Click Step-Growth Polymerization and E/Z Stereochemistry Using Nucleophilic Thiol–yne/–ene Reactions: Applying Old Concepts for Practical Sustainable (Bio)Materials

Ultra‐Tough Elastomers from Stereochemistry‐Directed Hydrogen Bonding in Isosorbide‐Based Polymers

(2022) Shannon R. Petersen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Shape Memory Behavior of Biocompatible Polyurethane Stereoelastomers Synthesized via Thiol–Yne Michael Addition

(2022) Yen-Hao Hsu et al.   BIOMACROMOLECULES

Sugar-Based Polymers with Stereochemistry-Dependent Degradability and Mechanical Properties

(2022) Connor J. Stubbs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concomitant control of mechanical properties and degradation in resorbable elastomer-like materials using stereochemistry and stoichiometry for soft tissue engineering

(2021) Mary Beth Wandel et al.   Nature Communications

Crosslinked Internal Alkyne-Based Stereo Elastomers: Polymers with Tunable Mechanical Properties

(2021) Yen-Hao Hsu et al.   MACROMOLECULES

Using stereochemistry to control mechanical properties in thiol‐yne click‐hydrogels

(2021) Laura Macdougall et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Isohexide Diyne Polymers and Hydrogenation to Their Saturated Polyethers

(2021) Ethan A. Gormong et al.   ACS Macro Letters

Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets

(2021) Anissa L. Khalfa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elastomeric polyamide biomaterials with stereochemically tuneable mechanical properties and shape memory

(2020) Joshua C. Worch et al.   Nature Communications

Fluorinated Polymers via Para‐Fluoro‐Thiol and Thiol‐Bromo Click Step Growth Polymerization

(2020) Tieshuai Zhao et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Sustainable and recyclable super engineering thermoplastic from biorenewable monomer

(2019) Seul-A Park et al.   Nature Communications

Stereochemical enhancement of polymer properties

(2019) Joshua C. Worch et al.   Nature Reviews Chemistry

Extremely rapid postfunctionalization of maleate and fumarate main chain polyesters in the presence of TBD

(2019) Ozgun Daglar et al.   POLYMER

Unsaturated Poly(ester-urethanes) with Stereochemically Dependent Thermomechanical Properties

(2019) Connor J. Stubbs et al.   MACROMOLECULES

Next-generation polymers: Isosorbide as a renewable alternative

(2019) Derek J. Saxon et al.   PROGRESS IN POLYMER SCIENCE

Design of synthetic extracellular matrices for probing breast cancer cell growth using robust cyctocompatible nucleophilic thiol-yne addition chemistry

(2018) Laura J. Macdougall et al.   BIOMATERIALS

Sugar-Derived Poly(β-thioester)s as a Biomedical Scaffold

(2018) Nicholas G. Moon et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Degradable and renewably-sourced poly(ester-thioethers) by photo-initiated thiol–ene polymerization

(2018) Leon M. Lillie et al.   Polymer Chemistry

Self-healing, stretchable and robust interpenetrating network hydrogels

(2018) Laura J. Macdougall et al.   Biomaterials Science

Structure/property relationships in copolymers comprising renewable isosorbide, glucarodilactone, and 2,5-bis(hydroxymethyl)furan subunits

(2017) Leon M. Lillie et al.   Polymer Chemistry

Organocatalyzed synthesis of fluorinated poly(aryl thioethers)

(2017) Nathaniel H. Park et al.   Nature Communications

Efficient In Situ Nucleophilic Thiol-yne Click Chemistry for the Synthesis of Strong Hydrogel Materials with Tunable Properties

(2017) Laura J. Macdougall et al.   ACS Macro Letters

Metrics of Green Chemistry and Sustainability: Past, Present, and Future

(2017) Roger A. Sheldon   ACS Sustainable Chemistry & Engineering

Independent Control of Elastomer Properties through Stereocontrolled Synthesis

(2016) Craig A. Bell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-Osmotic Hydrogels: A Rational Strategy for Safely Degradable Hydrogels

(2016) Hiroyuki Kamata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound

(2016) Ryo Tanaka et al.   Polymer Chemistry

Extremely rapid and versatile synthesis of high molecular weight step growth polymers via oxime click chemistry

(2016) Joe Collins et al.   Polymer Chemistry

Kinetics of bulk photo-initiated copper(i)-catalyzed azide–alkyne cycloaddition (CuAAC) polymerizations

(2016) Han Byul Song et al.   Polymer Chemistry

Thiol–ene Click Hydrogels for Therapeutic Delivery

(2016) Prathamesh M. Kharkar et al.   ACS Biomaterials-Science & Engineering

Thiol–ene Click Hydrogels for Therapeutic Delivery

(2016) Prathamesh M. Kharkar et al.   ACS Biomaterials Science & Engineering

Synthetic Polymers from Sugar-Based Monomers

(2015) Juan A. Galbis et al.   CHEMICAL REVIEWS

Sustainable Polyesters Derived from Glucose and Castor Oil: Building Block Structure Impacts Properties

