4.7 Article

Effects of intermediate wettability on entry capillary pressure in angular pores

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 473, Issue -, Pages 34-43

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2016.03.053

Keywords

Entry capillary pressure; Angular pores; Intermediate wettability; OpenFOAM

Funding

  1. UK Engineering and Physical Sciences Research Council (EPSRC)
  2. Engineering and Physical Sciences Research Council [1475494] Funding Source: researchfish

Ask authors/readers for more resources

Entry capillary pressure is one of the most important factors controlling drainage and remobilization of the capillary-trapped phases as it is the limiting factor against the two-phase displacement. It is known that the entry capillary pressure is rate dependent such that the inertia forces would enhance entry of the non-wetting phase into the pores. More importantly the entry capillary pressure is wettability dependent. However, while the movement of a meniscus into a strongly water-wet pore is well-defined, the invasion of a meniscus into a weak or intermediate water-wet pore especially in the case of angular pores is ambiguous. In this study using OpenFOAM software, high-resolution direct two-phase flow simulations of movement of a meniscus in a single capillary channel are performed. Interface dynamics in angular pores under drainage conditions have been simulated under constant flow rate boundary condition at different wettability conditions. Our results shows that the relation between the half corner angle of pores and contact angle controls the temporal evolution of capillary pressure during the invasion of a pore. By deviating from pure water-wet conditions, a dip in the temporal evolution of capillary pressure can be observed which will be pronounced in irregular angular cross sections. That enhances the pore invasion with a smaller differential pressure. The interplay between the contact angle and pore geometry can have significant implications for enhanced remobilization of ganglia in intermediate contact angles in real porous media morphologies, where pores are very heterogeneous with small shape factors. (C) 2016 The Authors. Published by Elsevier Inc.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Nanoscience & Nanotechnology

Fluid-Fluid Interfacial Effects in Multiphase Flow during Carbonated Waterflooding in Sandstone: Application of X-ray Microcomputed Tomography and Molecular Dynamics

Yongqiang Chen, Ahmad Sari, Junju Mu, Maxim Lebedev, Ali Saeedi, Vahid J. Niasar, Quan Xie

Summary: Fluid-fluid interfacial reactions play a significant role in influencing multiphase flow within porous materials, leading to increased hydrocarbon recovery during engineered carbonated waterflooding. Molecular dynamics simulations further show the impact of these interactions on interfacial properties, such as changes in interfacial tension, chemical species distribution, and CO2 diffusion.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Environmental Sciences

Dynamics of CO2 Density-Driven Flow in Carbonate Aquifers: Effects of Dispersion and Geochemistry

Hamidreza Erfani, Masoud Babaei, Vahid Niasar

Summary: This study investigates the process of CO2 dissolution in deep saline aquifers through numerical simulations, and highlights the importance of considering hydrodynamic dispersion and multispecies geochemical reactions. Results indicate that accounting for hydrodynamic dispersion can increase the CO2 dissolution flux and decrease the convection onset time, while geochemical reactions can enhance long-term efficiency but reduce total sequestered carbon during the diffusion-dominated period. The study emphasizes the significance of realistic geochemical representation and the spatial and temporal dependence of reactions for detailed simulation of the CO2 storage process.

WATER RESOURCES RESEARCH (2021)

Article Nanoscience & Nanotechnology

Operando Liquid Pressure Determination in Polymer Electrolyte Fuel Cells

Adrian Mularczyk, Qingyang Lin, Daniel Niblett, Alexandru Vasile, Martin J. Blunt, Vahid Niasar, Federica Marone, Thomas J. Schmidt, Felix N. Buchi, Jens Eller

Summary: This study investigates the complex and dynamic mechanisms of water cluster formation in fuel cells, aiming to minimize the number, size, and instability of water clusters by understanding the pressure evolution and instability of the feeding path during droplet formation. The research observed a 2 kPa higher breakthrough pressure compared to static capillary pressure evaluations, suggesting the need to rethink the dynamic liquid water invasion process in polymer electrolyte fuel cell gas diffusion layers.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Energy & Fuels

Electrostatic Characterization of the-COOH-Brine-Clay System: Implications for Wettability Alteration during Low Salinity Waterflooding in Sandstone Reservoirs

Yongqiang Chen, Vahid J. Niasar, Quan Xie

Summary: This study quantified the adhesion of the acid component (-COOH) on kaolinite surface using PHREEQC and PEST, revealing that PTBBA mainly adsorbs on the basal plane. This geochemical modeling corrected previous overestimations and provided a deeper understanding for predicting low salinity effects.

