Visible-light-driven photocatalytic degradation of ofloxacin by BiOBr nanocomposite modified with oxygen vacancies and N-doped CQDs: Enhanced photodegradation performance and mechanism

The rapid recombination of photogenerated carriers and weak light absorption capacity are two major challenges for bismuth-based photocatalysts. Here, N-CQDs/BiO1-xBr micro-flower photocatalysts with the visible-light activity were fabricated through the ethylene glycol solvothermal method for the first time, and oxygen vacancies (OVs) and N-doped carbon quantum dots (N-CQDs) were simultaneously introduced on the surface of BiOBr. OVs were introduced to form defective BiOBr (BiO1-xBr). N-CQDs and BiO1-xBr formed a strong binding effect. Then, the composition, morphology, crystal structure and photoelectric property of photocatalysts were studied, and the mechanism and pathway of ofloxacin (OFL) photodegradation were studied. N-CQDs/BiO1-xBr-4 was a micro-flower composed of nanosheets with a thickness of about 60 nm, this structure produced multiple light reflections. Photoelectrochemical analysis confirmed that the synergistic effect of OVs and N-CQDs significantly promoted the electron-hole separation (3 times vs BiOBr) and enhanced the light absorption range (Eg = 2.96 eV vs 3.24 eV). Meanwhile, the removal rate of OFL by N-CQDs/BiO1-xBr-4 was 6 times higher than that by BiOBr (Kobs of N-CQDs/BiO1-xBr-4 was 32 times higher than that of BiOBr). Electron spin resonances analysis and radical quenching experiments showed that .O2  and h+ played dominant roles in the OFL photodegradation system, and their contribution rates were 89.84% and 70.31%, respectively. There were main degradation pathways for OFL, including oxidation, dealkylation, hydroxylation and decarboxylation. This study explored the synergistic and complementary effects between OVs and N-CQDs, and provided a promising strategy for the photodegradation of toxic antibiotics by visible-light-driven photocatalysts.

Automated summary

In this study, N-CQDs/BiO1-xBr micro-flower photocatalysts with visible-light activity were successfully fabricated by introducing oxygen vacancies and N-doped carbon quantum dots. The synergistic effect of oxygen vacancies and N-CQDs significantly enhanced the electron-hole separation and light absorption capacity, resulting in a significantly higher removal rate of ofloxacin.