Journal
CELLULOSE
Volume 29, Issue 12, Pages 6579-6593Publisher
SPRINGER
DOI: 10.1007/s10570-022-04669-5
Keywords
Fullerocyclopropane; Stabilizer; Nitrocellulose; Arylmalonamide; Thermal decomposition
Funding
- National Natural Science Foundation of China [51972278]
- Associated Foundation of Xi'an Modern Chemistry Research Institute [204-J-2020-2634]
- Open Project of State Key Laboratory of Environment-friendly Energy Materials (Southwest University of Science and Technology) [21fksy19]
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This study synthesized novel arylmalonamide[70]fullerocyclopropanes and investigated their thermal stability and influence on the thermal decomposition of nitrocellulose. The results showed that these compounds can significantly improve the thermal stability of nitrocellulose, presenting promising potential for applications as stabilizers.
The thermal decomposition or even explosion of nitrocellulose during long-term storage is prevented by adding stabilizers to nitrocellulose-based propellants. A series of novel arylmalonamide[70]fullerocyclopropane (3a-c) were synthesized through Bingel reaction. The molecular structures of 3a-c were verified through H-1 NMR, C-13 NMR, Fourier transform infrared spectroscopy (FT-IR), UV-visible spectroscopy, and mass spectrum. The thermal stability of 3a-c to nitrocellulose was studied by methyl violet paper test and iso-thermogravimetry method, and the results showed that the stability of 3a-c to nitrocellulose was significantly better than that of the [60]fullerene-based stabilizers. The thermal stability of 3a-c to nitrocellulose improved as the increase of the carbon chain length on the p-position of the benzene ring. The effects of 3a-c on the thermal decomposition of nitrocellulose were obtained by differential thermal analysis, and the results showed that the critical temperature of the thermal explosion of nitrocellulose can be increased by 0.1-2.8 degrees C by 3a-c. The thermal stability of 3a-c to nitrocellulose in adiabatic environment was confirmed by accelerating rate calorimetry. In addition, the stabilization mechanism was studied through ESR and FT-IR, and the results showed that 3a-c can react with nitrogen oxide radicals released by nitrocellulose. These arylmalonamide[70]fullerocyclopropane with excellent thermal stability and strong radical scavenging ability can be used as a promising stabilizer for single and double based propellants.
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