Review
Chemistry, Multidisciplinary
Fei Zhang, Yukun Li, Bin Ding, Guosheng Shao, Neng Li, Peng Zhang
Summary: Producing solar fuels using photocatalysts is a promising solution to energy and environmental issues. To maximize the efficiency, photocatalysts need to have broad light absorption, fast charge carrier migration, and abundant reaction sites. Electrospun 1D nanofibers are effective in the production of solar fuels due to their large specific areas and high porosity. However, researching the mechanism behind electrospun nanofiber-based photocatalysts is challenging due to the multiple charge transfer routes and reaction sites involved.
Article
Chemistry, Multidisciplinary
Libo Wang, Bei Cheng, Liuyang Zhang, Jiaguo Yu
Summary: Efficient hierarchical photocatalysts, such as the S-scheme core-shell TiO2@ZnIn2S4 heterojunction, have gained attention for photocatalytic CO2 reduction. The improved performance is attributed to the inhibited recombination of photogenerated charge carriers induced by the S-scheme heterojunction, as well as the large specific surface areas and abundant active sites. In situ irradiated X-ray photoelectron spectroscopy, work function calculation, and electron paramagnetic resonance measurements confirm the S-scheme photogenerated charge transfer mechanism.
Article
Energy & Fuels
Kai Wang, Xiuli Shao, Qiang Cheng, Ke Li, Xiaoying Le, Guohong Wang, Hukun Wang
Summary: This article presents a novel core-shell Ta2O5/ZnIn2S4 heterojunction photocatalyst and demonstrates its high efficiency in solar-driven CO2 overall splitting. The efficient charge separation of photo-generated electron-hole pairs is achieved through the 2D/1D interface and the built-in electric field, resulting in a significantly enhanced yield of CO2 splitting products.
Article
Energy & Fuels
Zhongliao Wang, Bei Cheng, Liuyang Zhang, Jiaguo Yu, Haiyan Tan
Summary: The study demonstrates enhanced CO2 photoreduction activity through an S-scheme BiOBr/NiO heterojunction, showcasing improved understanding of the mechanism through integration of in situ monitoring techniques with density functional theory calculation.
Article
Chemistry, Physical
Zahra Salmanzadeh-Jamadi, Aziz Habibi-Yangjeh, Cailing Xu, Chundong Wang
Summary: Novel brown TiO2-x/Bi4O5I2/carbon dots (B-TiO2-x/Bi4O5I2/CDs) photocatalysts were successfully prepared for the degradation of antibiotics. The optimized nanocomposite showed impressive activity in the photodegradation of cephalexin, metronidazole, and tetracycline, with significantly higher efficiency compared to TiO2 and B-TiO2-x. The nanocomposite also displayed considerable stability after multiple cycles.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Pengpeng Zhang, Yige Zhao, Yukun Li, Neng Li, S. Ravi P. Silva, Guosheng Shao, Peng Zhang
Summary: The electrocatalysts play an important role in improving the electrochemical performance of lithium-sulfur batteries by selectively accelerating the redox kinetics behavior of Li2S. However, the internal redox reaction routes and active sites in the Li-S battery are difficult to observe directly. This study developed a system that combines the light field and in situ irradiated X-ray photoelectron spectroscopy to convert the black box battery into a see-through battery, allowing for direct observation of charge transportation and revealing the mechanism of Li2S decomposition and nucleation.
Article
Chemistry, Physical
Qiang Gao, Junxi Li, Bin Liu, Chenguang Liu
Summary: In this study, a series of direct Z-scheme heterojunction nanocomposites were synthesized and demonstrated significant effects in photocatalytic degradation and Cr(VI) reduction. The optimized sample showed enhanced photocatalytic removal rates and exhibited remarkable activity and stability. This research provides an integrated engineering strategy for Z-scheme photocatalyst systems with high efficiency and extensive applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Ashkan Bahadoran, Seeram Ramakrishna, Saeid Masudy-Panah, Jeffrey Roshan De Lile, Behzad Sadeghi, Jinghan Li, JiaJun Gu, Qinglei Liu
Summary: In this study, hierarchical WO3-CeO2 hollow sphere heterojunctions were prepared via a two-step hydrothermal method and showed enhanced photocatalytic activity, with the highest degradation of sulfamerazine achieved on the WO3-CeO2 heterojunction with 30% CeO2 content. The efficient separation of charge carriers and an S-scheme charge transfer mechanism were the key factors contributing to the improved performance.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Inorganic & Nuclear
J. W. Ben Li, Brendan J. Kennedy
Summary: Four honeycomb structured oxides Na3M2SbO6 (M = Co, Ni, C, Zn) were prepared and characterized. Na3Co2SbO6 showed the highest activity as a Hydrogen Evolution Catalyst (HEC), while Na3Ni2SbO6 was found to be inefficient. The rate of hydrogen evolution was not correlated with the measured bandgap.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Review
Chemistry, Physical
Benjamin Rotonnelli, Marie-Sophie Dias Fernandes, Fabrice Bournel, Jean-Jacques Gallet, Benedikt Lassalle-Kaiser
Summary: Water electrolysis for hydrogen production provides a convenient and carbon-free option to regulate the intermittency of renewable energy sources. Efficient catalysts based on noble metals are currently used for large-scale production, but efforts are being made to reduce catalyst usage while maintaining their efficiency. Fundamental studies on catalyst structure, reaction intermediates, and failure modes support these efforts. Synchrotron-based techniques, such as X-ray photoelectron and X-ray absorption spectroscopies, can provide valuable information during the reaction. This article gives an overview of these techniques and their application to water electrolysis.
