Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons

Formation and Fate of Formaldehyde in Methanol-to-Hydrocarbon Reaction: In Situ Synchrotron Radiation Photoionization Mass Spectrometry Study

(2020) Wu Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Operando Photoelectron Photoion Coincidence Spectroscopy Unravels Mechanistic Fingerprints of Propane Activation by Catalytic Oxyhalogenation

(2020) Guido Zichittella et al.   Journal of Physical Chemistry Letters

Establishing a Link Between the Dual Cycles in Methanol-to-Olefins Conversion on H-ZSM-5: Aromatization of Cycloalkenes

(2020) Min Hu et al.   ACS Catalysis

Methylcyclopentenyl Cations Linking Initial Stage and Highly Efficient Stage in Methanol-to-Hydrocarbon Process

(2020) Wenna Zhang et al.   ACS Catalysis

Insight into the effects of confined hydrocarbon species on the lifetime of methanol conversion catalysts

(2020) I. Lezcano-Gonzalez et al.   NATURE MATERIALS

Quantification of Redox Sites during Catalytic Propane Oxychlorination by Operando EPR Spectroscopy

(2020) Guido Zichittella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification of the Reaction Sequence of the MTO Initiation Mechanism Using Ab Initio-Based Kinetics

(2019) Philipp N. Plessow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Critical role of formaldehyde during methanol conversion to hydrocarbons

(2019) Yue Liu et al.   Nature Communications

Role of Acetaldehyde in the Roadmap from Initial Carbon–Carbon Bonds to Hydrocarbons during Methanol Conversion

(2019) Liu Yang et al.   ACS Catalysis

A Method for Assessing Catalyst Deactivation: A Case Study on Methanol-to-Hydrocarbons Conversion

(2019) Brandon L. Foley et al.   ACS Catalysis

Kinetic and Deactivation Differences Among Methanol, Dimethyl Ether and Chloromethane as Stock for Hydrocarbons

(2019) José Valecillos et al.   ChemCatChem

The radical internal coke structure as a fingerprint of the zeolite framework

(2019) Karima Ben Tayeb et al.   MICROPOROUS AND MESOPOROUS MATERIALS

First molecule with carbon–carbon bond in methanol-to-olefins process

(2019) Kailu Zang et al.   CHEMICAL PHYSICS LETTERS

Aluminum Redistribution in ZSM-5 Zeolite upon Interaction with Gaseous Halogens and Hydrogen Halides and Implications in Catalysis

(2019) Vladimir Paunović et al.   Journal of Physical Chemistry C

Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol-to-Hydrocarbons Process

(2018) Abhishek Dutta Chowdhury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extra-Framework Aluminum-Assisted Initial C−C Bond Formation in Methanol-to-Olefins Conversion on Zeolite H-ZSM-5

(2018) Chao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deactivation of Zeolite Catalyst H-ZSM-5 during Conversion of Methanol to Gasoline: Operando Time- and Space-Resolved X-ray Diffraction

(2018) Daniel Rojo-Gama et al.   Journal of Physical Chemistry Letters

Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process

(2018) Irina Yarulina et al.   Nature Chemistry

The Curious Case of Ketene in Zeolite Chemistry and Catalysis

(2018) Abhishek Dutta Chowdhury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Origin and evolution of the initial hydrocarbon pool intermediates in the transition period for the conversion of methanol to olefins over H-ZSM-5 zeolite

(2018) Sen Wang et al.   JOURNAL OF CATALYSIS

CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies

(2017) Bálint Sztáray et al.   JOURNAL OF CHEMICAL PHYSICS

Understanding the mechanism of catalytic fast pyrolysis by unveiling reactive intermediates in heterogeneous catalysis

(2017) Patrick Hemberger et al.   Nature Communications

Unraveling the Mechanism of the Initiation Reaction of the Methanol to Olefins Process Using ab Initio and DFT Calculations

(2017) Philipp N. Plessow et al.   ACS Catalysis

Insights into the Activity and Deactivation of the Methanol-to-Olefins Process over Different Small-Pore Zeolites As Studied with Operando UV–vis Spectroscopy

