Journal
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
Volume 160, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2022.107063
Keywords
A; Graphene; Nanocomposites; Thin films; B; Electrical properties
Funding
- National Natural Science Foundation of China [52103043]
- State Key Laboratory of Polymer Materials Engineering [sklpme2022-3-04]
- Fundamental Research Funds for the central Universities [YJ201971]
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This study successfully fabricated highly flexible and highly conductive graphene nanosheets (GNS) nanofiber films using aramid nanofibers as dispersants and binders. The films exhibited superior electromagnetic interference (EMI) shielding effectiveness, as well as excellent thermostability and nonflammability.
Graphene nanosheets (GNSs) hold tremendous potential for electromagnetic interference (EMI) shielding applications. However, fabricating highly conductive freestanding GNS shielding films remains challenging due to their poor dispersion and weak film-forming ability. Herein, aramid nanofibers (ANFs) were used as both a dispersant and binder to address the dispersion and film-forming problem of GNSs. Only 20 wt% ANF yielded a homogeneous GNS dispersion without precipitation after standing for 100 days. The resultant GNS/ANF films exhibited ultraflexibility and high electrical conductivity (12141.5 S/m). A superior EMI shielding effectiveness of 35.6 dB was achieved for the GNS/ANF films (20 mu m thick). The GNS/ANF films also exhibited excellent thermostability and nonflammability. This study opens an avenue for the assembly of GNSs into highly conductive freestanding films, showing strong potential applications in EMI shielding for modern high-power electronic devices.
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