4.7 Article

Polyamide-nylon 6 particulate polycarbonate composites with outstanding energy-absorbing properties

Journal

POLYMER
Volume 254, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2022.125082

Keywords

Energy absorption; Matrix yielding; Polyamide -nylon 6 particulate polycarbonate; composite

Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIT) [2022R1A2C3011968]
  2. Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, KOREA) [20013794]
  3. National Research Foundation of Korea [2022R1A2C3011968] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study systematically explores the toughening mechanism of thermoplastic polymer particle materials and ways to overcome the typical compromise in energy-absorbing composites through modeling and experimental research. The main energy-absorbing mechanism was found to be matrix yielding, which results from particle debonding and significantly contributes to crack propagation.
As there are gradually increasing interests in polymeric energy-absorbing materials to reduce unwanted noise/ vibration, and enhance impact resistance in structural applications, considerable efforts have been empirically made to improve energy-absorbing properties. However, there has been no detail understanding of the energy-absorbing mechanisms of particulate composites, thereby showing a trade-off between toughness and modulus/ strength. Therefore, by coupling modeling and experimental efforts, this study systematically explores the thermoplastic polymer particle toughening and ways to overcome the typical compromise in energy-absorbing composites. Polyamide-nylon 6 particulate polycarbonate composite was carefully designed for achieving extraordinary energy absorption with the uncompromised properties. The debonding, fracture toughness and yieldings were semi-empirically investigated to reveal fracture energy contributions. It was found that the mainly responsible energy-absorbing mechanism was matrix yielding (48.28%), which results from the particle debonding and significantly contribute to crack propagations. This study could provide new solutions for the energy-absorbing composites without any comprome in modulus/strength.

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