Nitrogen reduction by the Fe sites of synthetic [Mo3S4Fe] cubes

Merging Pincer Motifs and Potential Metal–Metal Cooperativity in Cobalt Dinitrogen Chemistry: Efficient Catalytic Silylation of N 2 to N(SiMe 3 ) 3

(2021) Ming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[2Fe–2S] Cluster Supported by Redox-Active o-Phenylenediamide Ligands and Its Application toward Dinitrogen Reduction

(2021) Qiuming Liang et al.   INORGANIC CHEMISTRY

Dinitrogen binding and activation at a molybdenum–iron–sulfur cluster

(2021) Alex McSkimming et al.   Nature Chemistry

Reactivity, Mechanism, and Assembly of the Alternative Nitrogenases

(2020) Andrew J. Jasniewski et al.   CHEMICAL REVIEWS

Reduction of Substrates by Nitrogenases

(2020) Lance C. Seefeldt et al.   CHEMICAL REVIEWS

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

(2020) Matthew J. Chalkley et al.   CHEMICAL REVIEWS

Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry

(2020) Kazuki Tanifuji et al.   CHEMICAL REVIEWS

Structural evidence for a dynamic metallocofactor during N2 reduction by Mo-nitrogenase

(2020) Wonchull Kang et al.   SCIENCE

Synthesis of [Mo3S4] Clusters from Half-Sandwich Molybdenum(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes

(2019) Yasuhiro Ohki et al.   INORGANIC CHEMISTRY

A bound reaction intermediate sheds light on the mechanism of nitrogenase

(2018) Daniel Sippel et al.   SCIENCE

Cubane-Type [Mo3S4M] Clusters with First-Row Group 4-10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum

(2018) Yasuhiro Ohki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fe-Catalyzed Conversion of N2 to N(SiMe3)3 via an Fe-Hydrazido Resting State

(2018) Adam D. Piascik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2 activation on a molybdenum–titanium–sulfur cluster

(2018) Yasuhiro Ohki et al.   Nature Communications

[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction

(2017) Ryoichi Araake et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Silylation of Dinitrogen with a Dicobalt Complex

(2015) Randall B. Siedschlag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Binding of dinitrogen to an iron–sulfur–carbon site

(2015) Ilija Čorić et al.   NATURE

Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase

(2014) T. Spatzal et al.   SCIENCE

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry