4.6 Article

Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules

Journal

JOURNAL OF MATERIALS SCIENCE
Volume 57, Issue 27, Pages 13078-13096

Publisher

SPRINGER
DOI: 10.1007/s10853-022-07399-y

Keywords

-

Funding

  1. Youth Growth Science and technology plan project of science and Technology Department of Jilin Province [20210508051RQ]
  2. Science and technology research project of Jilin Provincial Department of Education [JJKH20210755KJ]

Ask authors/readers for more resources

This study focuses on the preparation of bio-based epoxy resin with excellent thermal and flame retardant properties using green renewable resources. By using diphenolic acid, triglycidyl isocyanurate, and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide as raw materials, a multifunctional triglycidylester-diphenolic acid-bio-based epoxy (TDBE) was successfully prepared. The TDBE exhibited improved fire safety, reduced heat release rate, and increased adhesive strength, offering a broader application prospect for high-performance materials.
The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglycidylester-diphenolic acid- bio-based epoxy (TDBE) with diphenolic acid (DPA), triglycidyl isocyanurate (TGIC), and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide (DOPO) as raw materials. TDBE/DDM and bisphenol A epoxy resin curing agent (DGEBA/DDM) was prepared with 4,4'-diaminodiphenylmethane (DDM) as curing agent. TDBE/DDM has excellent fire safety. LOT value rose from 24.5 to 42.0%, and the UL-94 test level passes V-0 level. In the cone calorimeter test, the peak heat release rate (pHRR) is decreased by 69.3%. Besides, the lap shear TDBE adhesive strength was 42.9 MPa, which increased by 62.5%. This new multifunctional bio-based flame retardant epoxy resin provides a broader application prospect for high-performance materials. [GRAPHICS] .

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Industrial

Smart safety design for fire stairways in underground space based on the ascending evacuation speed and BMI

Ruihang Xie, Yin Pan, Tiejun Zhou, Wei Ye

SAFETY SCIENCE (2020)

Article Public, Environmental & Occupational Health

Telemedicine Assessment for the Mental Health of Rural Residents Based on the Safety Degree of Housing in Seismically Active Regions

Yin Pan, Ruihang Xie, Qin Yan, Tiejun Zhou

Summary: Earthquakes have a significant impact on the mental health of rural residents, with the safety and type of housing potentially playing a crucial role in influencing their mental well-being. Telemedicine assessment could be a promising approach for evaluating and prioritizing the mental health of rural residents in seismically active regions, offering potential for large-scale data scoring and mental health evaluation in the future.

FRONTIERS IN PUBLIC HEALTH (2021)

Article Materials Science, Composites

A novel waterborne g-CPP sizing agent for the interfacial enhancement of SCF/PP composites

Zheng Li, Kexin Wang, Xudong Liu, Jiaoli Hu, Jie Zhang, Guorui Yang, Ruihang Xie, Jialiang Zhang, Yuhui Ao

Summary: In this study, a new modified chlorinated polypropylene resin (g-CPP) was synthesized and used as a sizing agent for short carbon fiber (SCF) to enhance the interfacial adhesion of SCF reinforced polypropylene (PP) composites. The results showed that the g-CPP sizing agent improved the surface properties of SCF and significantly improved the flexural and tensile strengths of the composites.

POLYMER COMPOSITES (2022)

Review Construction & Building Technology

3D indoor environments in pedestrian evacuation simulations

Ruihang Xie, Sisi Zlatanova, Jinwoo Lee Brian

Summary: This paper surveys the use of three-dimensional indoor environments in pedestrian evacuation simulations and identifies the limitations and areas for future research. The findings highlight the need for enriching semantics, investigating 3D geometry, and fostering standardization of 3D indoor environments to enhance the realism of simulations.

AUTOMATION IN CONSTRUCTION (2022)

Article Engineering, Civil

Effect of Stairway Handrails on Pedestrian Fatigue and Speed during Ascending Evacuation

Rui Jiang, Yuexin Wang, Ruihang Xie, Tiejun Zhou, Dachuan Wang

Summary: This study aims to explore the specific effect mechanism of using handrails at different heights on individual fatigue and evacuation speed during ascending evacuation. The study found that participants' proportion of using handrails surged when the ascending vertical height exceeded a certain threshold and reached saturation, and handrails can effectively alleviate physical fatigue. In addition, using handrails significantly improved the evacuation speed, especially in the later period when speed attenuation slowed down.

ASCE-ASME JOURNAL OF RISK AND UNCERTAINTY IN ENGINEERING SYSTEMS PART A-CIVIL ENGINEERING (2022)

No Data Available