their ordered structure and unique properties. This review article discusses the discovery, magnetic and electronic properties, mechanical properties, and computational design of Heusler alloys. It also explores the challenges and future directions in this field.

PROGRESS IN MATERIALS SCIENCE (2023)

Article Chemistry, Multidisciplinary

BN-PVDF/rGO-PVDF Laminate Nanocomposites for Energy Storage Applications

Okikiola Ganiu Agbabiaka, Miracle Hope Adegun, Kit-Ying Chan, Heng Zhang, Xi Shen, Jang-Kyo Kim

Summary: In this study, a high dielectric energy storage composite was designed using a novel technique. The composite, consisting of reduced graphene oxide and boron nitride nanosheets as fillers, exhibited remarkable dielectric performance and ultra-low dielectric loss, achieving high energy density.

NANOMATERIALS (2022)

Article Chemistry, Multidisciplinary

Mechanochromic Optical/Electrical Skin for Ultrasensitive Dual-Signal Sensing

Heng Zhang, Haomin Chen, Jeng-Hun Lee, Eunyoung Kim, Kit-Ying Chan, Harun Venkatesan, Xi Shen, Jinglei Yang, Jang-Kyo Kim

Summary: This research aims to design a flexible optical/electrical skin capable of responding to complex stimuli with interactive feedback of human-readable structural colors. The OE-skin consists of various layers including an ionic electrode, elastomer dielectric layer, chromotropic layer, and a conductive carbon nanotube/MXene layer. It delivers an ultrafast, accurate response for capacitive pressure sensing and visualizes complex deformations in high-resolution spatial colors.

ACS NANO (2023)

Article Chemistry, Multidisciplinary

Anti-Fatigue Hydrogel Electrolyte for All-Flexible Zn-Ion Batteries

Qun Liu, Zhenlu Yu, Qiuna Zhuang, Jang-Kyo Kim, Feiyu Kang, Biao Zhang

Summary: Hydrogel electrolytes have been widely studied in Zn metal batteries for wearable electronics, but the mechanical stability of the hydrogel under repeated deformation has been overlooked, resulting in unsatisfactory performance. This study explores the compressive fatigue-resistance properties of the hydrogel electrolyte and identifies the critical roles of the salt and copolymer matrix in crack initiation and propagation. An optimal Zn(ClO4)(2)-polyacrylamide/chitosan hydrogel electrolyte (C-PAMCS) is found to exhibit an unprecedented lifespan and high areal capacity for Zn//Zn cells, enabling potential applications in flexible Zn-ion batteries.

ADVANCED MATERIALS (2023)

Review Materials Science, Multidisciplinary

Templating strategies for 3D-structured thermally conductive composites: Recent advances and thermal energy applications

Jie Yang, Xi Shen, Wei Yang, Jang-Kyo Kim

Summary: This review summarizes recent advances in the development of thermally conductive polymer composites using various templating methods, including self-templating, sacrificial templating, foam-templating, ice-templating, and template-directed chemical vapor deposition techniques. These unique methods allow for the fabrication of three-dimensional interconnected fillers with segregated, cellular, lamellar, and radially aligned structures, which are correlated to the thermal conductivity of the composites. Moreover, the review highlights the use of multiscale structural design strategies combined with different templating methods to further improve the thermal conductivity of the composites.

PROGRESS IN MATERIALS SCIENCE (2023)

Article Chemistry, Multidisciplinary

Homogenizing Zn Deposition in Hierarchical Nanoporous Cu for a High-Current, High Areal-Capacity Zn Flow Battery

Yang Li, Liangyu Li, Yunhe Zhao, Canbin Deng, Zhibin Yi, Diwen Xiao, Nauman Mubarak, Mengyang Xu, Jie Li, Guangfu Luo, Qing Chen, Jang-Kyo Kim

Summary: A hierarchical nanoporous electrode is developed by alloying Cu foam with Zn to homogenize the deposition and create nanoscale pores. This electrode shows uniform Zn deposition and stable performance in a Zn-I-2 flow battery, meeting practical demands.

SMALL (2023)

Article Chemistry, Physical

Uniform SnSe nanoparticles on 3D graphene host enabling a dual-nucleation-site interface for dendrite-free sodium metal batteries

Mengyang Xu, Zhenjing Liu, Yang Li, Nauman Mubarak, Hoilun Wong, Mohsen Tamtaji, Yunhe Zhao, Yuyin Li, Jun Wang, Jiawen You, Hongwei Liu, Yuting Cai, Kenan Zhang, Feng Xu, Khalil Amine, Jang-Kyo Kim, Zhengtang Luo

Summary: This study presents the synthesis of tin selenide nanoparticles grown on highly conductive, porous 3D graphene foam as a stable host for sodium metal anodes and reveals their energy storage mechanism through conversion reactions. The SnSe@GF electrode exhibits remarkable reversibility after 1500 cycles in asymmetric cells and extraordinary cyclic stability and low overpotentials for 2000 h in symmetric cells. The outstanding performance is attributed to the conversion of crystalline SnSe into low-crystallinity Na15Sn4 and Na2Se dual nucleation sites after pre-sodiation, which enables the formation of a unique interface with high sodium affinity and abundant active sites, resulting in uniform sodium nucleation/plating and dendrite suppression.