(2015) William C. Shearouse et al.   ACS Macro Letters

SuFEx-Based Synthesis of Polysulfates

(2014) Jiajia Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiol-epoxy polymerization via an AB monomer: Synthetic access to high molecular weight poly(β-hydroxythio-ether)s

(2014) Selmar Binder et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

"Nonswellable" Hydrogel Without Mechanical Hysteresis

(2014) H. Kamata et al.   SCIENCE

Organocatalytic, Regioselective Nucleophilic “Click” Addition of Thiols to Propiolic Acid Esters for Polymer-Polymer Coupling

(2013) Vinh X. Truong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isomerization-Free Polycondensations of Cyclic Anhydrides with Diols and Preparation of Polyester Gels Containing Cis or Trans Carbon Double Bonds via Photo-Cross-Linking and Isomerization in the Gels

(2013) Tang Tang et al.   MACROMOLECULES

Kinetic comparison of 13 homogeneous thiol–X reactions

(2013) Le-Thu T. Nguyen et al.   Polymer Chemistry

Highly functionalized, aliphatic polyamides via CuAAC and thiol-yne chemistries

(2012) Leen Billiet et al.   EUROPEAN POLYMER JOURNAL

A novel polymerization approach via thiol-yne addition

(2012) Oğuz Türünç et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis and Functionalization of Thiol-Reactive Biodegradable Polymers

(2012) Sebla Onbulak et al.   MACROMOLECULES

Thiol–epoxy ‘click’ polymerization: efficient construction of reactive and functional polymers

(2012) Andreas Brändle et al.   Polymer Chemistry

Ring-Opening Copolymerization of Maleic Anhydride with Epoxides: A Chain-Growth Approach to Unsaturated Polyesters

(2011) Angela M. DiCiccio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Functionalization of Linear Polyurethanes by Thiol-Maleimide Coupling Reactions

(2011) Leen Billiet et al.   MACROMOLECULES

Synthesis and post-polymerization modification of maleimide-containing polymers by ‘thiol-ene’ click and Diels-Alder chemistries

(2011) Daniel J. Hall et al.   POLYMER INTERNATIONAL

Metal-Free Alkyne Polyhydrothiolation: Synthesis of Functional Poly(vinylenesulfide)s with High Stereoregularity by Regioselective Thioclick Polymerization

(2010) Cathy K. W. Jim et al.   ADVANCED FUNCTIONAL MATERIALS

Thiol-Yne Chemistry: A Powerful Tool for Creating Highly Functional Materials

(2010) Richard Hoogenboom   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiol-Ene Click Chemistry

(2010) Charles E. Hoyle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decoupled control of stiffness and permeability with a cell-encapsulating poly(ethylene glycol) dimethacrylate hydrogel

(2010) Chaenyung Cha et al.   BIOMATERIALS

Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis

(2010) Andrew B. Lowe et al.   JOURNAL OF MATERIALS CHEMISTRY

Limitations of radical thiol-ene reactions for polymer-polymer conjugation

(2010) Sandy P. S. Koo et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of Stereoregular Cyclic Poly(lactide)s via “Thiol−Ene” Click Chemistry

(2010) Matthew J. Stanford et al.   MACROMOLECULES

Nucleophile-Initiated Thiol-Michael Reactions: Effect of Organocatalyst, Thiol, and Ene

(2010) Justin W. Chan et al.   MACROMOLECULES

Thiol−Yne Click Polymerization: Regio- and Stereoselective Synthesis of Sulfur-Rich Acetylenic Polymers with Controllable Chain Conformations and Tunable Optical Properties

(2010) Jianzhao Liu et al.   MACROMOLECULES

Biodegradable Polymer Crosslinker: Independent Control of Stiffness, Toughness, and Hydrogel Degradation Rate

(2009) Chaenyung Cha et al.   ADVANCED FUNCTIONAL MATERIALS

Electron-Deficient Alkynes as Cleavable Reagents for the Modification of Cysteine-Containing Peptides in Aqueous Medium

(2009) Hoi-Yan Shiu et al.   CHEMISTRY-A EUROPEAN JOURNAL

“Clicking” Polymer Brushes with Thiol-yne Chemistry: Indoors and Out

(2009) Ryan M. Hensarling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isomerization-Free Polycondensations of Maleic Anhydride with α,ω-Alkanediols

(2009) Hans R. Kricheldorf et al.   MACROMOLECULES

Copper-Catalyzed vs Thermal Step Growth Polymerization of Starch-Derived α-Azide−ω-Alkyne Dianhydrohexitol Stereoisomers: To Click or Not To Click?

(2009) Céline Besset et al.   MACROMOLECULES

Polymers from renewable 1,4:3,6-dianhydrohexitols (isosorbide, isomannide and isoidide): A review

(2009) F. Fenouillot et al.   PROGRESS IN POLYMER SCIENCE

Metal free thiol–maleimide ‘Click’ reaction as a mild functionalisation strategy for degradable polymers

(2008) Ryan J. Pounder et al.   CHEMICAL COMMUNICATIONS

Kinetic study of copper(I)‐catalyzed click chemistry step‐growth polymerization

(2008) Sandra Binauld et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Thiol−Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks

(2008) Benjamin D. Fairbanks et al.   MACROMOLECULES