Facets-Directed Epitaxially Grown Lead Halide Perovskite- Sulfobromide Nanocrystal Heterostructures and Their Improved Photocatalytic Activity

Lead halide perovskite nanocrystal heterostructures have been extensively studied in the recent past for improving their photogenerated charge carriers mobility. However, most of such heterostructures are formed with random connections without having strong evidence of epitaxial relation. Perovskite-chalcoha-lides are the first in this category, where all-inorganic hetero-structures are formed with epitaxial growth. Going beyond one facet, herein, different polyhedral nanocrystals of CsPbBr3 are explored for facet-selective secondary epitaxial sulfobromide growths. Following a decoupled synthesis process, the hetero-junctions are selectively established along {110} as well as {200} facets of 26-faceted rhombicuboctahedrons, the {110} facets of armed hexapods, and the {002} facets of 12-faceted dodecahedron nanocrystals of orthorhombic CsPbBr3. Lattice matching induced these epitaxial growths, and their heterojunctions have been extensively studied with electron microscopic imaging. Unfortunately, these heterostructures did not retain the intense host emission because of their indirect band structures, but such combinations are found to be ideal for promoting photocatalytic CO2 reduction. The pseudo-Type-II combination helped here in the successful movement of charge carriers and also improved the rate of catalysis. These results suggest that facet-selective all-inorganic perovskite heterostructures can be epitaxially grown and this could help in improving their catalytic activities.

Automated summary

Lead halide perovskite nanocrystal heterostructures with epitaxial growth have been explored to improve the mobility of photogenerated charge carriers. Selective facet-selective secondary epitaxial sulfobromide growths have been achieved using different polyhedral nanocrystals. Although the intense host emission was not retained in these heterostructures, they showed potential for promoting photocatalytic CO2 reduction through pseudo-Type-II combination.