ENERGY & FUELS (2021)

Article Mechanics

Enhanced thermal fingering in a shear-thinning fluid flow through porous media: Dynamic pore network modeling

Senyou An, Muhammad Sahimi, Takshak Shende, Masoud Babaei, Vahid Niasar

Summary: In this paper, a pore network model is proposed to simulate thermal transport in flow through three-dimensional unstructured pore networks. The study investigates the effects of pore space heterogeneity, injection flow rate, and shear-thinning rheology on thermal-viscous fingering instability in porous media. The results highlight the importance of designing optimal flow conditions for application purposes.

PHYSICS OF FLUIDS (2022)

Article Engineering, Chemical

Process-Dependent Solute Transport in Porous Media

Hamidreza Erfani, Nikolaos Karadimitriou, Alon Nissan, Monika S. Walczak, Senyou An, Brian Berkowitz, Vahid Niasar

Summary: High-resolution optical imaging was used to study solute transport under single-phase flow conditions in porous micromodels. It was found that the transport time scale during unloading is larger than that under loading, with the difference between dispersion values decreasing with an increase in flow rate. Patterned heterogeneity micromodels increased the difference between transport time scales during loading and unloading processes.

TRANSPORT IN POROUS MEDIA (2021)

Article Environmental Sciences

Impact of Displacement Direction Relative to Heterogeneity on Averaged Capillary Pressure-Saturation Curves

Javad Shokri, Omar E. Godinez-Brizuela, Hamidreza Erfani, Yongqiang Chen, Masoud Babaei, Brian Berkowitz, Vahid Niasar

Summary: This study used optical imaging to investigate two-phase drainage in a heterogeneous micromodel under different injection rates and flow directions, and found that the capillary pressure-saturation relationship near a heterogeneity interface deviates from conventional models. The initial findings highlight the gaps in the understanding of upscaling capillary pressure in heterogeneous porous materials, and indicate that the discontinuity in saturation is more pronounced in the fine-to-coarse direction.

WATER RESOURCES RESEARCH (2022)

Article Water Resources

Scaling CO2 convection in confined aquifers: Effects of dispersion, permeability anisotropy and geochemistry

Hamidreza Erfani, Masoud Babaei, Carl Fredrik Berg, Vahid Niasar

Summary: Solubility trapping of carbon dioxide (CO2) in deep saline aquifers is an effective mechanism for carbon storage. This study investigates the scaling relations of convective mixing in the dissolution of CO2 in aquifer brine. The results provide new insights into the factors affecting the dissolution flux and onset time of convection, which are important for the prioritization and selection of appropriate aquifers for geological CO2 storage.

ADVANCES IN WATER RESOURCES (2022)

Article Environmental Sciences

Analytical Solution for Predicting Salt Precipitation During CO2 Injection Into Saline Aquifers in Presence of Capillary Pressure

A. M. Norouzi, V Niasar, J. G. Gluyas, M. Babaei

Summary: Salt precipitation during CO2 injection into saline aquifers is a significant phenomenon that reduces permeability and injectivity. Capillary pressure drives brine backflow in water-wet systems, leading to more precipitation. We developed an analytical solution considering the effect of capillary pressure, which was validated using numerical simulations. The solution accurately estimated the influence of capillary pressure on injectivity impairment due to salt precipitation.

WATER RESOURCES RESEARCH (2022)

Article Environmental Sciences

Experimental Analysis of Mass Exchange Across a Heterogeneity Interface: Role of Counter-Current Transport and Non-Linear Diffusion

Monika S. Walczak, Hamidreza Erfani, Nikolaos K. Karadimitriou, Ioannis Zarikos, S. Majid Hassanizadeh, Vahid Niasar

Summary: Solute transport in heterogeneous and fractured systems is complex. The mass exchange rate coefficient changes with time, and the transfer rate coefficient is smaller during the unloading process, possibly due to concentration-dependent counter-current advection-diffusion.

WATER RESOURCES RESEARCH (2022)

Article Environmental Sciences

Upscaling Hydrodynamic Dispersion in Non-Newtonian Fluid Flow Through Porous Media

Senyou An, Muhammad Sahimi, Vahid Niasar

Summary: Hydrodynamic dispersion in flow through porous media is an essential phenomenon in many geosystems. However, limited studies have focused on dispersion in flow of non-Newtonian fluids. This study used pore-scale simulations to investigate the effects of rheology and flow dynamics on hydrodynamic dispersion. Surprisingly, the simulations revealed a non-monotonic relationship between injection rate and dispersivity, highlighting the need for improved theories of transport in porous materials for non-Newtonian fluids.

