4.7 Article

Remediation and phytotoxicity of decabromodiphenyl ether contaminated soil by zero valent iron nanoparticles immobilized in mesoporous silica microspheres

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 166, Issue -, Pages 478-483

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2015.10.042

Keywords

Polybrominated diphenyl ethers; Soil; Remediation; Nanoparticles; Phytotoxicity; Chinese cabbage

Funding

  1. National Natural Science Foundation of China [41471259]
  2. Guangdong Technology Research Centre for Ecological Management and Remediation of Urban Water Systems [2012gczxA005]
  3. Science and Technology Planning project of Guangdong province [2012B031000015]

Ask authors/readers for more resources

Polybrominated diphenyl ethers (PBDEs) are a new class of environmental pollutants which easily accumulated in the soil, especially at e-waste sites. However, knowledge about their phytotoxicity after degradation is not well understood. Nano zero valent iron (nZVI) immobilized in mesoporous silica microspheres covered with FeOOH (SiO2@FeOOH@Fe) synthesized in this study was utilized to remove decabromodiphenyl ether (BDE209) from soil. Results revealed that the removal efficiency of BDE209 can be achieved 78% within 120 h using a dosage of 0.165 g g(-1) and a pH of 5.42. Furthermore, the removal efficiency enhanced with increasing soil moisture content and the decreasing of initial BDE209 concentration. Phytotoxicity assays (biomass and germination rate, shoots and roots elongation of Chinese cabbage) were carried out to provide a preliminary risk assessment of treated soil for the application of SiO2@FeOOH@Fe. (c) 2015 Elsevier Ltd. All rights reserved.

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