4.7 Article

Lightweight porous NiCo-SiC aerogel with synergistically dielectric and magnetic losses to enhance electromagnetic wave absorption performances

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 926, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.166758

Keywords

NiCo alloy; SiC aerogel; Dielectric loss; Magnetic loss; Electromagnetic wave absorption

Funding

  1. National Natural Science Foundation of China [51902348]
  2. Natural Science Foundation of Hunan Province, China [2021JJ40152]
  3. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China

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In this study, a highly efficient microwave absorber, NiCo-SiC aerogel, was successfully prepared using eggplant as the raw material. The synergistic enhancement of dielectric and magnetic losses was achieved by incorporating magnetic NiCo alloy nanoparticles in the porous SiC skeleton and nanowires. The NiCo-SiC aerogel exhibited a low density, minimum reflection loss, and wide absorption bandwidth, indicating its potential applications in lightweight and excellent electromagnetic wave absorbers.
Microwave absorption performances can be remarkably enhanced using an electromagnetic (EM) wave absorber with synergistically dielectric and magnetic losses. In this study, the eggplant was used as a raw material to produce silicon carbide (SiC) aerogel by two steps: carbonization and subsequent carbothermic reduction. Then the magnetic NiCo layer was coated on the SiC aerogel (NiCo-SiC) by chemical plating method. The NiCo-SiC aerogel with an extremely low density (0.194 g/cm(3)) primarily composed of a porous SiC skeleton, SiC nanowires, and the magnetic NiCo alloy nanoparticles distributed on SiC skeleton and nanowires surfaces. The existence of magnetic NiCo alloy nanoparticles in the aerogel, the magnetic and dielectric losses are both increased by the formed heterogeneous interfaces. Thus, the NiCo-SiC aerogel with a thickness of 3 mm exhibits a minimum reflection loss (RLmin) of - 44.5 dB and an effective absorption bandwidth (RL < -10 dB) of 7.6 GHz, which displays the potential application in lightweight and excellent EM wave absorbers. (C) 2022 Published by Elsevier B.V.

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