Journal
JOURNAL OF CRYSTAL GROWTH
Volume 452, Issue -, Pages 158-161Publisher
ELSEVIER
DOI: 10.1016/j.jcrysgro.2016.03.016
Keywords
Growth from solution; Sol-Gel method; Nanomaterials; Oxides Magnetic materials; Titanium compounds
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We report the growth of [Mn, Co](x)TiO2 (x=0.01, 0.02 and 0.04) nanocrystals prepared by Sol-Gel technique, followed by freeze-drying treatment at -30 degrees C temperature for 12 h. The obtained Gel was thermally treated at different temperatures like 200, 400, 600 and 800 degrees C. The average crystalline size of 6-60 nm is achieved. The diffraction peak at 25.22, 25.49 and 25.6 shows that the main crystal phase is anatase without any indication of other phases. Transition metal doping leads to the reduction in the oxygen vacancies on the TiO2 surface and suppresses the crystallization of other phases by adsorbing onto the surface of the TiO2 particles. The peak at 27.47 indicates the presence of the rutile phase at 800 degrees C. Valence metal cation, Mn, Co ions can react with Ti4+ on the surface of TiO2, and Ti4+ is reduced to Ti3+ which inhibits the transformation of anatase to rutile. The photocatalytic degradation of formaldehyde has been successfully demonstrated using a 250 W UV. The binary doped transition metal ions in TiO2 nanoparticles can lead the efforts of enhancing their environmental application as photo catalyst. Magnetic measurement was carried using VSM. The magnetic susceptibility of the Mn, Co doped TiO2 nanopowder increases with increase in doping concentration and exhibits room temperature ferromagnetism. (C) 2016 Elsevier B.V. All rights reserved.
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