Enantioselective [3 + 2] Cycloaddition of Vinylcyclopropanes with Alkenyl N-Heteroarenes Enabled by Palladium Catalysis

β-Substituted Alkenyl Heteroarenes as Dipolarophiles in the Cu(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides Empowered by a Dual Activation Strategy: Stereoselectivity and Mechanistic Insight

(2021) Xin Chang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Diastereo- and Enantioselective [3 + 2] Cycloaddition of Vinylcyclopropanes with Azadienes: Efficient Access to Chiral Spirocycles

(2021) Kai Liu et al.   ORGANIC LETTERS

Synthesis of 2-aryl-1,2,4-triazol-3-one derivatives from β-nitroenamines

(2021) Dániel Nagy et al.   SYNTHETIC COMMUNICATIONS

Asymmetric Catalytic Reactions of Donor‐Acceptor Cyclopropanes

(2020) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in the Synthesis of Imine‐Containing Azaarene Derivatives via Photoredox Catalysis

(2020) Yanli Yin et al.   ChemCatChem

Transition Metal-Catalyzed Selective Carbon–Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions

(2020) Jianhua Wang et al.   CHEMICAL REVIEWS

Enantioselective [4 + 2] Cycloaddition Reaction of Vinylquinolines with Dienals Enabled by Synergistic Organocatalysis

(2020) Jing Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Highly Enantioselective Cycloaddition of Vinyl Cyclopropanes with Imines

(2019) Xiao-Bing Huang et al.   ORGANIC LETTERS

Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups

(2019) Wenbin Mao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elaborating Complex Heteroaryl-Containing Cycles via Enantioselective Palladium-Catalyzed Cycloadditions

(2019) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective synthesis of chiral azaheteroaryl ethylamines via dearomatizing aza-Michael/rearomatizing asymmetric protonation

(2018) Allan J. B. Watson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate Addition–Enantioselective Protonation of N-Aryl Glycines to α-Branched 2-Vinylazaarenes via Cooperative Photoredox and Asymmetric Catalysis

(2018) Yanli Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond geminal diesters: increasing the scope of metal-mediated vinylcyclopropane annulations while decreasing pre-activation

(2018) Duncan K. Brownsey et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Bifunctional iminophosphorane catalysed enantioselective sulfa-Michael addition of alkyl thiols to alkenyl benzimidazoles

(2018) Michele Formica et al.   Chemical Science

Synthetic applications of vinyl cyclopropane opening

(2017) Marta Meazza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cu-Catalyzed Enantioselective Boron Addition to N-Heteroaryl-Substituted Alkenes

(2017) Lu Wen et al.   ORGANIC LETTERS

Highly enantioselective catalytic synthesis of chiral pyridines

(2017) Ravindra P. Jumde et al.   Nature Communications

Alkenyl Arenes as Dipolarophiles in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides

(2016) Ana Pascual-Escudero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of pyridine-based agrochemicals by using Intermediate Derivatization Methods

(2016) Ai-Ying Guan et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines

(2016) Joshua J. Smith et al.   CHEMICAL COMMUNICATIONS

Asymmetric preparation of polysubstituted cyclopentanes by synergistic Pd(0)/amine catalyzed formal [3+2] cycloadditions of vinyl cyclopropanes with enals

(2016) Maxime Laugeois et al.   CHEMICAL COMMUNICATIONS

Asymmetric [3 + 2] Cycloaddition of Vinylcyclopropanes and α,β-Unsaturated Aldehydes by Synergistic Palladium and Organocatalysis

(2016) Kim Søholm Halskov et al.   ORGANIC LETTERS

Catalytic asymmetric addition of Grignard reagents to alkenyl-substituted aromatic N-heterocycles

(2016) R. P. Jumde et al.   SCIENCE

Recent Advances in the Synthesis and Reactivity of Vinylcyclopropanes

(2016) Srinivasan Chandrasekaran et al.   SYNTHESIS-STUTTGART

Stereoselective 1,6-Conjugate Addition/Annulation of para-Quinone Methides with Vinyl Epoxides/Cyclopropanes

(2016) Chao Ma et al.   ACS Catalysis

Enantioselective Aza Michael-Type Addition to Alkenyl Benzimidazoles Catalyzed by a Chiral Phosphoric Acid

(2015) Ya-Yi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A straightforward entry to chiral carbocyclic nucleoside analogues via the enantioselective [3+2] cycloaddition of α-nucleobase substituted acrylates

(2015) Ming-Sheng Xie et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Enantioselective Direct Additions of Aldehydes to 4-Vinylpyridines and Electron-Deficient Vinylarenes and Their Synthetic Applications

(2015) Sinan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+2] Cycloaddition of Vinylcyclopropane with Nitroalkenes Catalyzed by Palladium(0) with a Chiral Bis(tert-amine) Ligand

(2014) Feng Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Cycloadditions of Vinylcyclopropanes and in Situ Formed Unsaturated Imines: Construction of Structurally and Optically Enriched Spiroindolenines

(2014) Ze-Shui Liu et al.   ORGANIC LETTERS

Enantioselective Cycloadditions of Vinyl Cyclopropanes and Nitroolefins for Functionally and Optically Enriched Nitrocyclopentanes

(2014) Wen-Ke Li et al.   Asian Journal of Organic Chemistry

C═N-Containing Azaarenes as Activating Groups in Enantioselective Catalysis

(2013) Daniel Best et al.   JOURNAL OF ORGANIC CHEMISTRY

Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds

(2013) Lei Jiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Diastereo- and Enantioselective Formal [3 + 2]-Cycloadditions of Substituted Vinylcyclopropanes

(2012) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Vinyl Cyclopropanes and β,γ-Unsaturated α-Keto Esters: An Effective Route to Highly Functionalized Cyclopentanes

(2012) Liang-yong Mei et al.   ORGANOMETALLICS

Conjugate Additions to Vinyl-Substituted Aromatic N-Heterocycles

(2012) Douglas Klumpp   SYNLETT

Palladium-Catalyzed Diastereo- and Enantioselective Synthesis of Substituted Cyclopentanes through a Dynamic Kinetic Asymmetric Formal [3+2]-Cycloaddition of Vinyl Cyclopropanes and Alkylidene Azlactones

(2011) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Cytotoxicβ-Carboline Alkaloid fromGalianthe thalictroides

(2011) Patrícia Figueiredo et al.   PLANTA MEDICA

LiBr: A Mild Lewis Acid Catalyst for Efficient One-Pot Synthesis of α-Amino Nitriles

(2008) Anil Saini Suresh et al.   SYNTHETIC COMMUNICATIONS