Journal
ENVIRONMENTAL POLLUTION
Volume 313, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2022.120154
Keywords
Hydrogenolysis; Polyethylene; Non-noble metal catalyst; Mulching film waste
Categories
Funding
- National Natural Science Foundation of China [LQ21B030009, 51906215]
- Fundamental Research Funds for the Central Universities and Zhejiang Province Natural Science Foundation of China [22102147]
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The study shows that Ni/SiO2 catalyst exhibits high activity in the hydrogenolysis of polyethylene, producing up to 81.18% gasoline and diesel range hydrocarbons under relatively mild conditions. The gas products are primarily CH4, along with small amounts of C2H6 and C3H8, and a high yield of CH4 up to 9.68% was observed for molecule cleavage along the alkane chain.
The catalytic hydrogenolysis of a typical model compound of mulching film waste, polyethylene, was investi-gated as a potential way to improve economic efficiency of mulching film recycling. Nickel-based heterogeneous catalysts are proposed for polyethylene hydrogenolysis to produce liquid hydrocarbons. Among catalysts sup-ported on various carriers, Ni/SiO2 catalyst shows the highest activity which may due to the interactions between nickel and silica with the formation of nickel phyllosilicate. As high as 81.18% total gasoline and diesel range hydrocarbon was obtained from the polyethylene hydrogenolysis at relatively mild condition of 280 ?, and 3 MPa cold hydrogen pressure. The result is comparable to what have been reported in previous studies using noble metal catalysts. The gasoline and diesel range hydrocarbon are n-alkanes with a distribution at a range of C-4-C-22. The gas products are primarily CH4 along with a small amount of C2H6 and C3H8. High yield of CH4 as much as 9.68% was observed for the cleavage of molecule occurs along the alkane chain.
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