4.7 Article

Facile fabrication of mesoporous poly(ethylene-co-vinyl alcohol)/chitosan blend monoliths

Journal

CARBOHYDRATE POLYMERS
Volume 132, Issue -, Pages 345-350

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2015.06.040

Keywords

Poly(ethylene-co-vinyl alcohol); Chitosan; Thermally-induced phase separation; Monolith; Chelation

Funding

  1. Japan Society for Promotion of Science [25288090]
  2. Project for Creating Start-ups from Advanced Research and Technology
  3. MEXT
  4. Grants-in-Aid for Scientific Research [25288090] Funding Source: KAKEN

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Poly(ethylene-co-vinyl alcohol) (EVOH)/chitosan blend monoliths were fabricated by thermally-induced phase separation method. Chitosan was successfully incorporated into the polymeric monolith by selecting EVOH as the main component of the monolith. SEM images exhibit that the chitosan was located on the inner surface of the monolith. Fourier-transform infrared analysis and elemental analysis indicate the successful blend of EVOH and chitosan. BET results show that the blend monoliths had high specific surface area and uniform mesopore structure. Good adsorption ability toward various heavy metal ions was found in the blend monoliths due to the large chelation capacity of chitosan. The blend monoliths have potential application for waste water purification or bio-related applications. (C) 2015 Elsevier Ltd. All rights reserved.

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