Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 77, Issue 11-12, Pages 779-783Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2022-0119
Keywords
interpenetrated MOF network; room temperature phosphorescence; zinc complex
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Funding
- National Natural Science Foundation of China [21971100]
- Project for Science & Technology Innovation Talents in Universities of Henan Province [21HASTIT006]
- Scientific Research Projects of Henan Province [212102210638, 2019GGJS198]
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A new coordination complex with a unique two-dimensional network structure and phosphorescence emission properties has been synthesized under hydrothermal conditions.
A coordination complex {[Zn(EtAIPA)(dpe)]center dot H2O}( n ) (1), has been synthesized under hydrothermal conditions based on 5-(ethylamino)isophthalic acid (H(2)EtAIPA) and trans-1,2-di(4-pyridyl)ethene (dpe). The title complex was characterized by elemental analysis, UV/Vis absorption, single-crystal X-ray diffraction and emission properties. The as-prepared complex appears as a puckered 2D (4,4) network, The individual 2D nets are interlocked with each other to form a 3-fold parallel interpenetrated 2D architecture. Time-resolved measurements reveal cyan phosphorescence emission at room temperature.
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