Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 38, Issue -, Pages 181-185Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2016.05.001
Keywords
Oxidation reaction; 5-Hydroxymethylfurfural; Furan chemicals; Ruthenium catalyst; Molecular oxygen
Funding
- National Natural Science Foundation of China [21203252]
- Chenguang Youth Science and Technology Project of Wuhan [2014070404010212]
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In this study, a new ruthenium catalyst was used for the oxidation of biomass derived 5-hydroxymethylfurfural (HMF) under mild conditions, which was prepared by the exchange of Ru3+ with H+ in the structure of the zirconium phosphate (ZrP). The as-prepared ZrP-Ru catalyst showed high catalytic activity towards the oxidation of HMF, affording 100% of HMF conversion at 130 degrees C after 12 h under atmospheric oxygen pressure. 2,5-Furandicarboxylic acid (FDCA) and 2,5-diformylfuran (DFF) were detected to be the major oxidation products. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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