CURRENT OPINION IN ELECTROCHEMISTRY
(2023)
Article
Chemistry, Physical
Bingquan Xia, Bowen He, Jianjun Zhang, Laiquan Li, Yanzhao Zhang, Jiaguo Yu, Jingrun Ran, Shi-Zhang Qiao
Summary: In this study, 2D FePS3 nanosheets anchored with TiO2 nanoparticles were synthesized and tested for the photocatalytic hydrogen evolution reaction. The results showed that the photocatalytic activity of the composite material was significantly enhanced. Through various advanced characterizations, the mechanism behind the improved activity was revealed.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Kai Wang, Xiuli Shao, Kaijia Zhang, Juan Wang, Xinhe Wu, Hukun Wang
Summary: Photocatalytic pollutant degradation coupled hydrogen generation via water splitting utilizing solar energy is a promising method for addressing environmental pollution and energy shortage. However, the limited utilization efficiency of solar energy and quick recombination of photogenerated carriers have hindered its application. In this study, a 0D Bi3TaO7 nanodots-decorated 3D ZnIn2S4 nanoflowers photocatalyst was synthesized for efficient simultaneous photocatalytic degradation of antibiotics and hydrogen generation. The relationship between S-scheme heterojunction photocatalysts and photocatalytic pollutant degradation coupled hydrogen evolution will be discussed, along with a careful examination of the interfacial transfer mechanism.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Ashkan Bahadoran, Saeid Masudy-Panah, Jeffrey Roshan De Lile, Jinghan Li, JiaJun Gu, Behzad Sadeghi, Seeram Ramakrishna, Qinglei Liu
Summary: Developing interfacial connections between ZnO nanorods and ZnBi2O4 nanoparticles has successfully improved photocatalytic activity. The highest H-2 production was achieved with the ZnO-20 wt% ZnBi2O4 sample, showing a 12.7 times enhancement compared to pure ZnO.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Kai Wang, Qiang Cheng, Weidong Hou, Huazhang Guo, Xinhe Wu, Juan Wang, Jinmao Li, Zheng Liu, Liang Wang
Summary: This research proposes the rational design of an S-scheme heterojunction in hybrid semiconductors to achieve high photocatalytic activity in diluted CO2 reduction. The Ta2O5/Ag2S nanostructures with an S-scheme heterojunction demonstrate remarkable activity in photocatalytic DCR due to their unique structure and effective charge separation. This study provides a new strategy for designing S-scheme heterojunctions to improve the photocatalytic performance of diluted CO2 conversion.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
N. Ramesh Reddy, P. Mohan Reddy, Jae Hak Jung, Sang Woo Joo
Summary: The discharge of wastewater from the textile industry has a significant impact on global water resource quality. In this study, ZnO/NiO hierarchical nanostructures were synthesized using a simple solvothermal technique for photocatalytic dye degradation. The porous flower-like structures demonstrated high efficiency in degrading azo dyes and showed remarkable reusability.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Yi Yang, Bei Cheng, Jiaguo Yu, Linxi Wang, Wingkei Ho
Summary: An S-scheme heterojunction is constructed in a hybrid TiO2/In2S3 photocatalyst, which greatly promotes the separation of photogenerated carriers and enhances the production of H2O2. Computational methods and experiments are used to study the charge transfer and separation mechanisms within the S-scheme heterojunction.
Article
Green & Sustainable Science & Technology
Shiyu Gao, Sijie Wan, Jiaguo Yu, Shaowen Cao
Summary: The construction of conjugated copolymers with a donor-acceptor system is a promising strategy for improving photocatalytic activity. In this study, a donor-acceptor modified carbon nitride conjugated copolymer was fabricated and showed enhanced photocatalytic hydrogen evolution due to the extended pi-conjugated system and induced intramolecular charge transfer.
ADVANCED SUSTAINABLE SYSTEMS
(2023)
Article
Green & Sustainable Science & Technology
Xidong Zhang, Jiaguo Yu, Wojciech Macyk, S. Wageh, Ahmed A. Al-Ghamdi, Linxi Wang
Summary: In this study, a step-scheme heterojunction photocatalyst C3N4/PDA (CNP) was constructed, which showed improved H2O2 production rate compared to most reported photocatalysts.
