Article
Engineering, Environmental
Wenqing Luo, Xin Zhao, Gongting Wang, Zedong Teng, Yali Guo, Xiaonan Ji, Wei Hu, Min Li
Summary: The effects of humic acids (HA) and fulvic acids (FA) on the fate of Cd in anaerobic environment were investigated. The results showed that HA and FA could promote the reductive dissolution of Cd-bearing ferrihydrite and the formation of vivianite. HA was better than FA in immobilizing Cd.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Environmental Sciences
Jinlong Peng, Fenglian Fu, Chujia Ye, Bing Tang
Summary: The study found that fulvic acid had different effects on Fh-Se transformation at different pH values. Fulvic acid promoted Fh-Se transformation at initial pH 5.0, inhibited it at initial pH 10.0, and had varying effects at initial pH 7.5 depending on the C/Fe ratio. Fulvic acid induced the generation of more extractable Se(IV) at pH 5.0, more coprecipitated Se(IV) at pH 7.5, and blocked the release of Se(IV) at pH 10.0.
ENVIRONMENTAL POLLUTION
(2022)
Article
Environmental Sciences
Eduardo Gutierrez, Eduardo Chavez, Kasuni H. H. Gamage, David Arguello, Madhubhashini B. Galkaduwa, Ganga M. Hettiarachchi
Summary: The study investigated the effect of compost application on the soil Cd concentration in cacao farms and found that compost application can reduce the soluble Cd content in the soil. Additionally, it was found that compost application increases the Cd bound to humic acids in the soil, thereby reducing its availability to plants. Furthermore, the quality of the compost applied also plays a role in mitigating Cd contamination.
FRONTIERS IN ENVIRONMENTAL SCIENCE
(2022)
Article
Agronomy
Ondrej Sedlar, Jiri Balik, Jindrich Cerny, Martin Kulhanek, Michaela Smatanova
Summary: The quality of soil organic matter is crucial for soil structure, carbon sequestration, and pollutant immobilization. A study was conducted in Central Europe to investigate the effect of fertilization on soil organic matter quality after 16-23 years of treatment. Different crop rotations and fertilization treatments were evaluated, and the results showed that the C/N ratio of applied organic fertilizers had a significant correlation with humic acid carbon (C-HA) content, C-HA/C-FA ratio, and humification index in soil. The combination of farmyard manure and mineral fertilization resulted in higher levels of humic acid carbon content, humification rate, and humification index compared to other treatments.
Article
Environmental Sciences
Jialin Chi, Yanan Ou, Fangbai Li, Wenjun Zhang, Hang Zhai, Tongxu Liu, Qing Chen, Xiaoxia Zhou, Liping Fang
Summary: Phosphate and dissolved organic matter (DOM) play a role in the crystalline transformation of ferrihydrite in subsurface environments, inhibiting the process through synergistic effects of recrystallization and electron transfer inhibition. Phosphate can be retained on the surface or transformed to a nonextractable form, while DOM can be released into the solution or preserved in an extractable form. Analysis shows even distribution of phosphate on newly formed Fe oxyhydroxides, while the distribution of DOM depends on its specific species.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Changsheng Jin, Zhongwu Li, Mei Huang, Xiang Ding, Mi Zhou, Jia Chen, Bolin Li
Summary: Manganese oxide minerals (MnOs) have a significant influence on the mobility and fate of cadmium (Cd) in the environment. However, the presence of natural organic matter (OM) coating on MnOs complicates the retention and availability of harmful metals. This study synthesized organo-mineral composites using birnessite and fulvic acid (FA) and investigated their performance and underlying mechanism in Cd(II) adsorption. The results showed that the interaction between FA and MnOs significantly increased the adsorption capacity of Cd(II) due to the enhanced dispersion of MnOs particles and increased specific surface area. The dominant Cd(II) adsorption mechanism was identified as precipitation with minerals and complexation with Mn-O groups and acid oxygen-containing functional groups of FA. The findings contribute to a better understanding of Cd behavior in the environment and have implications for the remediation of Cd-contaminated water and soil using organo-mineral composites.
Article
Environmental Sciences
Zhe Zhou, Drew E. Latta, Michelle M. Scherer
Summary: The study showed that the presence of natural organic matter (NOM) inhibits the Fe(II)-catalyzed transformation of ferrihydrite (Fh). Nickel associated with SRNOM-Fh was found to be more susceptible to acid extraction compared to Fh in the presence of Fe(II). Transformation to secondary minerals may be necessary for nickel stabilization to occur.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Biochemistry & Molecular Biology
Xiaojing Chen, Xin Zhang, Hao Chen, Xiaoming Xu
Summary: This study found that Fulvic acid (FA) plays a significant role in alleviating Cd toxicity in lettuce. FA can increase the expression of photosynthetic proteins, reduce Cd uptake by roots, and enhance sulfur metabolism in cells, thereby improving photosynthetic performance and biomass of lettuce under Cd stress.