WATER RESOURCES RESEARCH (2022)

Article Multidisciplinary Sciences

The impact of phosphorus on projected Sub-Saharan Africa food security futures

Daniel Magnone, Vahid J. Niasar, Alexander F. Bouwman, Arthur H. W. Beusen, Sjoerd E. A. T. M. van der Zee, Sheida Z. Sattari

Summary: New research indicates that sustainable and fossil fuel-driven economic growth can contribute towards improving food security in Sub-Saharan Africa. Phosphorus availability is a major barrier to food security, and pathways towards sustainability or fossil fuel reliance have different impacts on food security. Prioritizing sustainable economic growth and avoiding nationalist ideologies are key to enhancing food security in the region.

NATURE COMMUNICATIONS (2022)

Article Energy & Fuels

Kinetics of wettability alteration and droplet detachment from a solid surface by low-salinity: A lattice-Boltzmann method

Senyou An, Yuting Zhan, Hassan Mahani, Vahid Niasar

Summary: In this study, an advanced model is proposed to investigate the dynamics of droplet detachment from a surface, taking into account the impact of buoyancy and interfacial forces. The results demonstrate that the detachment time of droplets is not only determined by the Bond number, but also influenced by the diffusion length scale.
Article Electrochemistry

Impact of Porous Microstructure on Performance of Redox Flow Batteries: A Modeling Study

Javad Shokri, Daniel Niblett, Masoud Babaei, Vahid Niasar

Summary: The study successfully validated the improved 3D printable electrode design to enhance the performance of flow batteries through pore network modeling. A parametric study was conducted to investigate the impact of microstructure on battery performance.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Interfacial Tension-Temperature-Pressure-Salinity Relationship for the Hydrogen-Brine System under Reservoir Conditions: Integration of Molecular Dynamics and Machine Learning

Sina Omrani, Mehdi Ghasemi, Mrityunjay Singh, Saeed Mahmoodpour, Tianhang Zhou, Masoud Babaei, Vahid Niasar

Summary: Hydrogen (H-2) underground storage is an efficient strategy for large-scale storage. This study employed molecular dynamics simulation to develop a dataset for the interfacial tension (IFT) between H-2 and brine systems, and established a reliable correlation using three machine learning approaches.

LANGMUIR (2023)

Article Chemistry, Physical

Mechanistic exploration of Co doping in optimizing the electrochemical performance of 2H-MoS2/N-doped carbon anode for potassium-ion battery

Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu

Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Addressing the synchronized impact of a novel strontium titanium over copolymerized carbon nitride for proficient solar-driven hydrogen evolution

Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng

Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Magnetic-driven Interleukin-4 internalization promotes magnetic nanoparticle morphology and size-dependent macrophage polarization

Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas

Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Polyamide nanofiltration membranes by vacuum-assisted interfacial polymerization: Broad universality of Substrate, wide window of monomer concentration and high reproducibility of performance

Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu

Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Comparing polymer-surfactant complexes to polyelectrolytes

Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott

Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Crosslinking alginate at water-in-water Pickering emulsions interface to control the interface structure and enhance the stress resistance of the encapsulated probiotics

Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu

Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Multi-layering of carbon conductivity enhancers for boosting rapid recharging performance of high mass loading lithium ion battery electrodes

Sang Ho Lee, Yige Sun, Patrick S. Grant

Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Defect engineering induces Mo-regulated Co9Se8/FeNiSe heterostructures with selenium vacancy for enhanced electrocatalytic overall water splitting in alkaline

Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing

Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Surfactant-free microemulsions (SFMEs) as a template for porous polymer synthesis

Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz

Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Morphology regulation of isomeric covalent organic frameworks for high selective light scattering detection of lead

Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao

Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Preparation and dynamic color-changing study of fluorescent polymer nanoparticles for individualized and customized anti-counterfeiting application

Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan

Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Employing polyaniline/viologen complementarity to enhance coloration and charge dissipation in multicolor electrochromic display with wide modulation range

Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li

Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Facile constructing Ti3C2Tx/TiO2@C heterostructures for excellent microwave absorption properties

Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu

Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Reversible crowdedness of pH-responsive and host-guest active polymersomes: Mimicking μm-sized cell structures

Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans

Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Potassium regulating electronic state of zirconia supported palladium catalyst and hydrogen spillover for improved acetylene hydrogenation

Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu

Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)