(2017) Joris Goetze et al.   ACS Catalysis

New insights into catalyst deactivation and product distribution of zeolites in the methanol-to-hydrocarbons (MTH) reaction with methanol and dimethyl ether feeds

(2017) Juan S. Martinez-Espin et al.   Catalysis Science & Technology

Initial Carbon-Carbon Bond Formation during the Early Stages of the Methanol-to-Olefin Process Proven by Zeolite-Trapped Acetate and Methyl Acetate

(2016) Abhishek Dutta Chowdhury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation Mechanism of the First Carbon-Carbon Bond and the First Olefin in the Methanol Conversion into Hydrocarbons

(2016) Yue Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis: Challenges and Opportunities

(2016) Alma I. Olivos-Suarez et al.   ACS Catalysis

Computational insights into the reaction mechanism of methanol-to-olefins conversion in H-ZSM-5: nature of hydrocarbon pool

(2016) Chuan-Ming Wang et al.   Catalysis Science & Technology

Simultaneous coking and dealumination of zeolite H-ZSM-5 during the transformation of chloromethane into olefins

(2016) M. Ibáñez et al.   Catalysis Science & Technology

The formation and degradation of active species during methanol conversion over protonated zeotype catalysts

(2015) U. Olsbye et al.   CHEMICAL SOCIETY REVIEWS

Coke formation and deactivation pathways on H-ZSM-5 in the conversion of methanol to olefins

(2015) Sebastian Müller et al.   JOURNAL OF CATALYSIS

Methylbenzene hydrocarbon pool in methanol-to-olefins conversion over zeolite H-ZSM-5

(2015) Chao Wang et al.   JOURNAL OF CATALYSIS

Methanol to Olefins (MTO): From Fundamentals to Commercialization

(2015) Peng Tian et al.   ACS Catalysis

Cooperativity between Al Sites Promotes Hydrogen Transfer and Carbon–Carbon Bond Formation upon Dimethyl Ether Activation on Alumina

(2015) Aleix Comas-Vives et al.   ACS Central Science

First principle chemical kinetics in zeolites: the methanol-to-olefin process as a case study

(2014) Veronique Van Speybroeck et al.   CHEMICAL SOCIETY REVIEWS

A route to form initial hydrocarbon pool species in methanol conversion to olefins over zeolites

(2014) Junfen Li et al.   JOURNAL OF CATALYSIS

Unraveling the Reaction Mechanisms Governing Methanol-to-Olefins Catalysis by Theory and Experiment

(2013) Karen Hemelsoet et al.   CHEMPHYSCHEM

Kinetic modeling of deactivation profiles in the methanol-to-hydrocarbons (MTH) reaction: A combined autocatalytic–hydrocarbon pool approach

(2013) Ton V.W. Janssens et al.   JOURNAL OF CATALYSIS

Catalyst deactivation by coke formation in microporous and desilicated zeolite H-ZSM-5 during the conversion of methanol to hydrocarbons

(2013) Francesca Lønstad Bleken et al.   JOURNAL OF CATALYSIS

Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity

(2012) Unni Olsbye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of the Catalytic Conversion of Methanol to Hydrocarbons

(2012) Samia Ilias et al.   ACS Catalysis

Methane conversion to light olefins—How does the methyl halide route differ from the methanol to olefins (MTO) route?

(2011) Unni Olsbye et al.   CATALYSIS TODAY

Zeolite-based materials for novel catalytic applications: Opportunities, perspectives and open problems

(2011) Jiří Čejka et al.   CATALYSIS TODAY

Radical Species Detection and Their Nature Evolution with Catalyst Deactivation in the Ethanol-to-Hydrocarbon Reaction over HZSM-5 Zeolite

(2011) F. Ferreira Madeira et al.   ACS Catalysis

In situ electron paramagnetic resonance: a unique tool for analyzing structure–reactivity relationships in heterogeneous catalysis

(2010) Angelika Brückner   CHEMICAL SOCIETY REVIEWS

Imaging photoelectron photoion coincidence spectroscopy with velocity focusing electron optics

(2009) Andras Bodi et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

Conversion of Methanol to Hydrocarbons: Spectroscopic Characterization of Carbonaceous Species Formed over H-ZSM-5

(2008) Luisa Palumbo et al.   Journal of Physical Chemistry C