Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 781, Issue -, Pages 36-40Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2016.07.010
Keywords
Tetrazines; Polypyrrole; beta-Cyclodextrin; Electropolymerisation; Inclusion complexes; Biosensor
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Funding
- PHC Brancui Project [32602 QD]
- ICMG [FR 2607]
- LabEx ARCANE [ANR-11-LABX-0003-01]
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Tetrazines were immobilized onto electrogenerated films of polypyrrole functionalized with beta-cyclodextrin. Their immobilization was ascribed to the formation of the inclusion complexes between the tetrazines derivatives and the beta-cyclodextrin cavity. We proved that the resulting supramolecular material kept the electrochemical and fluorescent properties of tetrazines. This original architecture was used with success as a bridge to immobilize the beta-cyclodextrin-tagged glucose oxidase, chosen as an enzyme model, to prove the efficiency of the method to build new supra-biomolecular architectures. (C) 2016 Elsevier B.V. All rights reserved.
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