Article
Chemistry, Inorganic & Nuclear
Weihong Yuan, Ran Pang, Shangwei Wang, Tao Tan, Jiangyue Su, Xuexia Chen, Ruize Liu, Chengyu Li, Su Zhang, Hongjie Zhang
Summary: We have developed a series of green-emitting persistent luminescence (PersL) phosphors BaY2Al2Ga2SiO12:Ce3+,Bi3+ (BYAGSO:Ce3+,Bi3+) via a defect engineering approach, which can be efficiently activated by blue-light and effectively reduce flicker in AC-LEDs. By investigating the trapping levels related to Bi3+ in BYAGSO:Ce3+,Bi3+ and fabricating an AC-LED device with low flicker, we demonstrate that the BYAGSO:Ce3+,Bi3+ phosphor is a promising candidate for low-flicker AC-LEDs.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Optics
Nan Ma, Zongjie Zhang, Wei Li, Xiaoyong Huang
Summary: A novel efficient cyan-emitting CLHSA:1%Ce3+ phosphor is discovered for blue-chip-pumped warm-white LEDs with high CRI. The optimal doping concentration of Ce3+ ions is found to be 1 mol%. The fabricated LED device shows a bright warm-white light emission with high CRI, low correlated color temperature, and good chromaticity coordinates.
JOURNAL OF LUMINESCENCE
(2023)
Article
Materials Science, Ceramics
Reziwanguli Yantake, Palidan Aierken, Taximaiti Yusufu, Shihang Zhou, Aierken Sidike
Summary: In this paper, a series of broadband cyan phosphors were prepared and characterized. The K0.96AlSiO4:0.04Ce(3+) phosphor showed the highest emission intensity and wide emission spectrum suitable for commercial LED applications.
CERAMICS INTERNATIONAL
(2023)
Review
Chemistry, Multidisciplinary
Noor Zamin Khan, Sayed Ali Khan, Weilong Chen, Muhammad Amin Padhiar, Muhammad Tahir Abbas, Zakir Ullah, Marcin Runowski, Xin Xu, Ren-Kui Zheng
Summary: Future generations of solid-state lighting will prioritize the development of innovative luminescent materials. Cyan-emitting phosphors fill the spectral gap and produce full-visible-spectrum lighting. The new cyan-emitting phosphor based on CLHAO garnet structure can be used as a cyan filler in warm-white LED manufacturing.
FRONTIERS IN CHEMISTRY
(2023)
Article
Chemistry, Applied
Yipeng Zhou, Yunsheng Hu, Ronghui Liu, Yuanhong Liu, Weidong Zhuang, Min Cao, Tongyu Gao, Junhang Tian, Yanfeng Li, Guantong Chen
Summary: A broadband blue-emitting Sr1-xCaxLu2O4:Ce3+ phosphor was synthesized for near-UV pumped white light-emitting diodes (w-LEDs). By partially substituting Sr2+ with Ca2+ (x = 0-0.2), the emission peak red-shifted, external quantum efficiency increased, and thermal stability improved in Sr1-xCaxLu2O4:Ce3+. The potential of Sr1-xCaxLu2O4:Ce3+ as blue phosphors for high CRI w-LEDs application was demonstrated.
JOURNAL OF RARE EARTHS
(2021)
Article
Chemistry, Physical
Amos Vincent Ntarisa, D. Joseph Daniel, D. Balaji, Arumugam Raja, H. J. Kim, Nguyen Duy Quang
Summary: In this study, powder samples of pure and Ce3+ doped cesium barium yttrium hexaborate were synthesized using a standard solid-state reaction technique. Various characterization techniques were employed to investigate the properties of the prepared samples. The rare earth ion Ce3+ was found to enhance the intrinsic luminescence of the phosphors, with an optimal doping concentration of 4 mol%. Additionally, the luminescence properties of the prepared phosphors were studied in detail for the first time in this manuscript.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Hao Liu, Zhongwen Li, Feng Nan, Rongfang Feng, Zhengzhong Zhang, Yongfu Liu
Summary: This study investigated a cyan phosphor with a suitable excitation wavelength and high thermal stability, which plays a key role in color conversion in white LEDs. The phosphor exhibits a high internal quantum efficiency and excellent thermal stability.
