The sintering analysis of biomass waste ash based on the in-situ exploration and thermal chemical calculation in the gasification process

The plentiful biomass wastes are promising fossil energy alternatives to generate indispensable energy. Biomass gasification is an effective way of producing high-value-added productions and reducing CO2 emissions. However, some ash-related issues, especially ash sintering, restrict the wide utilization of biomass energies. To minimize the negative effect of the sintering problem, this work studied the ash sin-tering process of typical cornstalk waste ash by in-situ experimental methods, including high-temperature stage microscope (HTSM) and thermomechanical analysis (TMA). Then the thermochemical calculation was combined to clarify the sintering mechanism. The result indicated that sintering was the first step during the ash fusion process. The initial sintering temperature (624 degrees C) was lower than the ash deforma-tion temperature (919 degrees C), which was the first characteristic temperature of ash fusion tests. The chemical reaction of the inherent ash-related components was the main reason for the appearance of the initial sintering temperature. From the element perspective, the chemical reaction of alkali and alkali earth met-als (AAEMs) was mainly involved. The alkali metals tended to react with SiO2 while alkali earth metals were prone to combine with P2O5. Except for ash sintering behavior during the heating process, the TMA trace showed another two stages, swelling and melting. Massive bubbles would be generated from the inside melts at the swelling stage and cause the drastic fluctuation of the ash-melting system until the end of the melting range. Moreover, the high heating rate was beneficial for alleviating the initial sin-tering temperature while having a tiny influence on changing the total range of sintering and swelling zones.(c) 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

Automated summary

The plentiful biomass wastes are a promising alternative to generate indispensable energy. Biomass gasification is effective in producing high-value-added products and reducing CO2 emissions. However, the wide utilization of biomass energies is restricted by ash-related issues, especially ash sintering. This study investigated the ash sintering process of cornstalk waste ash and clarified the sintering mechanism through in-situ experimental methods and thermochemical calculation.