Reduction of CO2 and CS2 with Uranium(III) Metallocene Aryloxides

Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes

(2022) Justin C. Wedal et al.   INORGANIC CHEMISTRY

Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)

(2021) Robert J. Ward et al.   ORGANOMETALLICS

CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes

(2021) Xianghui Shi et al.   CHEMICAL COMMUNICATIONS

C–H Bond Activation by an Isolated Dinuclear U(III)/U(IV) Nitride

(2020) Chad T. Palumbo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CO2 Activation with Formation of Uranium Carbonate Complexes in a Closed Synthetic Cycle

(2020) Pablo Waldschmidt et al.   ORGANOMETALLICS

Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules

(2018) Rachel J. Kahan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Structure and properties of [(4,6-tBu2C6H2O)2Se]2An(THF)2, An = U, Np, and their reaction with p-benzoquinone

(2018) Alexander J. Myers et al.   CHEMICAL COMMUNICATIONS

Coordination Chemistry and QTAIM Analysis of Homoleptic Dithiocarbamate Complexes, M(S2CNiPr2)4 (M = Ti, Zr, Hf, Th, U, Np)

(2018) Andrew C. Behrle et al.   INORGANIC CHEMISTRY

C–H Bond Addition across a Transient Uranium–Nitrido Moiety and Formation of a Parent Uranium Imido Complex

(2018) Kimberly C. Mullane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The role of uranium–arene bonding in H2O reduction catalysis

(2017) Dominik P. Halter et al.   Nature Chemistry

Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand

(2017) Christopher J. Inman et al.   ORGANOMETALLICS

Carbon oxygenate transformations by actinide compounds and catalysts

(2017) Polly L. Arnold et al.   Nature Reviews Chemistry

Uranium Tetrakis-Aryloxide Derivatives Supported by Tetraazacyclododecane: Synthesis of Air-Stable, Coordinatively-Unsaturated U(IV) and U(V) Complexes

(2016) Julian Hümmer et al.   INORGANIC CHEMISTRY

CO2 conversion to isocyanate via multiple N–Si bond cleavage at a bulky uranium(iii) complex

(2015) Clément Camp et al.   CHEMICAL COMMUNICATIONS

Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure, and Ligand-Dependent Redox Behavior

(2015) Julie Andrez et al.   CHEMISTRY-A EUROPEAN JOURNAL

CS2 activation at uranium(iii) siloxide ate complexes: the effect of a Lewis acidic site

(2015) Clément Camp et al.   DALTON TRANSACTIONS

Coordination chemistry of 2,2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu

(2015) Joseph A. Macor et al.   DALTON TRANSACTIONS

Dithio- and Diselenophosphinate Thorium(IV) and Uranium(IV) Complexes: Molecular and Electronic Structures, Spectroscopy, and Transmetalation Reactivity

(2015) Andrew C. Behrle et al.   INORGANIC CHEMISTRY

Activation of SO2and CO2by Trivalent Uranium Leading to Sulfite/Dithionite and Carbonate/Oxalate Complexes

(2014) Anna-Corina Schmidt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multimetallic Cooperativity in Uranium-Mediated CO2 Activation

(2014) Oliver Cooper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling selectivity in the reductive activation of CO2 by mixed sandwich uranium(iii) complexes

(2014) Nikolaos Tsoureas et al.   Chemical Science

Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex

(2013) Nathan A. Siladke et al.   ORGANOMETALLICS

Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation

(2012) Victor Mougel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Uranium-mediated reductive conversion of CO2 to CO and carbonate in a single-vessel, closed synthetic cycle

(2012) Anna-Corina Schmidt et al.   CHEMICAL COMMUNICATIONS

Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes

(2012) Polly L. Arnold et al.   DALTON TRANSACTIONS

Reactivity of U–E–U (E = S, Se) Toward CO2, CS2, and COS: New Mixed-Carbonate Complexes of the Types U–CO2E–U (E = S, Se), U–CS2E–U (E = O, Se), and U–COSSe–U

(2012) Oanh P. Lam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methane: a new frontier in organometallic chemistry

(2012) Vincent N. Cavaliere et al.   Chemical Science

CC Bond Formation through Reductive Coupling of CS2 to Yield Uranium Tetrathiooxalate and Ethylenetetrathiolate Complexes

(2011) Oanh P. Lam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of a Uranium Trithiocarbonate Complex via the Nucleophilic Addition of a Sulfide-Bridged Uranium Complex to CS2

(2011) Oanh P. Lam et al.   INORGANIC CHEMISTRY

Functionalization of Carbon Dioxide and Carbon Disulfide Using a Stable Uranium(III) Alkyl Complex

(2011) Ellen M. Matson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N2, Coupling of CO, and Deoxygenation Insertion of CO2under Ambient Conditions

(2011) Stephen M. Mansell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone

(2011) Ellen M. Matson et al.   ORGANOMETALLICS

Insights into the mechanism of carbonate formation through reductive cleavage of carbon dioxide with low-valent uranium centers

(2010) Oanh P. Lam et al.   CHEMICAL COMMUNICATIONS

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Uranium azide photolysis results in C–H bond activation and provides evidence for a terminal uranium nitride

(2010) Robert K. Thomson et al.   Nature Chemistry

Carbonate Formation from CO2via Oxo versus Oxalate Pathway: Theoretical Investigations into the Mechanism of Uranium-Mediated Carbonate Formation†

(2010) Ludovic Castro et al.   ORGANOMETALLICS

Synthesis of a Thorium Tuck-In Complex, [(η5:η1-C5Me4CH2)(η5-C5Me5)Th{iPrNC(Me)NiPr}], by CH Bond Activation Initiated by (C5Me5)−

(2009) William J. Evans et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C5Me5)U{μ-η5:η1:η1-C5Me3(CH2)2}(μ-H)2U(C5Me5)2]

(2008) William J. Evans et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U(iii) complex

(2008) Owen T. Summerscales et al.   CHEMICAL COMMUNICATIONS

Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction

(2008) William J. Evans et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6

(2008) Skye Fortier et al.   INORGANIC CHEMISTRY

Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding

(2008) Christopher R. Graves et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes

(2008) Suzanne C. Bart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY