4.7 Article

Cotton fabrics with antibacterial and antiviral properties produced by a simple pad-dry-cure process using diphenolic acid

Journal

APPLIED SURFACE SCIENCE
Volume 600, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2022.154152

Keywords

Diphenolic acid; Antibacterial effect; Antiviral capability; Cotton fabric; Pad-dry-cure process

Funding

  1. National Natural Science Foundation of China [51873195, 51803186, 51573167]

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In this study, diphenolic acid (DPA) was used as a finishing reagent to impart antibacterial and antiviral functions to cotton fabric. The DPA molecules were covalently linked onto cotton fiber surfaces through esterification reaction. The DPA modified fabrics showed high bacteriostatic reduction rates (BR) against Escherichia coli and Staphylococcus aureus, as well as rapid virus inactivation within 20 minutes. The modification process did not cause significant damage to the cotton fiber structure, and the resulting fabrics were safe for human skin.
In the present work, diphenolic acid (DPA), a sustainable green platform chemical, was employed as a finishing reagent to impart antibacterial and antiviral functions to cotton fabric. After a simple pad-dry-cure process, DPA molecules were covalently linked onto cotton fiber surfaces via the esterification reaction between their carboxyl groups and the hydroxyl groups of cellulose on the fiber surfaces. The DPA phenolic groups induced onto the cotton fibers enable to destroy pathogens by protein affinity interaction. Experimental results show that the DPA modified fabrics realize not only high bacteriostatic reduction rates (BR) against both Escherichia coli and Staphylococcus aureus, but also show excellent antivirus effect that allow a rapid virus inactivation shorter than 20 min. It was also demonstrated that the modification process generated insignificant damage on the cotton fiber structure, and the resultant cotton fabrics are safe for human skin. Therefore, this work may open a new way to endow cotton textiles with antibacterial and antiviral functions.

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