Mechanistic study on the dynamic interfacial tension of crude oil plus water systems: Experimental and modeling approaches

This study investigates dynamic interfacial tension (DIFT) of acidic crude oil (ACO) and non acidic/basic crude oils (BCO) + deionized water (DW) as a function of pressure from 500 to 4000 psi, and temperature from 30 to 80 degrees C using an axisymmetric drop shape analysis (ADSA) technique. DIFTs are also modeled using dynamic adsorption model, mono-exponential decay model, and empirical equations. The results showed that if a reduction in the surface excess concentration due to increasing temperature overlooks the total entropy of the molecules in the system, an increase in IFT would be expected. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.