4.7 Article

Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 180, Issue -, Pages 476-484

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2016.05.072

Keywords

Diethyl phthalate; Hydroxyl radical; Kinetics; Microbubbles; Mineralization; Ozonation

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Ozone microbubbles (OMBs) were used to remove diethyl phthalate (DEP) from water in a pilot plant. The removal of DEP and the mineralization efficiency were investigated under various reaction conditions. The removal of DEP by OMBs was very effective at the high pH and high ozone generation rates. Almost complete mineralization of DEP could be achieved at the high pH. The contribution of (OH)-O-center dot was computed by using a hydroxyl radical scavenger (i.e. t-BuOH). In neutral and alkaline media, the reaction of DEP with (OH)-O-center dot dominated over its direct reaction with ozone. The overall oxidation reaction fitted a second-order kinetic model. The overall rate constant and the volumetric mass transfer coefficient of ozone slightly increased with increasing pH. The results indicate that the OMBs were efficient in terms of the reduction of concentration of DEP and its complete mineralization. (C) 2016 Elsevier Ltd. All rights reserved.

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