Article
Environmental Sciences
Lei He, Dao-You Huang, Bo Liu, Quan Zhang, Han-Hua Zhu, Chao Xu, Qi-Hong Zhu
Summary: The combined application of selenium and humic substances can effectively reduce the cadmium content in rice grains and inhibit selenium accumulation, providing a cost-effective measure to mitigate cadmium contamination risks in paddy soil.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Environmental Sciences
Xiaoming Zhao, Zidan Yuan, Shaofeng Wang, Yuanming Pan, Ning Chen, Ayetullah Tunc, Kalong Cheung, Aslan Alparov, Weifeng Chen, Reza Deevsalar, Jinru Lin, Yongfeng Jia
Summary: The factors and mechanisms affecting the fate of Cd during the transformation of Cd-bearing ferrihydrite activated by Fe(II) under anaerobic conditions has been studied. The results show that pH, Fe(II) and Cd concentrations all have significant effects on the rates and pathways of the ferrihydrite transformation. High Cd loading inhibits the transformation rates and alters the transformation pathways. Cd is released into the solution during the ferrihydrite transformation, and a significant amount of Cd is transformed into an unextractable form. The release of Cd is enhanced by reducing the pH or increasing the Cd concentration.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Environmental Sciences
Chen Xu, Peng Lin, Ravindranath Garimella, Dien Li, Wei Xing, Nicole E. Patterson, Daniel Kaplan, Chris M. Yeager, Patrick G. Hatcher, Peter H. Santschi
Summary: The complex behavior of iodine isotopes and their interaction with natural organic matter pose a challenge for transport models. This study investigates the iodination of humic and fulvic acid and shows how it chemically alters the behavior of these organic matter, potentially affecting their mobility in the environment.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Engineering, Environmental
Yang Ding, Xixian Huang, Hui Zhang, Dexin Ding
Summary: This study evaluated the associations between DOM and U during the coprecipitation of DOM with Fh, and investigated the effects of DOM molecules on the kinetics of U release during Fe (oxyhydr)oxides transformation. The results showed that phenolic and polyphenolic compounds with different O/C ratios and aliphatic compounds contributed to UO22+ binding when Fh coprecipitated with DOM. In contrast, phenolic and polyphenolic compounds with higher O/C ratios and condensed aromatics were preferentially retained on Fe (oxyhydr)oxides during the transformation. XPS results suggested that the coprecipitated DOM molecules facilitated the reduction of U(VI) to U(IV) during the transformation.
Article
Environmental Sciences
Huihui Du, Ning Nie, Wenkai Rao, Lei Lu, Ming Lei, Boqing Tie
Summary: Research findings suggest that the coadsorption behavior of Cd-As on organomineral composites differs from that on pure minerals, and the presence of organics significantly affects the speciation and distribution of metals (loids). Organomineral composites are a more suitable analog than pure mineral phases to predict the mobility and fate of Cd-As in natural environments.
ENVIRONMENTAL POLLUTION
(2021)
Article
Soil Science
Jine Wei, Fenfen Zhang, Tangrong He, Jinzhou Du, Lijun Hou, Huan Feng
Summary: This study aimed to investigate the influence of organic carbon to iron molar ratio, ionic strength, and organic matter composition on the association of iron with organic matter. The results showed that different association modes, molar ratios, composition, and ionic strength affected the selective association of different organic matter components with iron oxide.
Article
Engineering, Environmental
Xilin Xiao, Leanne C. Powers, Jihua Liu, Michael Gonsior, Rui Zhang, Lianbao Zhang, Hugh L. MacIntyre, Xiaowei Chen, Chen Hu, John Batt, Qiang Shi, Dapeng Xu, Yao Zhang, Nianzhi Jiao
Summary: A study found that microbial processes play important roles in the transformation of terrigenous organic matter (TOM) during freshwater-seawater mixing, including the biodegradation of dissolved organic matter, changes in bacterial community structure and diversity. In addition, the sinking of surface-derived TOM may lead to increased transformation of dissolved organic matter and carbon storage in the bottom water.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Geochemistry & Geophysics
Xinze Lu, Geoffrey J. Gilleaudeau, Brian Kendall
Summary: The Late Ordovician mass extinction is the first major extinction event in the Phanerozoic, but the reasons for the decline in global biodiversity before the extinction are not well understood.
GEOCHIMICA ET COSMOCHIMICA ACTA
(2024)
Article
Geochemistry & Geophysics
Junyao Kang, Daniel D. Gregory, Benjamin Gill, Shiqiang Huang, Changxin Lai, Zhaoshan Chang, Huan Cui, Ivan Belousov, Shuhai Xiao
Summary: Sedimentary pyrite is an important geological archive, but it can be altered by diagenetic and hydrothermal processes. This study successfully trained machine learning algorithms to distinguish pyrite origins using trace element data. The approach was validated and applied to identify the origins of pyrite in two sedimentary successions in South China.
GEOCHIMICA ET COSMOCHIMICA ACTA
(2024)