MATERIALS RESEARCH BULLETIN
(2023)
Article
Chemistry, Physical
Peixin Gao, Qian Li, Siying Li, Shujie Gai, Yanan Li, Yibiao Ma, Zengtao Zhang, Maxim S. Molokeev, Zhi Zhou, Mao Xia
Summary: A novel cyan-emitting phosphor Sr2GdGaO5/0.02Bi(3+) with optical tuning performance is synthesized based on the crystal field regulation strategy. Energy transfer from Bi3+ to Eu3+ is achieved, leading to the preparation of WLED with high color rendering index.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Optics
Zhe Xu, Balaji Devakumar, Nan Ma, Wei Li, Xiaoyong Huang
Summary: Near-ultraviolet pumped white light-emitting diodes based on tri-color phosphors are important for high-quality solid-state lighting, but the cyan gap between blue and green phosphors poses a limitation on color rendering index. Efforts are needed to develop efficient cyan phosphors with emission peaking around 490 nm to address this issue.
JOURNAL OF LUMINESCENCE
(2022)
Article
Chemistry, Physical
Ming-Yang Qu, Ting-Qu Li, Qiao-Li Liu
Summary: This study investigates the issues of traditional phosphor-converted white light emitting diodes (LEDs) caused by blue-green cavities in the luminescence spectrum. A series of cyan-emitting garnet phosphors were synthesized and analyzed for their optical properties and thermal quenching behavior. The relationship between synthesis temperature, energy gap, crystal field splitting, and the nephelauxetic effect on the luminescence intensity was studied. The study also explores the application of a cyan component in high-quality w-LEDs.
Article
Materials Science, Multidisciplinary
Ming Wang, Zhiqiang Zhong, Junhan Lin, Rui Zhang
Summary: In this study, ZrSiO4:Bi3+ phosphors were synthesized using the conventional high-temperature solid-phase method, and their structural and optical properties were investigated. The results showed that Bi2O3 played a role in the phase generation, and ZrSiO4:Bi3+ exhibited a broad emission band centered at 548 nm under excitation at 361 nm. The optimized Bi3+ doping concentration was found to be 4 mol%, and the luminescence intensity of ZrSiO4:0.04Bi3+ remained at 84% of the room temperature value at 150 degrees C. These findings suggest that ZrSiO4:Bi3+ phosphors have potential in near-UV excited white LED applications.
Article
Chemistry, Multidisciplinary
Zongjie Zhang, Balaji Devakumar, Shaoying Wang, Liangling Sun, Nan Ma, Wei Li, Xiaoyong Huang
Summary: This study demonstrated the efficient application of Ce3+-doped phosphors based on CLHAO garnet in the fabrication of high-CRI warm-white LEDs, showing good optical performance and thermal stability. By combining with commercial phosphors, warm-white LED devices with high CRI and superior color quality can be produced.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Materials Science, Ceramics
Ying Lv, Siting Fan, Yujie Zhao, Yu Liu, Xiaohang Zhang, Jie Zhao, Jian Yu
Summary: In this paper, a series of Ca3LuAl3B4O15 (CLAB) luminescent materials doped with Bi3+, Tb3+, and Eu3+ were successfully prepared and characterized. The synthesized phosphor exhibits strong blue band emission from Bi3+ and intense characteristics line emission from Tb3+ and Eu3+ under UV light excitation. The emission color can be adjusted by changing the doping content. The fabricated w-LED using CLAB:0.5%Bi3+,2%Tb3+,0.75%Eu3+ shows excellent thermal stability and promising application in single-phosphor-converted warm w-LEDs.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
Jingming Chan, Lina Cao, Zhe Xu, Xiaoyong Huang
Summary: Efficient cyan-green-emitting phosphors are developed based on the solid-solution design of chemical cation substitution for near-ultraviolet-excited white light-emitting diodes (LEDs). The improved quantum efficiency and thermal stability of the phosphors make them suitable for high-quality full-visible-spectrum LED lighting.
MATERIALS TODAY PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Liang Zhang, Langping Dong, Yonghui Xu, Shuwen Yin, Hongpeng You
Summary: A variety of Bi3+-activated and Bi3+-Eu3+ codoped Y3GaO6 phosphor samples were obtained by solid-state reaction, demonstrating high quantum efficiency and good thermal stability, making them promising candidates for WLEDs.
DALTON TRANSACTIONS
(2021)