Nano-SiC-decorated Y2Si2O7 ceramic for enhancing electromagnetic waves absorption performance

To improve the electromagnetic (EM) wave absorption performance of rare earth silicate in harsh environments, this work synthesized dense SiC-Y2Si2O7 composite ceramics with excellent EM wave absorption properties by using the polymer permeation pyrolysis (PIP) process, which introduced carbon and SiC into a porous Y2Si2O7 matrix to form novel composite ceramics. SiC-Y2Si2O7 composite ceramics with different numbers of PIP cycles were tested and analysed. The results show that the as-prepared composites exhibit different microstructures, porosities, dielectric properties and EM wave absorption properties. On the whole, the SiC-Y2Si2O7 composite ceramics (with a SiC/C content of 29.88 wt%) show superior microwave absorption properties. The minimum reflection loss (RLmin) reaches -16.1 dB when the thickness is 3.9 mm at 9.8 GHz. Moreover, the effective absorption bandwidth (EAB) included a broad frequency from 8.2 GHz to 12.4 GHz as the absorbent thickness varied from 3.15 mm to 4.6 mm. In addition, the EM wave absorption mechanism was analysed profoundly, which ascribed to the multiple mediums of nanocrystalline, amorphous phases and turbostratic carbon distributed in the Y2Si2O7 matrix. Therefore, SiC-Y2Si2O7 composite ceramics with high-efficiency EM wave absorption performance promise to be a novel wave absorbing material for applications in harsh environments.

Automated summary

In this study, dense SiC-Y2Si2O7 composite ceramics with excellent electromagnetic wave absorption properties were synthesized using the polymer permeation pyrolysis process. The as-prepared composites exhibited different microstructures, porosities, dielectric properties, and electromagnetic wave absorption properties. SiC-Y2Si2O7 composite ceramics with a SiC/C content of 29.88 wt% showed superior microwave absorption properties.