ADVANCED SUSTAINABLE SYSTEMS
(2023)
Article
Chemistry, Physical
Min Wu, Jiawei Ye, Bei Cheng, Jiaguo Yu, Liuyang Zhang
Summary: This study successfully synthesized a Pt/NiCo2O4-NF catalyst with excellent formaldehyde oxidation capacity. The nickel foam substrate prevents aggregation of nanowires and promotes uniform dispersion of nanoparticles. The unique properties of NiCo2O4, combined with the hierarchical structure, contribute to the adsorption and oxidation of formaldehyde.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Bo Zhong, Bei Cheng, Yanbing Zhu, Rui Ding, Panyong Kuang, Jiaguo Yu
Summary: This study presents a robust electrode composed of porous nickel foam and Fe-doped Ni3S2 nanosheet arrays for alkaline water electrolysis. The electrode exhibits high catalytic activity and stability, outperforming commercial electrodes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Miaoli Gu, Yi Yang, Liuyang Zhang, Bicheng Zhu, Guijie Liang, Jiaguo Yu
Summary: In this study, an inorganic matrix ZnIn2S4@BiVO4 was constructed as a model catalyst for non-sacrificial photocatalytic H2O2 production, achieving excellent performance under visible-light. The involvement of O-1(2) intermediate in H2O2 generation was discovered, revealing a different reaction pathway.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Taymaz Tabari, Marcin Kobielusz, Agnieszka Jarosz-Duda, Dheerendra Singh, Andrzej Kotarba, Artur Blachowski, Jiaguo Yu, Wojciech Macyk
Summary: Understanding the charge transfer mechanism in the straddle heterojunction architecture is crucial for designing active materials. The synthesis and thorough study of BiVO4, La1-xSrxFeO3-delta perovskites, and BiVO4@La1-xSrxFeO3-delta straddle heterojunction architectures addressed this issue. The insertion of Sr2+ ions into A-sites increased the Fe4+ ions at B-sites, strengthening the Fe-O bond and improving electrocatalytic activity. The increased Fermi levels reduced band bending and enhanced the drift direction of photoinduced charges, leading to significantly higher photocurrent in the heterojunction architecture.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Ping Xie, Xuejie Wang, Zibao Qian, Tao Liu, Jiaguo Yu, Liuyang Zhang
Summary: The volume expansion and poor conductivity of FeS as a sodium-ion battery anode can be alleviated by surface decoration, improving its sodium storage performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Linxi Wang, Jian Sun, Bei Cheng, Rongan He, Jiaguo Yu
Summary: Photocatalysis provides a low-cost, clean and sustainable process for H2O2 production, but electron-hole recombination and slow reaction kinetics hinder its practical application. The solution lies in constructing S-scheme heterojunctions to enhance carrier separation and boost redox power. This Perspective summarizes recent advances in S-scheme photocatalysts for H2O2 production, including building heterojunctions, H2O2-production performance, and photocatalytic mechanisms. Future research directions and strategies to improve H2O2 yields are suggested.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Multidisciplinary Sciences
Shengyao Wang, Bo Jiang, Joel Henzie, Feiyan Xu, Chengyuan Liu, Xianguang Meng, Sirong Zou, Hui Song, Yang Pan, Hexing Li, Jiaguo Yu, Hao Chen, Jinhua Ye
Summary: Tracking the products of CO2 photoreduction is challenging due to low conversion efficiency and carbon contamination. Isotope-tracing experiments are commonly used but often yield false-positive results. Accurate and effective strategies for evaluating CO2 photoreduction products are needed.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Bowen He, Peng Xiao, Sijie Wan, Jianjun Zhang, Tao Chen, Liuyang Zhang, Jiaguo Yu
Summary: This study utilizes Ni-doped Zn0.2Cd0.8S quantum dots coupled with TiO2 microspheres to enhance the photocatalytic performance by modulating active sites and built-in electric fields in a step-scheme heterojunction.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Peiyu Hu, Guijie Liang, Bicheng Zhu, Wojciech Macyk, Jiaguo Yu, Feiyan Xu
Summary: Exploring photocatalysts for CO2 conversion is a promising approach for mitigating energy scarcity and environmental pollution. In this study, SnO2/Cs3Bi2Br9 heterojunctions were constructed to enhance CO2 photoreduction. The unique structure enabled efficient separation of photoexcited electron/hole pairs and demonstrated excellent selectivity for CH4 production.
Article
Chemistry, Physical
Hongying Li, Bicheng Zhu, Jian Sun, Haiming Gong, Jiaguo Yu, Liuyang Zhang
Summary: Compared to hydrogen production through pure water photocatalysis, utilizing seawater directly for hydrogen production is more in line with the principles of sustainable development. RuO2 and TiO2 have been widely recognized to exhibit good stability in seawater. This study investigates hydrogen production in simulated seawater using a RuO2-modified TiO2 model system. The results show that the hydrogen production activity of TiO2/RuO2 nanofibers in simulated seawater is comparable to that in pure water.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Review
Chemistry, Multidisciplinary
Bicheng Zhu, Jian Sun, Yanyan Zhao, Liuyang Zhang, Jiaguo Yu
Summary: Semiconductor photocatalytic technology has significant applications and can be enhanced by constructing 2D S-scheme heterojunction photocatalysts, which can efficiently separate charges and maximize redox capabilities.
ADVANCED MATERIALS
(2023)