ENERGY STORAGE MATERIALS (2023)

Article Chemistry, Physical

Engineering anisotropic structures of thermally insulating aerogels with high solar reflectance for energy-efficient cooling applications

Eunyoung Kim, Kit-Ying Chan, Jie Yang, Harun Venkatesan, Miracle Hope Adegun, Heng Zhang, Jeng-Hun Lee, Xi Shen, Jang-Kyo Kim

Summary: In this study, the microstructure and thermal conductivity of waterborne polyurethane (WPU) aerogels were tailored through unidirectional freeze-casting at different freezing temperatures. The addition of two-dimensional boron nitride nanosheets (BNNSs) further intensified the anisotropy of WPU aerogels. The resulting composite aerogel exhibited low density and low thermal conductivity, making it suitable for efficient thermal insulation applications and offering better thermal management under direct sunlight.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Accelerating the dissolution kinetics of iodine with a cosolvent for a high-current zinc-iodine flow battery

Yunhe Zhao, Yang Li, Jiatao Mao, Zhibin Yi, Nauman Mubarak, Yiting Zheng, Jang-Kyo Kim, Qing Chen

Summary: The use of iodine in aqueous flow batteries shows potential for high-performance energy storage, but the low solubility of iodine limits its efficiency. By adding acetonitrile as a cosolvent, the solubility of iodine is enhanced, leading to significantly improved current efficiency and stable charging current in the Zn-I-2 flow battery.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

Highly porous carbon nanofiber electrodes for vanadium redox flow batteries

Yunhe Zhao, Yang Li, Muhammad Ihsan-ul-haq, Nauman Mubarak, Mengyang Xu, Xianying Qin, Tian-Shou Zhao, Jang-Kyo Kim

Summary: The electrochemical performance of carbon nanofiber electrodes in vanadium redox flow batteries can be enhanced by optimizing their morphological and physical properties. This can be achieved by modifying the precursor composition and carbonization temperature, resulting in tailored surface area, porosity, and electrical conductivity. The optimized carbon nanofibers exhibit high wettability and activity, leading to improved electrochemical performance in vanadium redox flow batteries.

NANOSCALE (2022)

Article Chemistry, Physical

Dendritic growth lowers carbon electrode work function for efficient perovskite solar cells

Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu

Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.

CARBON (2024)

Article Chemistry, Physical

High-performance epoxy nanocomposites via constructing a rigid-flexible interface with graphene oxide functionalized by polyetheramine and f-SiO2

Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu

Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.

CARBON (2024)

Article Chemistry, Physical

A facile route to the synthesis of carbon replicas cast from narrow-mesoporous matrices

Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski

Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.

CARBON (2024)

Article Chemistry, Physical

Microstructure and energetic characteristics of direct ink printed polymer-free rGO/nanothermite aerogel

Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen

Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.

CARBON (2024)

Article Chemistry, Physical

A solar-driven interfacial evaporator for seawater desalination based on mussel-inspired superhydrophobic composite coating

Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang

Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.

CARBON (2024)

Article Chemistry, Physical

Bead-like flexible ZIF-67-derived Co@Carbon composite nanofibre mat for wideband microwave absorption in C-band

Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang

Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.

CARBON (2024)

Article Chemistry, Physical

A perovskite-graphene device for X-ray detection

J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas

Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.

CARBON (2024)

Article Chemistry, Physical

Microporous carbon prepared by microwave pyrolysis of scrap tyres and the effect of K+ in its structure on xylene adsorption

Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik

Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.

CARBON (2024)

Article Chemistry, Physical

Ambipolar charge transfer of larger fullerenes enabled by the modulated surface potential of h-BN/Rh(111)

Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning

Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.

CARBON (2024)

Article Chemistry, Physical

Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption

Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li

Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.

CARBON (2024)

Article Chemistry, Physical

In situ self-adaptive growth of graphene coatings on hard substrates via competitive NiCo catalysis reaction

Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu

Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.

CARBON (2024)

Article Chemistry, Physical

Monodispersed semiconducting SWNTs significantly enhanced the thermoelectric performance of regioregular poly(3-dodecylthiophene) films

Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen

Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.

CARBON (2024)

Review Chemistry, Physical

Component optimization and microstructure design of carbon nanotube-based microwave absorbing materials: A review

Heng Wei, Weihua Li, Kareem Bachagha

Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.

CARBON (2024)

Article Chemistry, Physical

MXene-based polymer brushes decorated with small-sized Ag nanoparticles enabled high-performance lithium host for stable lithium metal battery

Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu

Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.

CARBON (2024)

Article Chemistry, Physical

A stable full cell having high energy density realized by using a three-dimensional current collector of carbon nanotubes and partial prelithiation of silicon monoxide

Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda

Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.

CARBON (2024)