4.8 Article

Salt template assisted synthesis of Fe@graphene for high-performance electromagnetic wave absorption

Journal

CARBON
Volume 199, Issue -, Pages 268-278

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2022.07.072

Keywords

Salt template assisted pyrolysis; Iron phthalocyanine derived carbon; Microwave absorption; Impedance matching; Finite element simulation

Funding

  1. Sichuan Science and Tech- nology Program [2020YFG0372]

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With the deterioration and complexity of the electromagnetic environment, there is an increasing demand for thin, light, and wideband electromagnetic wave absorbing materials. Graphene-based composites are considered as potential candidates for future microwave absorbing materials. In this study, Fe@graphene was prepared using a modified salt template method and iron phthalocyanine as the carbon source. The Fe@graphene achieved excellent electromagnetic wave absorption performance with an effective absorption bandwidth of 7.9 GHz at a filling level of 1 wt%. The effect of material dispersion and cubic structure was also investigated using finite element simulation.
As the electromagnetic environment becomes increasingly deteriorated and complex, there is an increasing ur-gency for electromagnetic wave absorbing materials with thin, light, and wide strength characteristics. Graphene-based composites are considered candidates for the next generation of microwave absorbing materials. To realize the large-scale preparation of graphene-based materials, we utilize a modified salt template assisted pyrolysis method and innovatively chose iron phthalocyanine as the carbon source to prepare Fe@graphene. KCl cubic templates are prepared using an anti-solvent method, and iron phthalocyanine is pyrolyzed on the surface to form graphene and loaded with Fe particles in situ. The prepared Fe@graphene achieves extremely excellent electromagnetic wave absorption performance, with an effective absorption bandwidth of 7.9 GHz at a filling level of only 1 wt%. The effect of material dispersion and cubic structure is also investigated in this paper using finite element simulation.

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